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- PLAVEC, J, et al.
(author)
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REPARAMETRIZATION OF KARPLUS EQUATION RELATING (3)J(C-C-O-P) TO TORSION ANGLE
- 1995
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In: TETRAHEDRON LETTERS. - : PERGAMON-ELSEVIER SCIENCE LTD. - 0040-4039. ; 36:11, s. 1949-1952
-
Journal article (other academic/artistic)abstract
- A new three-parameter Karplus equation (3)J(C-C-O-P) = 9.1 cos(2) Phi - 1.9 cos Phi + 0.8 is based on the 17 (3)J(CP) coupling constants and the corresponding X-ray derived torsion angles giving an r.m.s. of 0.3 Hz and Delta J < 0.5 Hz between J(exp) and
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45. |
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46. |
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- PURI, N, et al.
(author)
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THE SYNTHESIS AND REACTIVITY OF NEW 2-(N,N-DIISOPROPYLAMINO)-3-METHYLSULFONYL-1,3,2-BENZOXAZAPHOSPHOLES - THE UTILITY OF THE 5-CHLORO ANALOG IN THE ONE-POT SYNTHESIS OF OLIGOTHIOPHOSPHATES - [AP(S)PPA, AP(S)PPPA, PPP5'A2'P(S)5'A, M(7)GP(S)PPA, AP(S)PPPP
- 1995
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In: TETRAHEDRON. - : PERGAMON-ELSEVIER SCIENCE LTD. - 0040-4020. ; 51:10, s. 2991-3014
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Journal article (other academic/artistic)abstract
- The synthesis of 2-(N,N-diisopropylamino)-2-3-dihydro-3-methylsulfonyl-1,3,2- benzoxazaphospholes 22, 23 and 24 is reported. Their reactivities have been investigated using a variety of acid catalyst under conditions normally employed in phosphoramidite c
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50. |
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