| 1. |
- Larsson, Per, et al.
(författare)
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An attempt to measure the flow of chlorinated hydrocarbons, such as PCBs, from water to air in the field
- 1987
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Ingår i: Environmental Pollution. - : Elsevier BV. - 0269-7491 .- 1873-6424. ; 44:3, s. 219-225
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Tidskriftsartikel (refereegranskat)abstract
- A field sampling device to study the transport of aromatic, persistent chlorinated hydrocarbons from water to air was constructed. It was tested in large, outdoor artificial ponds contaminated with polychlorinated biphenyls (PCBs). The PCB compounds volatilised to air at a rate of 0·9 to 9·6 ng m−2 h−1 depending on levels of PCBs in the water and water temperature.
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| 2. |
- Larsson, Per, et al.
(författare)
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Factors determining the uptake of persistent pollutants in an eel population (Anguilla anguilla L.) of a eutrophic lake
- 1991
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Ingår i: Environmental Pollution. - 0269-7491 .- 1873-6424. ; 69:1, s. 39-50
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Tidskriftsartikel (refereegranskat)abstract
- The distribution of persistent pollutants in an eel population from a eutrophic lake of southern Scandinavia was examined. The origin of PCBs, DDT, DDE and lindane found in the fish was most likely the atmosphere. The most important factors for uptake of the chlorinated hydrocarbons was age (exposure time), growth rate and fat content. The life cycle of the eel is unique with a stage in freshwater when energy reserves (fat stored in muscular tissue) and lipophilic pollutants are accumulated. This stage is followed by a long migration to the spawning areas in the Sargasso Sea when pollutants are released from the fat deposits. These two stages followed by a once-in-a-lifetime spawning behaviour, makes the eel especially vulnerable to persistent pollutants. The effects of persistent pollutants combined with the eel's unusual life cycle may explain the decline in the eel population in northern Europe in recent decades.
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| 3. |
- Bidleman, TF, et al.
(författare)
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Chiral pesticides as tracers of air-surface exchange
- 1998
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Ingår i: Environmental Pollution. - 0269-7491 .- 1873-6424. ; 102:1, s. 43-49
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Tidskriftsartikel (refereegranskat)abstract
- The enantiomers of chiral pesticides are selectively broken down in soil and water to yield residues and metabolites, which are non-racemic. The distinctive enantiomer signatures of residues are preserved upon volatilization, providing site-specific tracers for air-soil and air-water exchange. Applications of enantiomeric tracers include distinguishing the atmospheric transport of freshly applied pesticides from those which are 'recycled' from lakes, oceans and soil, and investigating biotic vs abiotic degradation pathways. Examples are given of using pesticide enantiomers to follow volatilization from the Great Lakes and arctic waters and as indicators of pesticide emissions from agricultural soils.
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| 4. |
- Bignert, Anders, et al.
(författare)
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Temporal trends of organochlorines in Northern Europe, 1967–1995. Relation to global fractionation, leakage from sediments and international measures
- 1998
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Ingår i: Environmental Pollution. - 0269-7491 .- 1873-6424. ; 99:2, s. 177-198
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Tidskriftsartikel (refereegranskat)abstract
- The time trend monitoring of organochlorine pollution was carried out in Sweden since the late 1960s. This report presents data on concentrations of DDT, PCB, HCHs and HCB in biota samples collected and analysed annually. All the matrices and compounds studied show a significant decrease over time. The data cover severely polluted Swedish marine and fresh water in southern Sweden as well as locally unpolluted waters in remote northern Arctic regions of Sweden. A total of 13 time series representing different locations and species are presented for the different pollutants. The period studied covers the time when pollution was serious as well as the time of recovery. All monitoring activities were carried out at the same laboratories over the entire study period, which means that comparability over time is good in the sets of data presented. The various time trends show a convincing agreement with trends and annual change over time, although the concentrations differ between the species and locations investigated, the highest concentrations being in the south. Since the annual changes are normally similar regardless of locations and species, spatial variations in concentrations remain over time, although concentrations are lower today. The onset of changes in concentrations over time can be related to international measures or other circumstances that lowered releases into the environment. Similarities in the annual changes, as well as the time when changes began, are discussed with respect to suggested hypotheses on the fate of the investigated organochlorines. It was not possible to verify that the oxygenation of anoxic sediments mobilised old pollution in Baltic sediments. Neither was it possible to conclude that eutrophication has caused a measurable effect on the rate and timing of the decreases. Finally, long-range transport to Arctic regions seems to be due more to a one step transport than to the ‘Grass-hopper’ effect. The comprehensive database used, clearly shows how important it is to have datasets big enough to describe between-year variation before attempting to evaluate the time trend. In addition, if between-year variation is not known, it is then also difficult to evaluate spatial variation on the basis of single year observations.
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| 5. |
- Karlen, C., et al.
(författare)
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Runoff rates, chemical speciation and bioavailability of copper released from naturally patinated copper
- 2002
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Ingår i: Environmental Pollution. - 0269-7491 .- 1873-6424. ; 120:3, s. 691-700
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Tidskriftsartikel (refereegranskat)abstract
- The release of copper, induced by atmospheric corrosion, from naturally patinated copper of varying age (0 and 30 years) has been investigated together with its potential ecotoxic effect. Results were generated in an interdisciplinary research effort in which corrosion science and ecotoxicology aspects were combined. The aim of the investigation was to elucidate the situation when copper-containing rainwater leaves a roof in terms of runoff rate, chemical speciation, bioavailability and ecotoxicity effects. Data have been collected during a three-year field exposure conducted in the urban environment of Stockholm, Sweden. The potential environmental effects have been evaluated using a combination of a copper specific biosensor test with the bacterium Alcaligenes eutrophus and the conventional 72-h growth inhibition test with the green alga Raphidocelis subcapitata. The results show annual runoff rates between 1.0 and 1.5 g/m(2) year for naturally patinated copper of varying age. The runoff rate increased slightly with patina age, which mainly is attributed to the enhanced first flush effect observed on thicker patina layers. The total copper concentration in investigated runoff samplings ranged from 0.9 to 9.7 mg/l. Both computer modeling and experimental studies revealed that the majority (60-100%) of released copper was present as the free hydrated cupric ion, Cu(H2O)(6)(2+), the most bioavailable copper species. However, other copper species in the runoff water, such as, e.g. Cu(OH)(+) and CU2(OH)(2)(2+), were also bioavailable. The copper-containing runoff water, sampled directly after release from the roof, caused significant reduction in growth rate of the green alga. It should be emphasized that the results describe the runoff situation immediately after release from the copper roof and not the real environmental ecotoxicity. Therefore the data should only be used as an initial assessment of the potential environmental effect of copper runoff from building applications. Future risk assessments should also consider dilution effects of copper, changes in its chemical speciation and bioavailability during environmental entry, and type and sensitivity of the receiving ecosystem.
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| 6. |
- Larsson, Per, et al.
(författare)
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Animals need not to be killed to reveal their body-burdens of chlorinated hydrocarbons
- 1987
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Ingår i: Environmental Pollution. - : Elsevier BV. - 0269-7491 .- 1873-6424. ; 45:1, s. 73-78
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Tidskriftsartikel (refereegranskat)abstract
- The levels of persistent, lipophilic pollutants in different organs and body-fluids of birds are governed by partitioning, i.e. the levels are correlated. This implies that it may be possible to estimate the total body-burden of chlorinated hydrocarbons, without sacrificing the animals, by examining the levels in secretory fluid. This hypothesis was tested on the goosander, a fish-eating waterfowl. We found that levels of PCB and DDE in secretions from the uropyginal gland were linearly related to levels in the breast muscle. Thus, by estimating the amounts of persistent pollutants in water-repellent secretions, the total body-burden could be calculated.
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| 7. |
- Lin, Zhixun, et al.
(författare)
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The chemical and mineralogical behavior of Pb in shooting range soils from central sweden
- 1995
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Ingår i: Environmental Pollution. - : Elsevier. - 0269-7491 .- 1873-6424. ; 89:3, s. 303-309
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Tidskriftsartikel (refereegranskat)abstract
- Recently investigations have shown that the annual flux of lead from shotgun pellets to shooting range soils is significant in some countries. This paper presents the data of chemical and mineralogical analyses of soils and Pb-pellet crusts from five shooting ranges in Sweden and, based on these results, evaluates the retention of lead in these shooting range soils. In the soils, Pb-pellets and bullets are readily decomposed and transformed to crust materials composed of Pb-bearing minerals. The transformation products in the crust materials, identified by X-ray diffraction, are predominantly hydrocerussite [Pb3(CO3)2 (OH)2], associated with cerussite (PbCO3) and anglesite (PbSO4). In a period of 20–25 years, an average of 4·8% metallic lead in the pellets has been transformed to lead carbonate and lead sulphate, where the former is the more stable mineral in the surface environment. However, in soils relatively rich in humus an average of 15·6% metallic lead in the pellets was transformed to secondary lead compounds in the same period. The results of the chemical analyses indicate that Pb is rather immobile in the soil profile. The surficial horizon contains higher concentrations of lead (52–3400 mg kg−1), while lower concentrations of lead were found in the E and B horizons where the total Pb concentrations (8–37 mg kg−1) are within about one standard deviation of the mean reference sample concentration. An inverse relationship is revealed between the aluminium hydroxide content of the soil fraction and EDTA-extractable Pb, which suggests that these compounds have affected the retention of lead.
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| 8. |
- Lundgren, Kjell, et al.
(författare)
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Flux estimates and sedimentation of polychlorinated naphthalenes in the northern part of the Baltic sea
- 2003
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Ingår i: Environmental Pollution. - 0269-7491 .- 1873-6424. ; 126:1, s. 93-105
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Tidskriftsartikel (refereegranskat)abstract
- The concentrations and fluxes of polychlorinated naphthalenes (PCNs) were measured in surface sediments, and settling particulate matter collected in sediment traps, at two coastal and two offshore sampling stations in the Gulf of Bothnia, northern Baltic Sea, Sweden. The PCN concentrations (of tetra- to hepta-chloro congeners) in the surface sediments ranged from 0.27 to 2.8 ng/g dry weight and were of the same order of magnitude as background concentrations reported previously in Europe. The PCN fluxes in the southern basin (0.93 and 0.86 μg/m2/year) of the Gulf of Bothnia were higher than those in the northern basin (0.58 and 0.49 μg/m2/year); they were also higher near the coast than in the open sea. These PCN fluxes are similar to the pre-industrial levels determined from lake sediments in northwest England. The PCN homologue distribution changed from a relatively even distribution in samples collected near the coast, to TeCNs dominating in the samples from the open sea. This indicates that higher chlorinated PCNs are deposited and retained in sediments to a higher degree near the coast. The total annual deposition of PCNs in sediments in the Gulf of Bothnia was estimated to be 91 kg/year. Background concentrations in sediments, fluxes and annual sedimentation rates of polychlorinated naphthalenes were measured and estimated at two coastal and two offshore remote sampling stations in the Gulf of Bothnia, northern Baltic Sea.
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| 9. |
- Markkola, A M, et al.
(författare)
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Scots pine responses to CO2 enrichment--I. Ectomycorrhizal fungi and soil fauna.
- 1996
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Ingår i: Environmental Pollution. - : Elsevier. - 0269-7491 .- 1873-6424. ; 94:3, s. 309-16
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Tidskriftsartikel (refereegranskat)abstract
- Ectomycorrhizal Scots pine seedlings were grown in unfertilized forest soil at ambient and double (ca 700 ppm) atmospheric concentrations of CO2. The biomass of seedlings and fungal biomass both in the roots and in the soil and the numbers of certain groups of soil animals were measured under summer conditions and after an artificial winter acclimation period. No biomass parameter showed any significant change due to CO2 elevation. Increases were found during the winter acclimation period in total and fine root biomasses, fungal biomass in the soil and total fungal biomass both in the roots and in the soil, while the ratio of needle biomass: fungal biomass and the shoot: root ratio decreased. The N concentration in previous-year needles was lower in the double CO2 environment than with ambient CO2. Enchytraeids almost disappeared in the double CO2 environment during winter acclimation, while the numbers of nematodes increased at the same time in both treatments.
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| 10. |
- Markkola, A. M, et al.
(författare)
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Shift in ectomycorrhizal community composition in Scots pine (Pinus sylvestris L.) seedling roots as a response to nickel deposition and removal of lichen cover
- 2002
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Ingår i: Environmental Pollution. - : Elsevier. - 0269-7491 .- 1873-6424. ; 120:3, s. 797-803
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Tidskriftsartikel (refereegranskat)abstract
- Scots pine seedlings were exposed to wet-deposited nickel (Ni) and removal of lichen cover in a dry heath Scots pine forest. Ni deposition affected the colonization of roots by indigenous ectomycorrhizal fungi in contrasting ways in intact and skimmed quadrats. Highest frequencies of tubercle morphotypes of ectomycorrhiza were found in quadrats exposed to 100 mg m-2 year-1 Ni in lichen covered treatment, while in skimmed quadrats these peaked after the treatment with 10 mg Ni m-2 year-1. Removal of the lichen layer increased the value of diversity index (H′) of ectomycorrhizal fungal community, probably due to the increase in the evenness of the morphotype distribution. Lichen removal seemed also to improve the condition of the short roots, as the frequencies of poor and senescent short roots were decreased by the removal.
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