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61.
  • Andersson, David, 1978- (författare)
  • From the Electronic Structure of Point Defects to Functional Properties of Metals and Ceramics
  • 2007
  • Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
    • Point defects are an inherent part of crystalline materials and they influence important physical and chemical properties, such as diffusion, hardness, catalytic activity and phase stability. Increased understanding of point defects enables us to tailor the defect-related properties to the application at hand. Modeling and simulation have a prominent role in acquiring this knowledge. In this thesis thermodynamic and kinetic properties of point defects in metals and ceramics are studied using first-principles calculations based on density functional theory. Phenomenological models are used to translate the atomic level properties, obtained from the first-principles calculations, into functional materials properties. The next paragraph presents the particular problems under study. The formation and migration of vacancies and simple vacancy clusters in copper are investigated by calculating the energies associated with these processes. The structure, stability and electronic properties of the low-oxygen oxides of titanium, TiOx with 1/3 < x < 3/2, are studied and the importance of structural vacancies is demonstrated. We develop an integrated first-principles and Calphad approach to calculate phase diagrams in the titanium-carbon-nitrogen system, with particular focus on vacancy-induced ordering of the substoichiometric carbonitride phase, TiCxNy (x+y < 1). The possibility of forming higher oxides of plutonium than plutonium dioxide is explored by calculating the enthalpies for nonstoichiometric defect-containing compounds and the analysis shows that such oxidation is only produced by strong oxidants. For ceria (CeO2) doped with trivalent ions from the lanthanide series we probe the connection between the choice of a dopant and the improvement of ionic conductivity by studying the oxygen-vacancy formation and migration properties. The significance of minimizing the dopant-vacancy interactions is highlighted. We investigate the redox thermodynamics of CeO2-MO2 solid solutions with M being Ti, Zr, Hf, Th, Si, Ge, Sn or Pb and show that reduction is facilitated by small solutes. The results in this thesis are relevant for the performance of solid electrolytes, which are an integral part of solid oxide fuel cells, oxygen storage materials in automotive three-way catalysts, nuclear waste materials and cutting tool materials.
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62.
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63.
  • Andersson, Lena, 1980, et al. (författare)
  • Methodological issues on the use of urinary alpha-1-microglobuline in epidemiological studies.
  • 2008
  • Ingår i: Nephrology Dialysis Transplantation. - : Oxford University Press (OUP). - 0931-0509 .- 1460-2385. ; 23:4, s. 1252-1256
  • Tidskriftsartikel (refereegranskat)abstract
    • Background. Alpha-1-microglobulin (A1M) is a low molecular weight protein that can be measured in urine and used as a marker for tubular function, assuming that the normal variability within and between individuals is known. The aims of this study were to investigate this variability, to find the optimal way of sampling and quantifying A1M in spot urine samples to reflect the 24 h excretion and to examine storage stability. Method. Timed urine specimens were collected from 29 healthy volunteers at fixed time points over 24 h on two separate days. Volumes, creatinine and specific gravity were determined. All samples were analysed with a commercial ELISA for A1M. Results. We found a clear diurnal variation in A1M excretion rate and a gender effect (higher in males). The excretion rate was higher in the daytime, with high urinary flow, compared to overnight values. A1M excretion in spot urine samples was highly correlated with the 24 h excretion at all times except 22:00 in male subjects. Urinary A1M adjusted for creatinine concentration correlated well with the 24 h excretion. Variability within individuals was only 20% of the total variability in 24 h A1M excretion, but 43% in first morning urine. Expressed as CV, the intra-individual variability (between days) was 29% in 24 h excretion. Conclusion. We conclude that diurnal variation and gender should be taken into account when comparing groups. Moreover, in spot samples (e.g. first morning samples) adjustment of A1M for creatinine or specific gravity is a reliable alternative to 24 h urine.
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64.
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65.
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66.
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67.
  • Andersson, M., et al. (författare)
  • Dynamics of entry and exit of product varieties : What evolution dynamics can account for the empirical regularities?
  • 2011
  • Ingår i: Nonlinear Economic Dynamics. - : Nova Science Publishers, Inc.. - 9781616687885 ; , s. 155-174
  • Bokkapitel (refereegranskat)abstract
    • Firm-level heterogeneity is substantial even in narrowly defined industries. This chapter focuses on formulating evolution dynamics which can account for the observed heterogeneity and its maintenance. Based on examination of data on Swedish firms' supply pattern across different markets over time, we present a parsimonious model that has the ambition to capture the picture of heterogeneous firms, while accommodating the simultaneous exit and entry of destination varieties in firms' supply pattern. The model assumes both scale economies of firms and path-dependence, where the latter is manifested in such a way that the arrival rate of innovation ideas to an individual firm is a function of each firm's stock of varieties at every given point in time. The path-dependence phenomenon is an "explosive" non-linearity, whereas conservation mechanisms include development of demand and exit of established varieties. The described path dependence explains the skewed distribution of varieties across firms. Exit of obsolete varieties and growth of demand keep the "equilibrium" away from competitive exclusion where only few large firms remain. We make use of simulations to depict and assess the innovation dynamics of the proposed model.
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68.
  • Andersson, Martin, et al. (författare)
  • Dynamics of Entry and Exit of Product Varieties : – what evolution dynamics can account for the empirical regularities?
  • 2009
  • Rapport (övrigt vetenskapligt/konstnärligt)abstract
    • Firm-level heterogeneity is substantial even in narrowly defined industries. This paper focuses on formulating evolution dynamics which can account for the observed heterogeneity and its maintenance. Based on examination of data on Swedish firm’ supply pattern to different markets over time, we present a parsimonious model that has the ambition to capture the picture of heterogeneous firms, while accommodating the simultaneous exit and entry of destination varieties in firms’ supply pattern. The model assumes both scale economies of firms and pathdependence, where the latter is manifested in such a way that the arrival rate of innovation ideas to an individual firm is a function of each firm’s stock of varieties at every given point in time. The path-dependence phenomenon is an “explosive” non-linearity, whereas conservation mechanisms include development of demand and exit of established varieties. The described path dependence explains the skewed distribution of varieties across firms, but the question of what keeps the “equilibrium” away from competitive exclusion where only few large firms remain. We make use of simulations to depict and assess the innovation dynamics of the proposed model.
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69.
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70.
  • Andersson, Martin, et al. (författare)
  • Heterogeneous Distributions of Firms Sustained by Innovation Dynamics-A Model with Empirical Illustrations and Analysis
  • 2012
  • Ingår i: Journal of Industry, Competition and Trade. - : Springer Science and Business Media LLC. - 1566-1679 .- 1573-7012. ; 12:2, s. 239-263
  • Tidskriftsartikel (refereegranskat)abstract
    • This paper develops a framework of innovation dynamics to appreciate observed heterogeneity of firm size distributions, in which dynamics refer to exit and entry of product varieties and variety markets of individual firms. The analysis is based on a model of variety-triplets where every such triplet in the economy is identified by a unique combination of a variety, destination and firm. New variety triplets are introduced by innovating firms in a quasi-temporal setting of monopolistic competition. Ideas for variety-triplets arrive to firms according to a firm-specific and state dependent Poisson process, whereas variety triplets exit according to a destination-specific Poisson process. The empirical analysis employs a detailed firm-level data base which provides information about all variety triplets. Firm size is measured by a firm's number of variety triplets. The empirical results are compatible with the model predictions of (i) a persistent distribution of firm sizes, (ii) frequent events of exit and entry, and (iii) state dependent entry, where a state may be given by each firm's composition of triplets and/or other firm attributes.
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