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The Carbocation :
The Carbocation : A Forgotten Lewis Acid Catalyst
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- Naidu, Veluru Ramesh (författare)
- KTH,Organisk kemi
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- Ni, Shengjun (författare)
- KTH,Organisk kemi
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- Franzén, Johan (författare)
- KTH,Organisk kemi
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(creator_code:org_t)
- 2015-06-11
- 2015
- Engelska.
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Ingår i: ChemCatChem. - : Wiley. - 1867-3880 .- 1867-3899. ; 7:13, s. 1896-1905
- Relaterad länk:
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https://urn.kb.se/re...
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visa fler...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- A Lewis acid that has received negligible attention as a catalyst is the carbocation. The carbocation is isoelectronic to boron and owes its Lewis acidity to a low-lying empty p(C) orbital. In terms of reactivity and stability carbocations are very versatile Lewis acids, from the extremely unstable methylium cation to the water-stable tris(N,N-dimethylaniline) methylium ion (crystal violet). Although the Lewis acid properties of carbocations have been extensively studied since the discovery of the tropolium ion more than 130years ago there is only a handful examples on the application of carbocations as Lewis acid catalysts. Herein, the research on triarylmethylium (trityl)-cation catalysis is summarized. In light of the reports the trityl ion emerges as a highly efficient and highly versatile Lewis acid catalyst capable of catalyzing different classes of reactions often with high selectivity and low catalyst loadings (for some reactions down to ppm levels).
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- aldol reaction
- carbocations
- Diels-Alder reaction
- Lewis acids
- organocatalysis
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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