Supramolecular self-assembly of heterobimetallic complexes : a new N,P-based, selective heteroditopic ligand

• Pyrimidine-hydrazone and phosphole architectures have been combined to create a new heteroditopic ligand capable of forming heterobimetallic Zn(II)/Pd(II), Pb(II)/Pd(II) and Cu(II)/Pd(II) complexes in high yielding stepwise or one pot reactions. The catalytic activity of these complexes in Heck coupling and Miyaura borylation reactions was investigated.

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NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

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