Synthesis and characterization of binuclear palladium(I) compounds and the influence of competing arenes

• The binuclear palladium(I) compounds, [Pd-2(Ga2Cl7)(2)(C7H8)(2)] (1), [Pd-2(GaCl4)(2)(C9H12)(2)]center dot C9H12 (2) and [Pd-2(Ga2Cl7)(2)(C6H5Cl)(2)] (3), have been prepared from palladium(II) chloride in gallium(III) chloride-arene reaction media. All isolated crystalline solids (1, 2 and 3) have been structurally characterized by single crystal X-ray diffraction and Raman spectroscopy. The results form quantum chemical calculations on the interaction energies of the arenes and the dipalladium unit of these compounds is also presented.

Ämnesord

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

NATURVETENSKAP  -- Kemi -- Organisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Organic Chemistry (hsv//eng)

Nyckelord

Palladium

Gallium chloride

Arenes

Binuclear compounds

Crystal structure

Inorganic chemistry

Oorganisk kemi

Organic chemistry

Organisk kemi

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