| 121. |
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| 122. |
- Heimdal Nilsson, Elna, et al.
(författare)
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Re-evaluation of the reaction rate coefficient of CH3Br + OH with implications for the atmospheric budget of methyl bromide
- 2013
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Ingår i: Atmospheric Environment. - : Elsevier BV. - 1352-2310. ; 80, s. 70-74
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Tidskriftsartikel (refereegranskat)abstract
- The reaction rate coefficient k(CH3Br + OH) has been determined in the temperature range 298-373 K, using pulse radiolysis/UV kinetic spectroscopy, and at 298 K using a relative rate method. The Arrhenius expression obtained from a fit to the experimental results is (2.9 +/- 0.9) x 10(-12) exp(-(1230 +/- 125)/T) cm(3) molecule(-1) s(-1), which is greater than the expression currently recommended. The relative rate experiments give k(298 K) = (4.13 +/- 0.63) x 10(-14) cm(3) molecule(-1) s(-1). The results of the absolute and relative rate experiments indicate that the source budget of atmospheric CH3Br should be reinvestigated, as was recently done for CH3Cl. (C) 2013 Elsevier Ltd. All rights reserved.
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| 123. |
- Hertel, Ole, et al.
(författare)
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Assessing atmospheric nitrogen deposition to natural and semi-natural ecosystems - Experience from Danish studies using the DAMOS
- 2013
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Ingår i: Atmospheric Environment. - : Elsevier BV. - 1352-2310. ; 66, s. 151-160
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Tidskriftsartikel (refereegranskat)abstract
- Local agricultural emissions contribute significantly to the atmospheric reactive nitrogen loads of Danish terrestrial ecosystems. In the vicinity of the sources this may be up to 6-8 kg N ha(-1) yr(-1) depending on location and ecosystem type. This contribution arises from dry deposition of gas phase ammonia derived from local livestock production. Long-range transport, however, often constitutes the largest contribution to the overall atmospheric terrestrial reactive nitrogen loadings in Denmark. This is often in the range 10-15 kg N ha(-1) yr(-1) and consists mainly of aerosol phase nitrate and ammonium (reaction products of nitrogen oxides and ammonia), but also dry deposition of other reactive nitrogen compounds (mainly nitrogen oxides in the form of gas phase nitric acid and nitrogen dioxide). In Denmark's environmental management of the sensitive terrestrial ecosystems modelling tools are required that account for both the local and the long-range transported contributions. This motivated development of the Danish Ammonia MOdelling System (DAMOS) that has been successfully applied to the assessment of atmospheric nitrogen loadings to sensitive Danish ecosystems. We present here three different examples of such assessments. Our results show that ecosystems located in Western Denmark (Case 1) receive the highest loads of atmospheric nitrogen depositions which generally exceed the critical load. This part of the country has the highest livestock density. In the Eastern part of the country, the atmospheric loadings are often below or close to the lower end of the interval for critical load values. These lower loads in Eastern Denmark (Case 2) are due to lower density of agricultural activities, as well as, lower precipitation rates, which leads to less wet deposition of reactive nitrogen. In general there is a gradient in atmospheric deposition over the country, with the highest depositions in the South-Western part of Denmark (Case 3) due to long-range transport contributions from North-Western Europe, but also due to local ammonia deposition associated with the high local emission from the high density livestock farming in this area. (c) 2012 Elsevier Ltd. All rights reserved.
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| 124. |
- Hoffmann, Anne, et al.
(författare)
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Remote sensing and in situ measurements of tropospheric aerosol, a pamarcmip case study
- 2012
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Ingår i: Atmospheric Environment. - : Elsevier BV. - 1352-2310 .- 1873-2844. ; 52, s. 56-66
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Tidskriftsartikel (refereegranskat)abstract
- In this work, a closure experiment for tropospheric aerosol is presented. Aerosol size distributions and single scattering albedo from remote sensing data are compared to those measured in-situ. An aerosol pollution event on 4 April 2009 was observed by ground based and airborne lidar and photometer in and around Ny-Alesund, Spitsbergen, as well as by DMPS, nephelometer and particle soot absorption photometer at the nearby Zeppelin Mountain Research Station. The presented measurements were conducted in an area of 40 x 20 km around Ny-Alesund as part of the 2009 Polar Airborne Measurements and Arctic Regional Climate Model Simulation Project (PAMARCMiP). Aerosol mainly in the accumulation mode was found in the lower troposphere, however, enhanced backscattering was observed up to the tropopause altitude. A comparison of meteorological data available at different locations reveals a stable multi-layer-structure of the lower troposphere. It is followed by the retrieval of optical and microphysical aerosol parameters. Extinction values have been derived using two different methods, and it was found that extinction (especially in the UV) derived from Raman lidar data significantly surpasses the extinction derived from photometer AOD profiles. Airborne lidar data shows volume depolarization values to be less than 2.5% between 500 m and 2.5 km altitude, hence, particles in this range can be assumed to be of spherical shape. In-situ particle number concentrations measured at the Zeppelin Mountain Research Station at 474 m altitude peak at about 0.18 mu m diameter, which was also found for the microphysical inversion calculations performed at 850 m and 1500 m altitude. Number concentrations depend on the assumed extinction values, and slightly decrease with altitude as well as the effective particle diameter. A low imaginary part in the derived refractive index suggests weakly absorbing aerosols, which is confirmed by low black carbon concentrations, measured at the Zeppelin Mountain as well as on board the Polar 5 aircraft.
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| 125. |
- Holzinger, R., et al.
(författare)
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A signature of aged biogenic compounds detected from airborne VOC measurements in the high arctic atmosphere in March/April 2018
- 2023
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Ingår i: Atmospheric Environment. - 1352-2310. ; 309
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Tidskriftsartikel (refereegranskat)abstract
- During the PAMARCMiP 2018 campaign (March and April 2018) a proton-transfer-reaction mass spectrometer (PTR-MS) was deployed onboard the POLAR 5 research aircraft and sampled the high Arctic atmosphere under Arctic haze conditions. More than 100 compounds exhibited levels above 1 pmol/mol in at least 25% of the measurements. We used acetone mixing ratios, ozone concentrations, and back trajectories to identify periods with and without long-range transport from continental sources. During two flights, surface ozone depletion events (ODE) were observed that coincided with enhanced levels of acetone, and methylethylketone, and ice nucleating particles (INP).Air masses with continental influence contained elevated levels of compounds associated with aged biogenic emissions and anthropogenic pollution (e.g., methanol, peroxyacetylnitrate (PAN), acetone, acetic acid, meth-ylethylketone (MEK), proprionic acid, and pentanone). Almost half of all positively detected compounds (>100) in the high Arctic atmosphere can be associated with terpene oxidation products, likely produced from mono-terpenes and sesquiterpenes emitted from boreal forests. We speculate that the transport of biogenic terpene emissions may constitute an important control of the High Arctic aerosol burden. The sum concentration of the detected aerosol forming vapours is-12 pmol/mol, which is of the same order than measured dimethylsulfide (DMS) mixing ratios and their mass density corresponds to approximately one fifth of the measured non-black -carbon particles.
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| 126. |
- Hung, Hayley, et al.
(författare)
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Toward the next generation of air quality monitoring : Persistent organic pollutants
- 2013
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Ingår i: Atmospheric Environment. - : Elsevier BV. - 1352-2310 .- 1873-2844. ; 80, s. 591-598
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Tidskriftsartikel (refereegranskat)abstract
- Persistent Organic Pollutants (POPs) are global pollutants that can migrate over long distances and bioaccumulate through food webs, posing health risks to wildlife and humans. Multilateral environmental agreements, such as the Stockholm Convention on POPs, were enacted to identify POPs and establish the conditions to control their release, production and use. A Global Monitoring Plan was initiated under the Stockholm Convention calling for POP monitoring in air as a core medium; however long temporal trends (>10 years) of atmospheric POPs are only available at a few selected sites. Spatial coverage of air monitoring for POPs has recently significantly improved with the introduction and advancement of passive air samplers. Here, we review the status of air monitoring and modeling activities and note major uncertainties in data comparability, deficiencies of air monitoring and modeling in urban and alpine areas, and lack of emission inventories for most POPs. A vision for an internationally-integrated strategic monitoring plan is proposed which could provide consistent and comparable monitoring data for POPs supported and supplemented by global and regional transport models. Key recommendations include developing expertise in all aspects of air monitoring to ensure data comparability and consistency; partnering with existing air quality and meteorological networks to leverage synergies; facilitating data sharing with international data archives; and expanding spatial coverage with passive air samplers. Enhancing research on the stability of particle-bound chemicals is needed to assess exposure and deposition in urban areas, and to elucidate long-range transport. Conducting targeted measurement campaigns in specific source areas would enhance regional models which can be extrapolated to similar regions to estimate emissions. Ultimately, reverse-modeling combined with air measurements can be used to derive “emission” as an indicator to assess environmental performance with respect to POPs on the country, region, or global level.
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| 127. |
- Hussein, T., et al.
(författare)
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Factors affecting non-tailpipe aerosol particle emissions from paved roads: on road measurements in Stockholm, Sweden.
- 2008
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Ingår i: Atmos. Environ.. - : Elsevier BV. ; 42:4, s. 688-702
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Tidskriftsartikel (refereegranskat)abstract
- A large fraction of urban PM10 concentrations is due to non-exhaust traffic emissions. In this paper, a mobile measurement system has been used to quantify the relative importance of road particle emission and suspension of accumulated dust versus direct pavement wear, tire type (studded, friction, and summer), pavement type, and vehicle speed. Measurements were performed during May–September on selected roads with different pavements and traffic conditions in the Stockholm region. The highest particle mass concentrations were always observed behind the studded tire and the lowest were behind the summer tire; studded-to-summer ratios were 4.4–17.3 and studded-to-friction ratios were 2.0–6.4. This indicates that studded tires lead to higher emissions than friction and summer tires regardless to the asphalt type. By comparing with measurements in a road simulator, it could be estimated that the pavement wear due to the friction tires was 0.018–0.068 of the suspension of accumulated road dust. Likewise for studded tires road-wear was estimated to be 1.2–4.8 the suspension of accumulated dust. This indicates that wear due to friction tires is very small compared to the suspension of accumulated dust and that suspension due to studded tires may sometimes be as large as the wear of the road. But this will vary depending on, e.g. the amount of dust accumulated on the roads. An important dependence on vehicle speed was also observed. During May, the particle mass concentrations behind the studded tire at vehicle speed 100 km h−1 were about 10 times higher than that at 20 km h−1. The speed dependence was not so pronounced in September, which could be due to less accumulated dust on the roads. The particle number size distribution of the emissions due to road wear by studded tire was characterized by a clear increase in number concentrations of the coarse fraction of aerosol particles, with a geometric mean diameter between 3 and 5 μm. The size distribution of the emissions due to the summer tire was very similar with smaller concentrations. An important limitation with the measurements presented is that they were made by using a van, which is bigger than regular cars and has bigger tires. Thus, road wear and dust suspension due to cars are expected to be different.
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| 128. |
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| 129. |
- Hwang, K.W., et al.
(författare)
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Observation of difference in the size distribution of carbon and major inorganic compounds of atmospheric aerosols after the long-range transport between the selected days of winter and summer
- 2008
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Ingår i: Atmospheric Environment. - : Elsevier BV. - 1352-2310 .- 1873-2844. ; 42:5, s. 1057-1063
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Tidskriftsartikel (refereegranskat)abstract
- This paper presents the results from a study conducted in two urban areas in Korea to compare the size distributions of atmospheric aerosols, focusing on carbonaceous and certain major inorganic compounds, after long-range transport between selected days in winter and summer. Size segregated aerosols were sampled for 3 consecutive days each in February and July, 2004, and were analyzed to obtain the 24-h averaged concentrations of total mass, elemental carbon, organic carbon, nitrate, and sulfate. Backward trajectories from the receptor site on the sampling days were calculated to estimate the elapsed time for the air parcel to travel between Wonju and the Seoul metropolitan area. The averaged elapsed time on the sampling days was 3–12 h in the winter and 10–19 h in the summer. The enrichment of fine particles as expressed in particulate matter (PM)2/(PM10–PM2) was higher in the summer as compared to that in the winter. Size-fractionized concentration ratios of the organic to the elemental carbon at Wonju were two times as high as those at Seoul except for the particles with size <0.5 μm. This increasing trend was in proportional to the length of the elapsed time during the summer. Ultrafine particles in the summer were further enriched in carbon compounds, particularly in organic carbons and those in winter more enriched in the sulfates and nitrates. The mass fractions of organic carbon, elemental carbon, sulfate and nitrate became more significant with the decrease in the particle size.
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| 130. |
- Hyder, Murtaza, et al.
(författare)
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Yearly trend of dicarboxylic acids in organic aerosols from south of Sweden and source attribution
- 2012
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Ingår i: Atmospheric Environment. - : Elsevier BV. - 1352-2310. ; 57, s. 197-204
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Tidskriftsartikel (refereegranskat)abstract
- Seven aliphatic dicarboxylic acids (C3-C9) along with phthalic acid, pinic acid and pinonic acid were determined in 35 aerosol (PM10) samples collected over the year at Vavihill sampling station in south of Sweden. Mixture of dichloromethane and methanol (ratio 1:3) was preferred over water for extraction of samples and extraction was assisted by ultrasonic agitation. Analytes were derivatized using N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA) containing 1% trimethylsilyl chloride and analyzed using gas chromatography/mass spectrometry. Among studied analytes, azelaic acid was found maximum with an average concentration of 6.0 +/- 3.6 ng m(-3) and minimum concentration was found for pimelic acid (1.06 +/- 0.63 ng m(-3)). A correlation coefficients analysis was used for defining the possible sources of analytes. Higher dicarboxylic acids (C7-C9) showed a strong correlation with each other (correlation coefficients (r) range, 0.96-0.97). Pinic and pinonic acids showed an increase in concentration during summer. Lower carbon number dicarboxylic acids (C3-C6) and phthalic acid were found strongly correlated, but showed a poor correlation with higher carbon number dicarboxylic acids (C7-C9), suggesting a different source for them. Biomass burning, vehicle exhaust, photo-oxidation of volatile organic compounds (natural and anthropogenic emissions) were possible sources for dicarboxylic acids. (C) 2012 Elsevier Ltd. All rights reserved.
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