| 1. |
- Berggren, Magnus, et al.
(författare)
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Controlling inter-chain and intra-chain excitations of a poly(thiophene) derivative in thin films
- 1999
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Ingår i: Chemical Physics Letters. - : Elsevier. - 0009-2614 .- 1873-4448. ; 304:1-2, s. 84-90
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Tidskriftsartikel (refereegranskat)abstract
- The decay of photoexcitations in polythiophene chains has been studied in solid solutions of the polymer from room temperature to 4 K. A strong blue shift of the emission spectrum is observed in the polymer blend, as compared to the homopolymer. Dispersion of the polythiophene suppresses the non-radiative processes, which are suggested to be correlated to close contacts of polymer chains. Quantum chemistry modeling of the excited state distributed on two chains corroborate this conclusion.
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| 2. |
- Berggren, Magnus, et al.
(författare)
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Ultraviolet electroluminescence from an organic light emitting diode
- 1995
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Ingår i: Advanced Materials. - : Wiley-VCH Verlag Berlin. - 0935-9648 .- 1521-4095. ; 7:11, s. 900-903
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Tidskriftsartikel (refereegranskat)abstract
- The extension of the emission region for organic LEDs into the ultraviolet region is reported. Emission at 394 nm is achieved by modifying the geometry of a device based on poly(octylphenyl)bithiophene (PTOPT) and poly(octylphenyl)oxadiazole (PBD) which had previously been shown to emit white light. Through changing the geometry the red and green emission peaks have been suppressed and the UV band (from the PBD) enhanced.
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| 3. |
- Granlund, Thomas, et al.
(författare)
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A polythiophene microcavity laser
- 1998
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Ingår i: Chemical Physics Letters. - : Elsevier. - 0009-2614 .- 1873-4448. ; 288:5-6, s. 879-884
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Tidskriftsartikel (refereegranskat)abstract
- We report photopumped lasing in a microcavity device with a polythiophene layer as the emitter. These microcavity devices are built by joining two polymer coated dielectric mirrors at elevated temperature. When photopumping the film, a lasing threshold is observed at 120 nJ/cm(2). Comparative studies with fast pump-probe spectroscopy of thin polythiophene films and the same polymer in photopumped lasing studies, indicate that the gain coefficient is 80 +/- 20 cm(-1), and that the exciton concentration is 2 X 10(17) cm(-3) at the lasing transition, well below the exciton-exciton recombination level. (C) 1998 Elsevier Science B.V. All rights reserved.
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| 4. |
- Granlund, Thomas, et al.
(författare)
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Lasing in substituted polythiophene between dielectric mirrors
- 1999
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Ingår i: Synthetic metals. - : Elsevier. - 0379-6779 .- 1879-3290. ; 102:1-3, s. 1038-1041
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Tidskriftsartikel (refereegranskat)abstract
- We report photopumped lasing in a microcavity device with a polythiophene layer as emitter. The microcavity is made of a polymer film between two dielectric Bragg reflecting mirrors (DBR). The:microcavity devices is built by joining two polymer coated DBR mirrors at elevated temperature. When photopumping the film,a lasing threshold is observed at 120 nJ/cm(2). Comparative studies with fast pump-probe spectroscopy of thin polythiophene films, and the same polymer in photopumped lasing studies, indicate that the gain coefficient is 80 +/- 20 cm(2) and that the exciton concentration is 2X10(17) cm(2) at the lasing transition, well below the exciton-exciton recombination level.
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| 5. |
- Granström, Magnus, et al.
(författare)
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Micrometer- and Nanometer-Sized Polymeric Light-Emitting Diodes
- 1995
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Ingår i: Science. - : American Association for the Advancement of Science. - 0036-8075 .- 1095-9203. ; 267:5203, s. 1479-1481
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Tidskriftsartikel (refereegranskat)abstract
- A method for the fabrication of micrometer- and submicrometer-sized polymeric light-emitting diodes is presented. Such diodes have a variety of applications. Light sources of dimensions around 100 nanometers are required for subwavelength, near-field optical microscopy. Another possible application is patterning on the micrometer and nanometer scale. The diodes have been made in the form of a sandwich structure, with the conductive polymer poly(3,4-ethylene-dioxythiophene) polymerized in the pores of commercially available microfiltration membranes defining the hole-injecting contacts, poly[3-(4-octylphenyl)-2,2-bithiophene] as the light-omitting layer, and a thin film of calcium-aluminum as the electron injector.
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| 6. |
- Granström, Magnus, et al.
(författare)
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Phase separation of conjugated polymers - Tools for new functions in polymer LEDs
- 1997
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Ingår i: Synthetic metals. - : Elsevier. - 0379-6779 .- 1879-3290. ; 85:1-3, s. 1193-1194
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Tidskriftsartikel (refereegranskat)abstract
- Within the single family of substituted poly(thiophenes) it is possible to realize such diverse device designs as voltage controlled colours from polymer LEDs, sub-micron size LEDs, and white light emitters. Many of these features become possible by the use of polymer blends in which one or more poly(thiophenes) are mixed with a matrix polymer (PMMA). The phase structure in these blends can be controlled by stoichiometry and mode of formation. That phase structure can be used to prevent exciton transfer, and to define new colours in polymer LEDs. It also allows us to make anisotropic conductors suitable for contacting optical devices.
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| 7. |
- Granström, Magnus, et al.
(författare)
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Polymeric light-emitting diodes of submicron size - Structures and developments
- 1996
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Ingår i: Synthetic metals. - : Elsevier. - 0379-6779 .- 1879-3290. ; 76:1-3, s. 141-143
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Tidskriftsartikel (refereegranskat)abstract
- Micron- and submicron-sized light-emitting diodes (LEDs) made using conjugated polymers as electroluminescent layers and contact materials are presented. Two different routes to make arrays of such small light sources have been developed. The benefits and drawbacks of the use of the conjugated polymer poly(2,3-ethylene-dioxythiophene) (PEDOT) as hole injector in polymer LEDs are also discussed.
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| 8. |
- Granström, Magnus, et al.
(författare)
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Self organizing polymer films - a route to novel electronic devices based on conjugated polymers
- 1997
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Ingår i: Supramolecular science. - : ELSEVIER SCI LTD. - 0968-5677 .- 1873-4146. ; 4:1-2, s. 27-34
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Tidskriftsartikel (refereegranskat)abstract
- Polymer blends are often used in polymer light emitting diodes as a tool to increase the efficiency of the devices. In this report, we show the necessity to take the phase separation properties of such blends into account, as the miscibility of the involved polymers drastically affects the resulting film structure. By using phase separated polymer blends involving conjugated poly(thiophenes) and different nonconjugated polymers as matrices, different types of applications, such as light emitting diodes with improved voltage control of emitted colour, sub-micron size LEDs and anisotropic conductors are demonstrated. (C) 1997 Elsevier Science Ltd. All rights reserved.
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| 9. |
- Inganäs, Olle, et al.
(författare)
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Thiophene polymers in light emitting diodes : Making multicolour devices
- 1995
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Ingår i: Synthetic metals. - : Elsevier. - 0379-6779 .- 1879-3290. ; 71:1-3, s. 2121-2124
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Tidskriftsartikel (refereegranskat)abstract
- We can control the bandgap of thiophene polymers over 2 eV by choosing the nature, position and regularity of side chain substitutions. Electroluminescence from these polymers cover the full visible spectrum, from the blue into the near infra-red. Blends of these polymer materials allow us to construct voltage controlled variable colour light sources. A newly developed transfer technique allow us to mount thin oriented films of the polymers in polymer LEDs to obtain polarised light sources giving polarisation anisotropys of up to 3. Sub-lambda light sources have been constructed from these polymer materials using nanometer polymer electrodes.
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