| 841. |
- Gorska, M., et al.
(författare)
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Evolution of the N=82 Shell Gap below 132Sn Inferred from Core Excited States in 131In
- 2009
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Ingår i: Physics Letters. Section B: Nuclear, Elementary Particle and High-Energy Physics. - : Elsevier BV. - 0370-2693 .- 1873-2445. ; 672:4-5, s. 313-316
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Tidskriftsartikel (refereegranskat)abstract
- The gamma-ray decay of ail excited state in In-131, the one proton hole neighbor of the doubly magic (132)sn has been measured. A high-spin, core-excited isomer with T-1/2 = 630(60) us was identified following production by both relativistic fragmentation of a Xe-136 beam and fission Of a U-238 beam. This state deexcites by a single gamma-ray branch of 3782(2) keV from which direct evidence for the size of the N = 82 shell gal) is inferred. The results are discussed in comparison to a shell-model Calculation including configurations across the closed shells at N = 82 and Z = 50. (C) 2009 Elsevier B.V. All rights reserved.
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| 842. |
- Gouttevin, I., et al.
(författare)
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A two-layer canopy model with thermal inertia for an improved snowpack energy balance below needleleaf forest (model SNOWPACK, version 3.2.1, revision 741)
- 2015
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Ingår i: Geoscientific Model Development. - : Copernicus GmbH. - 1991-959X .- 1991-9603. ; 8:8, s. 2379-2398
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Tidskriftsartikel (refereegranskat)abstract
- A new, two-layer canopy module with thermal inertia as part of the detailed snow model SNOWPACK (version 3.2.1) is presented and evaluated. As a by-product of these new developments, an exhaustive description of the canopy module of the SNOWPACK model is provided, thereby filling a gap in the existing literature. In its current form, the two-layer canopy module is suited for evergreen needleleaf forest, with or without snow cover. It is designed to reproduce the difference in thermal response between leafy and woody canopy elements, and their impact on the underlying snowpack or ground surface energy balance. Given the number of processes resolved, the SNOWPACK model with its enhanced canopy module constitutes a sophisticated physics-based modeling chain of the continuum going from atmosphere to soil through the canopy and snow. Comparisons of modeled sub-canopy thermal radiation to stand-scale observations at an Alpine site (Alptal, Switzerland) demonstrate improvements induced by the new canopy module. Both thermal heat mass and the two-layer canopy formulation contribute to reduce the daily amplitude of the modeled canopy temperature signal, in agreement with observations. Particularly striking is the attenuation of the nighttime drop in canopy temperature, which was a key model bias. We specifically show that a single-layered canopy model is unable to produce this limited temperature drop correctly. The impact of the new parameterizations on the modeled dynamics of the sub-canopy snowpack is analyzed. The new canopy module yields consistent results but the frequent occurrence of mixed-precipitation events at Alptal prevents a conclusive assessment of model performance against snow data. The new model is also successfully tested without specific tuning against measured tree temperature and biomass heatstorage fluxes at the boreal site of Norunda (Sweden). This provides an independent assessment of its physical consistency and stresses the robustness and transferability of the chosen parameterizations. The SNOWPACK code including the new canopy module, is available under Gnu General Public License (GPL) license and upon creation of an account at https://models.slf.ch/.
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| 843. |
- Graves, Alex, et al.
(författare)
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An experimental and theoretical investigation on Ti-5553/WC-Co(6%) chemical interactions during machining and in diffusion couples
- 2023
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Ingår i: Wear. - : Elsevier BV. - 0043-1648 .- 1873-2577. ; 516-517, s. 204604-
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Tidskriftsartikel (refereegranskat)abstract
- Chemical interactions that drive crater wear in turning are often studied using diffusion couples where the tool and workpiece are fixed. In contrast, in actual turning, there is a constant supply of new workpiece material at the tool-chip interface. In this work, diffusion simulations of a WC-Co(6%) and Ti-5Al-5V system were conducted, with constant replenishment of titanium at the interface (open system) and a fixed amount of material (closed system). The simulations showed that the formation of W(bcc), ry-phase, and TiC is dependent on the activity of C and the permeability of Co and C in titanium. Scanning and transmission electron microscopy-based techniques were used to analyse a Ti-5Al-5V-5Mo-3Cr and WC-Co(6%) diffusion couple and a worn WC-Co(6%) insert. The sequence of phases in the closed system simulation was similar to that observed in the diffusion couple. The open system simulation indicated that W(bcc) can form at WC-WC boundaries (where Co is low) within the subsurface of a WC-Co(6%) that has adhered titanium, and at the WC/Ti interface. Additionally, high densities of stacking faults and dislocations were found within subsurface WC grains, indicating a significant reduction of the tool's integrity.
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| 844. |
- Greger, Henriksson, 1963-, et al.
(författare)
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Uncertainty regarding waste handling in everyday life
- 2010
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Ingår i: Sustainability. - : MDPI AG. - 2071-1050. ; 2:9, s. 2799-2813
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Tidskriftsartikel (refereegranskat)abstract
- According to our study, based on interviews with households in a residential area in Sweden, uncertainty is a cultural barrier to improved recycling. Four causes of uncertainty are identified. Firstly, professional categories not matching cultural categories—people easily discriminate between certain categories (e.g., materials such as plastic and paper) but not between others (e.g., packaging and “non-packaging”). Thus a frequent cause of uncertainty is that the basic categories of the waste recycling system do not coincide with the basic categories used in everyday life. Challenged habits—source separation in everyday life is habitual, but when a habit is challenged, by a particular element or feature of the waste system, uncertainty can arise. Lacking fractions—some kinds of items cannot be left for recycling and this makes waste collection incomplete from the user’s point of view and in turn lowers the credibility of the system. Missing or contradictory rules of thumb—the above causes seem to be particularly relevant if no motivating principle or rule of thumb (within the context of use) is successfully conveyed to the user. This paper discusses how reducing uncertainty can improve recycling.
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| 845. |
- Gremel, Gabriela, et al.
(författare)
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A systematic analysis of commonly used antibodies in cancer diagnostics
- 2014
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Ingår i: Histopathology. - : Wiley. - 0309-0167 .- 1365-2559. ; 64:2, s. 293-305
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Tidskriftsartikel (refereegranskat)abstract
- AimsImmunohistochemistry plays a pivotal role in cancer differential diagnostics. To identify the primary tumour from a metastasis specimen remains a significant challenge, despite the availability of an increasing number of antibodies. The aim of the present study was to provide evidence-based data on the diagnostic power of antibodies used frequently for clinical differential diagnostics. Methods and resultsA tissue microarray cohort comprising 940 tumour samples, of which 502 were metastatic lesions, representing tumours from 18 different organs and four non-localized cancer types, was analysed using immunohistochemistry with 27 well-established antibodies used in clinical differential diagnostics. Few antibodies, e.g. prostate-specific antigen and thyroglobulin, showed a cancer type-related sensitivity and specificity of more than 95%. A majority of the antibodies showed a low degree of sensitivity and specificity for defined cancer types. Combinations of antibodies provided limited added value for differential diagnostics of cancer types. ConclusionsThe results from analysing 27 diagnostic antibodies on consecutive sections of 940 defined tumours provide a unique repository of data that can empower a more optimal use of clinical immunohistochemistry. Our results highlight the benefit of immunohistochemistry and the unmet need for novel markers to improve differential diagnostics of cancer.
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| 846. |
- Grespi, A., et al.
(författare)
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Probing the electrode-liquid interface using operando total-reflection X-ray absorption spectroscopy
- 2024
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Ingår i: Surface Science. - : Elsevier B.V.. - 0039-6028 .- 1879-2758. ; 748
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Tidskriftsartikel (refereegranskat)abstract
- Traditional methods to study electrochemical (EC) processes, although successful, are based on current/voltage measurements, providing information about performances rather than offering a direct observation of chemical and structural changes occurring at the electrode surface. These processes are localized at the electrode-electrolyte interface, the structure of which is the main determinant of their behavior, but most surface sensitive experimental techniques are limited to ex situ conditions, owing to the need for an ultra-high vacuum environment. In this contribution, we report operando X-ray absorption spectroscopy in total external reflection geometry (Refle-XAFS) at P64 beamline (DESY, Hamburg), using a simple and versatile EC flow cell designed for multimodal surface sensitive studies with hard X-ray scattering and spectroscopy techniques. We show that the Refle-XAFS method can be used to study chemical surface changes of industrial alloys and model electrodes in harsh electrochemical environments, without being limited to thin film samples. The surface passive film development and breakdown of a corrosion-resistant Ni-Cr-Mo alloy and the electro-oxidation of polycrystalline gold (poly-Au), relevant for fundamental studies on water electrolysis, were investigated. Despite the strong attenuation of the beam by the electrolyte and the PEEK walls of the EC cell, nanoscale surface oxide films were detected using beam energies down to 8 keV. The passivity breakdown region of Ni alloy 59 in 1 M NaCl at pH 7 and pH 12 was identified, showing differences in the composition of the surface oxides during anodic polarization. The electro-oxidation of poly-Au in 0.05 M H2SO4 was observed, showing a progression from two-dimensional Au1+/3+ to three-dimensional thick Au3+ surface oxide/hydroxide during OER.
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| 847. |
- Grosshans, Holger, et al.
(författare)
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Computational sensitivity study of spray dispersion and mixing on the fuel properties in a gas turbine combustor
- 2017
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Ingår i: Fluid Dynamics Research. - : Institute of Physics Publishing (IOPP). - 0169-5983 .- 1873-7005. ; 49:2
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Tidskriftsartikel (refereegranskat)abstract
- A swirl stabilized gas turbine burner has been simulated in order to assess the effects of the fuel properties on spray dispersion and fuel-air mixing. The properties under consideration include fuel surface tension, viscosity and density. The turbulence of the gas phase is modeled applying the methodology of large eddy simulation whereas the dispersed liquid phase is described by Lagrangian particle tracking. The exchange of mass, momentum and energy between the two phases is accounted for by two-way coupling. Bag and stripping breakup regimes are considered for secondary droplet breakup, using the Reitz-Diwakar and the Taylor analogy breakup models. Moreover, a model for droplet evaporation is included. The results reveal a high sensitivity of the spray structure to variations of all investigated parameters. In particular, a decrease in the surface tension or the fuel viscosity, or an increase in the fuel density, lead to less stable liquid structures. As a consequence, smaller droplets are generated and the overall spray surface area increases, leading to faster evaporation and mixing. Furthermore, with the trajectories of the small droplets being strongly influenced by aerodynamic forces (and less by their own inertia), the spray is more affected by the turbulent structures of the gaseous phase and the spray dispersion is enhanced.
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| 848. |
- Grosshans, Holger, et al.
(författare)
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Enhanced liquid-gas mixing due to pulsating injection
- 2015
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Ingår i: Computers & Fluids. - : Elsevier BV. - 0045-7930 .- 1879-0747. ; 107, s. 196-204
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Tidskriftsartikel (refereegranskat)abstract
- This paper considers the effects of intermittent injection of a liquid jet or spray on the initial break-up and mixing of one fluid with the surrounding ambient fluid. The aim of the analysis is to describe the physical process and indicate the mechanisms that control the mixing under different flow conditions (time-dependent injection and its frequency relative to the time scales of the flow) and fluid properties (density ratio), Schmidt number for a single phase case which is studied for comparison, or the Weber number for the two-phase cases. The computations use Large Eddy Simulation (LES) to account for turbulence, and either Volume Of Fluid (VOF) for the initial break-up or Lagrangian Particle Tracking (LPT) with droplet break-up model in the case of liquid droplets injected into the ambient gas. The results show that, depending on the physical properties of the liquid and ambient gas, the initial break-up and turbulent mixing can be enhanced substantially with intermittent injection. The numerical modeling is validated by recovering key results of experimental and analytical works. It can be observed that a main effect during the mixing is the suction of ambient fluid at the tail of the injected liquid, which depends on the fluid properties. Increased injection frequency shows to increase the mixing significantly during the initial transient phase.
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| 849. |
- Grosshans, H., et al.
(författare)
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Sensitivity of VOF simulations of the liquid jet breakup to physical and numerical parameters
- 2016
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Ingår i: Computers & Fluids. - : Elsevier. - 0045-7930 .- 1879-0747. ; 136, s. 312-323
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Tidskriftsartikel (refereegranskat)abstract
- In this paper the characteristics of the primary breakup of a liquid jet is analyzed numerically. We applied the Volumes of Fluids (VOF) approach utilizing the Direction Averaged Curvature (DAC) model, to estimate the interface curvature, and the Direction Averaged Normal (DAN) model, to propagate the interface. While being used for the first time to predict liquid atomization, this methodology showed a high accuracy. The influence of varying the fluid properties, namely liquid-gas density and viscosity ratio, and injection conditions is discussed related to the required grid resolution. Resulting droplet sizes are compared to distributions obtained through the One-Dimensional Turbulence (ODT) model.
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| 850. |
- Grønberg, Christina, et al.
(författare)
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Membrane Anchoring and Ion-Entry Dynamics in P-type ATPase Copper Transport
- 2016
-
Ingår i: Biophysical Journal. - : Elsevier. - 0006-3495 .- 1542-0086. ; 111:11, s. 2417-2429
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Tidskriftsartikel (refereegranskat)abstract
- Cu+-specific P-type ATPase membrane protein transporters regulate cellular copper levels. The lack of crystal structures in Cu+-binding states has limited our understanding of how ion entry and binding are achieved. Here, we characterize the molecular basis of Cu+ entry using molecular-dynamics simulations, structural modeling, and in vitro and in vivo functional assays. Protein structural rearrangements resulting in the exposure of positive charges to bulk solvent rather than to lipid phosphates indicate a direct molecular role of the putative docking platform in Cu+ delivery. Mutational analyses and simulations in the presence and absence of Cu+ predict that the ion-entry path involves two ion-binding sites: one transient Met148-Cys382 site and one intramembranous site formed by trigonal coordination to Cys384, Asn689, and Met717. The results reconcile earlier biochemical and x-ray absorption data and provide a molecular understanding of ion entry in Cu+-transporting P-type ATPases.
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