| 1. |
- Aleksandrovskii, A. N., et al.
(författare)
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Effect of argon on the thermal expansion of fullerite C60 at helium temperatures
- 2001
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - : American Institute of Physics. - 1063-777X .- 1090-6517. ; 27:3, s. 245-246
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Tidskriftsartikel (refereegranskat)abstract
- The linear thermal expansion of compacted Ar-doped fullerite C60(ArxC60) is investigated at 2–12 K using a dilatometric method. The thermal expansion of ArxC60 is also studied after partial desaturation of argon from fullerite. It is revealed that argon doping resulted in a considerable change of the temperature dependence of the thermal expansion of fullerite. An explanation of the observed effects is proposed.
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| 2. |
- Aleksandrovskii, A. N., et al.
(författare)
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Low-temperature thermal expansion of pure and inert gas-doped fullerite C60
- 2003
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Ingår i: Fizika Nizkikh Temperatur (Kharkov). - : AIP Publishing. - 0132-6414 .- 1816-0328. ; 29:4, s. 432-442
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Tidskriftsartikel (refereegranskat)abstract
- The low temperature (2–24 K) thermal expansion of pure (single-crystal and polycrystalline) C60 and polycrystalline C60 intercalated with He, Ne, Ar, and Kr has been investigated using the high-resolution capacitance dilatometer. The investigation of the time dependence of the sample length variations deltaL(t) on heating by deltaT shows that the thermal expansion is determined by the sum of positive and negative contributions, which have different relaxation times. The negative thermal expansion usually prevails at helium temperatures. The positive expansion is connected with the phonon thermalization of the system. The negative expansion is caused by reorientation of the C60 molecules. It is assumed that the reorientation is of a quantum character. The inert gas impurities affect the reorientation of the C60 molecules very strongly, especially at liquid helium temperatures. A temperature hysteresis of the thermal expansion coefficient of Kr– and He–C60 solutions has been revealed. The hysteresis is attributed to orientational polyamorphous transformation in these systems.
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| 3. |
- Aleksandrovskii, A.N., et al.
(författare)
-
Thermal expansion of fullerite C60 alloyed with argon and neon
- 2001
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - Woodbury : American Institute of Physics. - 1063-777X .- 1090-6517. ; 27:12, s. 1033-1036
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Tidskriftsartikel (refereegranskat)abstract
- The linear thermal expansion of compacted fullerite C60 alloyed with argon (ArxC60) and neon (NexC60) are investigated by a dilatometric method. The experimental temperature is 2–12 K. In the same temperature interval the thermal expansion of ArxC60 and NexC60 are examined after partial desaturation of the gases from fullerite. It is found that Ar and Ne alloying affects the temperature dependence of the thermal expansion coefficient of C60 quite appreciably. The libration and translation contributions to the thermal expansion of pure C60 are separated. The experimental results on the thermal expansion are used to obtain the Debye temperature of pure C60. The effects observed are tentatively interpreted.
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| 4. |
- Aleksandrovskii, A. N., et al.
(författare)
-
Thermal expansion of single-crystal fullerite C60 at helium temperatures
- 2000
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 26:1, s. 75-80
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Tidskriftsartikel (refereegranskat)abstract
- The thermal expansion of single-crystal fullerite C60 has been studied in the range of liquid-helium temperatures (2–10 K). At temperatures below ~4.5 K the thermal expansion of fullerite C60 becomes negative, in agreement with the previous results on polycrystalline materials. A qualitative explanation of the results is proposed.
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| 5. |
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| 6. |
- Buga, Sergei G., et al.
(författare)
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Dissociation energy of 3D-polymeric C60 : Calorimetric study and structural analysis
- 2001
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Ingår i: Electronic Properties of Novel Materials - Science and Technology of Molecular Nanostructures. - Melville, NY : American Institute of Physics. - 0735400334 ; , s. 49-53
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Konferensbidrag (refereegranskat)abstract
- Annealing of 2D- and 3D-polymeric C[sub60] fullerene obtained under pressures of 9.5 and 12.5 GPa and temperatures of 670 and 770 K has been investigated by DSC in the range 240–640 K. An endothermal heat effect was observed with a peak maximum just below 540 K, a temperature characteristic for breakdown of (2+2) intermolecular links in dimers, 1D and 2D polymers. Exothermal effects, starting from 380 K, were observed for the first time in polymeric fullerenes. These effects are attributed to relaxation processes and to breakdown of other types of intermolecular bonds such as common four-sided rings and (3+3) interlinks.
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| 7. |
- Buga, Sergei G., et al.
(författare)
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DSC study of annealing and phase transformations of C60 and C70 polymerized under pressures in the range 9.5 - 13 GPa.
- 2002
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Ingår i: Journal of Physics and Chemistry of Solids. - : Elsevier B.V.. - 0022-3697 .- 1879-2553. ; 63:2, s. 331-343
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Tidskriftsartikel (refereegranskat)abstract
- C60 and C70 fullerenes polymerized under pressures between 9.5 and 13 GPa and temperatures between 670 and 1850 K were investigated by differential scanning calorimetry (DSC) in the range 240–640 K. Endothermal heat effects were observed with a peak maximum just below 540 K, a temperature characteristic for breakdown of (2+2) intermolecular links in dimers, 1D and 2D polymers. Exothermal effects, starting from 380 K, were observed for the first time in polymeric fullerenes. These effects are attributed to relaxation processes and to breakdown of other types of intermolecular bonds such as common four-sided rings and (3+3) interlinks.
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| 8. |
- Buga, Sergei G., et al.
(författare)
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Pressure effect on electrical properties and photoluminescence spectra of solid C60 and C70 fullerenes
- 2001
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Ingår i: Frontiers of High Pressure Research II: Application of High Pressure to Low-Dimensional Novel Electronic Materials. - Dordrecht : Springer/Kluwer. - 9781402001604 ; , s. 483-491
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Konferensbidrag (refereegranskat)abstract
- Electrical resistivity of crystalline and disordered fullerite samples obtained by static high-pressure-high-temperature treatment of C-60 and C-70 at P = 12.5 GPa and T = 820-1500 K was investigated in the temperature range of 2.4-300 K, Room-temperature activation energy of charge carriers was found to be in the range 40-200 meV. T-3/2 and T-4 dependencies of conductivity versus temperature were revealed both in crystalline and disordered structures. Photoluminescence spectra of C-60 samples treated at P = 13 GPa. T = 770-1470 K show 50 nm short-wave length shift of characteristic 750 nm PL band.
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| 9. |
- Buga, Sergei G., et al.
(författare)
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Semimetallic and semiconductor properties of some superhard and ultrahard fullerites in the range 300-2 K
- 2000
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Ingår i: Proceedings of the 5th IUMRS International Conference on Advanced Materials, Beijing 1999. - : Elsevier B.V.. ; , s. 1009-1015
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Konferensbidrag (refereegranskat)abstract
- Electrical resistivity and magnetoresistance were measured on samples with disordered structures synthesized from pure C60 and C70 at pressures in the range 8–12.5 GPa and temperatures of 900–1500 K. Different types of behaviour were observed: semimetallic, VRH and semiconducting, depending on the degree of disorder and the particular short-range order of the samples. A negative magnetoresistance was observed at T<10 K on samples with a semimetallic type of conductivity synthesized at 8 GPa pressure. The temperature dependence of resistivity in the sample with a disordered crystalline structure based on 3D-polymerized C60 molecules fits Mott's law for hopping conductivity. T3/2, T2 and T4 dependencies of conductivity are observed for samples with densities of 2.8 and 3.05 g/cm3 synthesized at a pressure of 12.5 GPa. The effect of hydrostatic pressure on the resistivity of cross-linked layered carbon structures obtained from C60 at P=8 GPa, T=1600 K was investigated up to 0.6 GPa at room temperature. An approximately linear decrease of resistivity was observed with a very small value of the derivative d ln ρ/dp=0.06 /GPa, which correlates with a very low compressibility of the material.
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| 10. |
- Buga, Sergei G., et al.
(författare)
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Synthesis of superhard 3D-polymeric C60 fullerites from rhombohedral 2D-polymer by high-pressure-high-temperature treatment.
- 2003
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Ingår i: High Pressure Research vol. 23, issue 3. - London : Taylor & Francis. ; , s. 259-264
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Konferensbidrag (refereegranskat)abstract
- Rhombohedral C60 polymer was subjected to high-pressure-high-temperature treatment at P =13 GPa, T =620-1620 K. After quenching, crystalline and disordered structures with densities in the range of 2.1-2.9 g cm-1 were obtained. The structures of the samples have been investigated by powder X-ray diffraction and Raman scattering. DSC analysis showed a transformation of the polymeric structure into monomeric on annealing in the range 400-640 K. The temperature dependence of the electrical resistance of samples with disordered structure was measured in the range 2.5-300K. For different samples, the conductivity was proportional to T1/2, T3/2, T4 and exp(-1/T1/4).
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