| 271. |
- Liu, Rong, et al.
(författare)
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Chemoenzymatic preparation of (2S,3S)- and (2R,3R)-2,3-butanediols and their esters from mixtures of d,l- and meso-diols
- 2001
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Ingår i: Tetrahedron. - 0957-4166 .- 1362-511X. ; 12:5, s. 771-778
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Tidskriftsartikel (refereegranskat)abstract
- An efficient method of preparing the pure enantiomers of 2,3-butanediol front commercially available mixtures of the d,l- and meso-isomers was developed. It furnished (2S,3S)-2.3-butanediol with > 99% e.e. and a >9.5/0.5 diastereomeric ratio and (2R,3R)-2,3-butanediol in 95% e.e. and >9.5/<5 diastereomeric ratio.
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| 272. |
- Liu, Rong, et al.
(författare)
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Preparation of the four stereoisomers of 3-bromo-2-butanol or their acetates via lipase-catalysed resolutions of the racemates derived from dl- or meso-2,3-butanediol
- 2005
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Ingår i: Tetrahedron. - : Elsevier BV. - 0957-4166 .- 1362-511X. ; 16:15, s. 2607-2611
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Tidskriftsartikel (refereegranskat)abstract
- The four stereoisomeric 3-bromo-2-butanols and/or their acetates were prepared via lipase-catalysed kinetic resolution by hydrolyses of the acetates of the (+/-)-syn- and (+/-)-anti-3-bromo-2-butanols, or via esterifications of the alc hols. The diastereomeric bromoacetates were obtained by syntheses from the dl- and meso-2,3-butanediols, respectively. On a preparative scale, the four stereoisomers, either as the free alcohols or as their acetates, were obtained in > 95% ee, and in 35-40% yield (based on the starting racemates).
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| 273. |
- Liu, Sirui, et al.
(författare)
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Design of Hygroscopic Bioplastic Products Stable in Varying Humidities
- 2023
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Ingår i: Macromolecular materials and engineering. - : Wiley. - 1438-7492 .- 1439-2054. ; 308:2
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Tidskriftsartikel (refereegranskat)abstract
- Hygroscopic biopolymers like proteins and polysaccharides suffer from humidity-dependent mechanical properties. Because humidity can vary significantly over the year, or even within a day, these polymers will not generally have stable properties during their lifetimes. On wheat gluten, a model highly hygroscopic biopolymer material, it is observed that larger/thicker samples can be significantly more mechanically stable than thinner samples. It is shown here that this is due to slow water diffusion, which, in turn, is due to the rigid polymer structure caused by the double-bond character of the peptide bond, the many bulky peptide side groups, and the hydrogen bond network. More than a year is required to reach complete moisture saturation (≈10 wt.%) in a 1 cm thick plate of glycerol-plasticized wheat gluten, whereas this process takes only one day for a 0.5 mm thick plate. The overall moisture uptake is also retarded by swelling-induced mechanical effects. Hence, hygroscopic biopolymers are better suited for larger/thicker products, where the moisture-induced changes in mechanical properties are smeared out over time, to the extent that the product remains sufficiently tough over climate changes, for example, throughout the course of a year.
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| 274. |
- Lundström, Nicole, et al.
(författare)
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Teachers’ Expectations of Learning Analytics from a Value-Based Perspective
- 2023
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Ingår i: Open Science in Engineering - Proceedings of the 20th International Conference on Remote Engineering and Virtual Instrumentation. - Cham : Springer Nature. ; , s. 811-822
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Konferensbidrag (refereegranskat)abstract
- Learning Analytics (LA) is an established field of research and practice. Yet, there is still scarce evidence of LA on improved learning and teaching. In this regard, researchers highlight a need to involve not only students but also teachers in the development of LA systems to ensure that LA is implemented effectively. Earlier research has pointed out several ethical issues that are important to consider when designing and using LA services. Ethics are interrelated with stakeholders’ values since the values represent things that are seen as important to individuals. These values are rarely considered when designing LA systems; it is problematic since it may influence the design and the implementation of effective LA solutions in a negative way. The aim of this study is therefore to explore which values teachers consider important in relation to LA systems to be used in higher education. The selected and adapted set of envisioning cards was used during an online workshop with 11 teachers. The results indicate that there are several critical values that are important for teachers in relation to LA systems, including variation, personalization, flexibility, insight, transparency, efficiency, and trust. By taking these values into consideration when designing LA systems, teachers’ needs can be better met in the setting of higher education.
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| 275. |
- Lundström, Ulla, et al.
(författare)
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Advances in understanding the podzolization process resulting from a multidisciplinary study of three coniferous forest soils in the Nordic Countries
- 2000
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Ingår i: Geoderma. - 0016-7061 .- 1872-6259. ; 94:04-feb, s. 335-353
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Tidskriftsartikel (refereegranskat)abstract
- Geochemical, mineralogical, micromorphological, microbiological, hydrochemical and hpdrological joint investigations were performed at two coniferous podzolic sites in the north of Sweden and at one in the south of Finland. Mycorrhizal fungi were found to create numerous pens (3-10-mu m diameter) in many weatherable mineral grains in the eluvial (E) horizon. During the growing season, identified low molecular weight (LMW) organic acids such as citric, shikimic, oxalic and fumaric acids comprised 0.5-5% of the DOC and 0.5-15% of the total acidity in soil solutions. Between 20% and 40% of the dissolved Al was bound to the identified LMW organic acids. Mineral dissolution via complexing LMW acids, probably exuded in part by the mycorrhiza hyphae, is likely to be a major weathering process in podzols. We found no evidence for a decreasing C/metal ratio of the migrating organo-metal complexes that could explain the precipitation of secondary Fe and AL in the illuvial (B) horizon. Instead, microbial degradation of organic ligands resulting in the release of ionic,Al and Fe to the soil solution may he an important process facilitating the formation of solid Al-SI-OH and Fe-OH phases in the podzol B horizon. However, within the B horizon transport as proto-imogilite (PI) sols might be possible. In the B horizon, the extractable,Al and Fe was predominantly inorganic. The large specific surface area (SSA) removable by oxalate extraction, the high point of zero charge salt effect (PZSE), the low cation exchange capacity (CEC) and the high sulphate exchange capacity (SEC), painted to the presence of short-range ordered variable charge phases. Imogolite type material (ITM) was indeed identified in all B horizons by IR spectroscopy and crystalline imogolite was found in the deep B horizon of one profile. Mossbauer spectroscopy indicated that Fe in the form of ferrihydrite was formed by intergrowth with an Al-Si-OH phase. The high amounts of Fe and Al transported from the O to the E horizon indicate that there could be an upward transport of these elements before they are leached to the B horizon. We hypothesize that the LMW Al complexes an transported by hyphae to the mor (O) layer, partly released and subsequently complexed by high molecular weight (HMW) acids.
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| 276. |
- Löf, Carl-Gustav
(författare)
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Connection priority power control in cellular radio systems with multicast traffic
- 1998
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Ingår i: Universal Personal Communications, 1998. ICUPC '98. IEEE 1998 International Conference on. - : IEEE. - 0780351061 ; , s. 241-245
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Konferensbidrag (refereegranskat)abstract
- The number of applications where a subset of all receivers is addressed with the same information, so called multicasting, grow in most types of communication networks. In wireless personal communication systems, an effective integration of multicast services is required both from radio resource utilization and application point of view. We propose a combined centralized power control and connection removal algorithm for cellular radio systems with multicast services, utilizing physical multicasting. The aim is to obtain acceptable signal-to-interference-ratios (SIR) in all active communication links. The numerical results show that the power control method we propose outperforms a reference system using fixed transmitter power.
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| 277. |
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| 278. |
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| 279. |
- Magnuson, Martin, et al.
(författare)
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Competition between decay and dissociation of core-excited carbonyl sulfide studied by x-ray scattering
- 1999
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - 1050-2947 .- 1094-1622. ; 59:6, s. 4281-4287
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Tidskriftsartikel (refereegranskat)abstract
- We show evidence of dissociation during resonant inelastic soft x-ray scattering Carbon and oxygen K-shell and sulfur L-shell resonant and nonresonant x-ray emission spectra were measured using monochromatic synchrotron radiation for excitation and ionization. After sulfur L-2,L-3-->pi*, sigma* excitation, atomic lines are observed in the emission spectra as a consequence of competition between de-excitation and dissociation. In contrast thr carbon and oxygen spectra show weaker line-shape variations and no atomic Lines. The spectra are compared to results from ab initio calculations. The discussion of the dissociation paths is based on calculated potential energy surfaces and atomic transition energies.
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| 280. |
- Mahmood, Aamir, 1980-, et al.
(författare)
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Cross-Layer Optimization of Wireless Links under Reliability and Energy Constraints
- 2018
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Ingår i: IEEE Wireless Communications and Networking Conference, WCNC. - New York : IEEE. - 9781538617342
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Konferensbidrag (refereegranskat)abstract
- The vision of connecting billions of battery operated devices to be used for diverse emerging applications calls for a wireless communication system that can support stringent reliability and latency requirements. Both reliability and energy efficiency are critical for many of these applications that involve communication with short packets which undermine the coding gain achievable from large packets. In this paper, we study a cross-layer approach to optimize the performance of low-power wireless links. At first, we derive a simple and accurate packet error rate (PER) expression for uncoded schemes in block fading channels based on a new proposition that shows that the waterfall threshold in the PER upper bound in Nakagami-m fading channels is tightly approximated by the m-th moment of an asymptotic distribution of PER in AWGN channel. The proposed PER approximation establishes an explicit connection between the physical and link layers parameters, and the packet error rate. We exploit this connection for cross-layer design and optimization of communication links. To this end, we propose a semi-analytic framework to jointly optimize signal-to-noise ratio (SNR) and modulation order at physical layer, and the packet length and number of retransmissions at link layer with respect to distance under the prescribed delay and reliability constraints.
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