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A window–space-dire...
A window–space-directed assembly strategy for the construction of supertetrahedron-based zeolitic mesoporous metal–organic frameworks with ultramicroporous apertures for selective gas adsorption
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- Zhang, Lei (författare)
- College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China; Department of Chemistry, University of North Texas, Denton 76201, United States; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China
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- Li, Fangfang (författare)
- College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China
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- You, Jianjun (författare)
- College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China
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- Hua, Nengbin (författare)
- College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China
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- Wang, Quanting (författare)
- College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China
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- Si, Junhui (författare)
- College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China
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- Chen, Wenzhe (författare)
- College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China
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- Wang, Wenjing (författare)
- CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
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- Wu, Xiaoyuan (författare)
- CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
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- Yang, Wenbin (författare)
- CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
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- Yuan, Daqiang (författare)
- CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
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- Lu, Canzhong (författare)
- CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China; Xiamen Institute of Rare Earth Materials, Chinese Academy of Sciences, Xiamen 361021, China
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- Liu, Yanrong (författare)
- Luleå tekniska universitet,Energivetenskap
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- Al-Enizi, Abdullah M. (författare)
- Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
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- Nafady, Ayman (författare)
- Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
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- Ma, Shengqian (författare)
- Department of Chemistry, University of North Texas, Denton 76201, United States
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(creator_code:org_t)
- Royal Society of Chemistry, 2021
- 2021
- Engelska.
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Ingår i: Chemical Science. - : Royal Society of Chemistry. - 2041-6520 .- 2041-6539. ; 12:16, s. 5767-5773
- Relaterad länk:
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https://doi.org/10.1...
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https://ltu.diva-por... (primary) (Raw object)
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Despite their scarcity due to synthetic challenges, supertetrahedron-based metal–organic frameworks (MOFs) possess intriguing architectures, diverse functionalities, and superb properties that make them in‑demand materials. Employing a new window–space-directed assembly strategy, a family of mesoporous zeolitic MOFs have been constructed herein from corner-shared supertetrahedra based on homometallic or heterometallic trimers [M3(OH/O)(COO)6] (M3 = Co3, Ni3 or Co2Ti). These MOFs consisted of close-packed truncated octahedral cages possessing a sodalite topology and large β-cavity mesoporous cages (~22 Å diameter) connected by ultramicroporous apertures (~5.6 Å diameter). Notably, the supertetrahedron-based sodalite topology MOF composed with the Co2Ti trimer exhibited high thermal and chemical stability as well as the ability to efficiently separate acetylene (C2H2) from carbon dioxide (CO2).
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Maskinteknik -- Energiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Mechanical Engineering -- Energy Engineering (hsv//eng)
Nyckelord
- Energiteknik
- Energy Engineering
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- Av författaren/redakt...
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Zhang, Lei
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Li, Fangfang
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You, Jianjun
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Hua, Nengbin
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Wang, Quanting
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Si, Junhui
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Chen, Wenzhe
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Wang, Wenjing
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Wu, Xiaoyuan
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Yang, Wenbin
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Yuan, Daqiang
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Lu, Canzhong
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Liu, Yanrong
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Al-Enizi, Abdull ...
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Nafady, Ayman
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Ma, Shengqian
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- Om ämnet
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- TEKNIK OCH TEKNOLOGIER
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TEKNIK OCH TEKNO ...
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och Maskinteknik
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och Energiteknik
- Artiklar i publikationen
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Chemical Science
- Av lärosätet
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Luleå tekniska universitet