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- Aasmundtveit, K.E., et al.
(författare)
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Structural anisotropy of poly(alkylthiophene) films
- 2000
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Ingår i: Macromolecules. - : American Chemical Society (ACS). - 0024-9297 .- 1520-5835. ; 33:8, s. 3120-3127
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Tidskriftsartikel (refereegranskat)abstract
- The structural anisotropy of various poly(alkylthiophene) films have been studied by X-ray diffraction, using both conventional methods and synchrotron radiation at grazing incidence. Solution-cast films orient with the side chains preferably normal to the film surface, whereas spin-cast films of nonstereoregular material orient with both the main and the side chains in the film plane. For thick (10-50 µm) solution-cast films, the degree of orientation depends strongly on the solvent used for casting, and on the stereoregularity of the polymer, films of stereoregular materials being more oriented than those of nonregular materials. The most oriented nonregular films are those cast from mixtures of chloroform and tetrahydrofuran. Thin (50-500 nm) solution-cast films are more oriented than the thicker ones, and the effects of different stereoregularity or different casting solvents are small. For spin-cast films, the degree of orientation is independent of substrate and solvent. Spin-cast films of stereoregular material have two different phases: One with the side chains normal to the substrate, and another where they are parallel to the substrate. The diffraction peaks of spin-cast poly(octylthiophene) narrow considerably upon heating.
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- Aasmundtveit, K.E., et al.
(författare)
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Structural aspects of electrochemical doping and dedoping of poly(3,4-ethylenedioxythiophene)
- 2000
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Ingår i: Synthetic metals. - 0379-6779 .- 1879-3290. ; 113:1, s. 93-97
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Tidskriftsartikel (refereegranskat)abstract
- Electrochemical dedoping and redoping of p-toluene sulfonate doped poly(3,4-ethylenedioxythiophene) (PEDOT) has been studied with in situ grazing incidence diffraction with water used as an electrolyte. The diffraction peak positions and integrated intensities do not change significantly during doping and dedoping, while the peak widths increase upon dedoping and decrease upon doping. This implies that the lattice parameters and the relative positions of the polymer chains and the p-toluene sulfonate ions remain unchanged, the redox processes being carried out by the motion of smaller ions between the polymer and the electrolyte, and that the structural order decreases upon dedoping and increases upon doping in a reversible manner.
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- Abram, Simone, et al.
(författare)
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The free movement of people around the world would be Utopian : IUAES World Congress 2013
- 2017
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Ingår i: Identities. - 1070-289X .- 1547-3384. ; 24:2, s. 123-155
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Forskningsöversikt (refereegranskat)abstract
- This article contains the text and discussion of a debate held at the IUAES World Congress in Anthropology at Manchester University in 2013. The motion was proposed by Bela Feldman-Bianco (State University of Campinas), seconded by Noel Salazar (University of Leuven) and was opposed by Shahram Khosravi (Stockholm University), seconded by Nicholas de Genova (then at Goldsmiths' College). The debate was chaired by Simone Abram (Durham University).
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| 8. |
- Admassie, Shimelis, et al.
(författare)
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Biopolymer hybrid electrodes for scalable electricity storage
- 2016
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Ingår i: Materials Horizons. - : ROYAL SOC CHEMISTRY. - 2051-6347 .- 2051-6355. ; 3:3, s. 174-185
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Forskningsöversikt (refereegranskat)abstract
- Powering the future, while maintaining a cleaner environment and a strong socioeconomic growth, is going to be one of the biggest challenges faced by mankind in the 21st century. The first step in overcoming the challenge for a sustainable future is to use energy more efficiently so that the demand for fossil fuels can be reduced drastically. The second step is a transition from the use of fossil fuels to renewable energy sources. In this sense, organic electrode materials are becoming increasingly attractive compared to inorganic electrode materials which have reached a plateau regarding performance and have severe drawbacks in terms of cost, safety and environmental friendliness. Using organic composites based on conducting polymers, such as polypyrrole, and abundant, cheap and naturally occurring biopolymers rich in quinones, such as lignin, has recently emerged as an interesting alternative. These materials, which exhibit electronic and ionic conductivity, provide challenging opportunities in the development of new charge storage materials. This review presents an overview of recent developments in organic biopolymer composite electrodes as renewable electroactive materials towards sustainable, cheap and scalable energy storage devices.
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| 10. |
- Aikio, A. T., et al.
(författare)
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Temporal evolution of two auroral arcs as measured by the Cluster satellite and coordinated ground-based instruments
- 2004
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Ingår i: Annales Geophysicae. - : Copernicus GmbH. - 0992-7689 .- 1432-0576. ; 22:12, s. 4089-4101
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Tidskriftsartikel (refereegranskat)abstract
- The four Cluster s/c passed over Northern Scandinavia on 6 February 2001 from south-east to north-west at a radial distance of about 4.4 R-E in the post-midnight sector. When mapped along geomagnetic field lines, the separation of the spacecraft in the ionosphere was confined to within 110 km in latitude and 50 km in longitude. This constellation allowed us to study the temporal evolution of plasma with a time scale of a few minutes. Ground-based instrumentation used involved two all-sky cameras, magnetometers and the EISCAT radar. The main findings were as follows. Two auroral arcs were located close to the equatorward and poleward edge of a large-scale density cavity, respectively. These arcs showed a different kind of a temporal evolution. (1) As a response to a pseudo-breakup onset, both the up- and downward field-aligned current (FAC) sheets associated with the equatorward arc widened and the total amount of FAC doubled in a time scale of 1-2 min. (2) In the poleward arc, a density cavity formed in the ionosphere in the return (downward) current region. As a result of ionospheric feedback, a strongly enhanced ionospheric southward electric field developed in the region of decreased Pedersen conductance. Furthermore, the acceleration potential of ionospheric electrons, carrying the return current, increased from 200 to 1000 eV in 70 s, and the return current region widened in order to supply a constant amount of return current to the arc current circuit. Evidence of local acceleration of the electron population by dispersive Alfven waves was obtained in the upward FAC region of the poleward arc. However, the downward accelerated suprathermal electrons must be further energised below Cluster in order to be able to produce the observed visible aurora. Both of the auroral arcs were associated with broad-band ULF/ELF (BBELF) waves, but they were highly localised in space and time. The most intense BBELF waves were confined typically to the return current regions adjacent to the visual arc, but in one case also to a weak upward FAC region. BBELF waves could appear/disappear between s/c crossings of the same arc separated by about 1 min.
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