| 1. |
- Thomas, HS, et al.
(författare)
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- 2019
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swepub:Mat__t
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| 2. |
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| 3. |
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| 4. |
- Andersson, Mats R., et al.
(författare)
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Improved photoluminescence efficiency of films from conjugated polymers
- 1997
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Ingår i: Synthetic metals. - : Elsevier. - 0379-6779 .- 1879-3290. ; 85:1-3, s. 1383-1384
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Tidskriftsartikel (refereegranskat)abstract
- We have demonstrated two general ways to increase the photoluminescence efficiency of films from conjugated polymers. One is to disperse the conjugated polymer on a molecular level by using attractive forces between the conjugated polymer and the matrix. The other method is to substitute the conjugated polymer with side chains which separates the conjugated backbones. Using this idea a new poly(thiophene) with a photoluminescence efficiency of 16% in films has been prepared. LEDs from this polymer exhibit an external efficiency of 0.1% for single layer and 0.7% for double layer diodes.
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| 5. |
- Andersson, Mats R., et al.
(författare)
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Electroluminescence from Substituted Poly(thiophenes) : From Blue to Near-Infrared
- 1995
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Ingår i: Macromolecules. - : American Chemical Society. - 0024-9297 .- 1520-5835. ; 28:22, s. 7525-7529
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Tidskriftsartikel (refereegranskat)abstract
- We report a systematic approach to the control of the conjugation length along the poly(thiophene) backbone. The planarity of the main chain can be permanently modified by altering the pattern of substitution and character of the substituents on the poly(thiophene) chain, and the conjugation length is thus modified. We obtain blue, green, orange, red, and near-infrared electroluminescence from four chemically distinct poly(thiophenes). The external quantum efficiencies are in the range of 0.01-0.6%.
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| 6. |
- Andersson, Mats R., et al.
(författare)
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Regioselective polymerization of 3-(4-octylphenyl)thiophene with FeCl3
- 1994
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Ingår i: Macromolecules. - : American Chemical Society. - 0024-9297 .- 1520-5835. ; 27:22, s. 6503-6506
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Tidskriftsartikel (refereegranskat)abstract
- We have shown that it is possible to regioselectively polymerize 3-(4-octylphenyl) thiophene with FeCl3. Adding FeCl3 slowly to the monomer leads to a soft and therefore regioselective polymerization. The head-to-tail content was determined by H-1 NMR to be 94 +/- 2%. Thin films of the polymer treated with chloroform vapor have an absorption maximum at 602 nm (2.06 eV) with clear vibronic fine structure. Free standing films have a conductivity of 4 S/cm, which is 100 times higher than for earlier prepared poly(3-(4-octylphenyl)thiophene). A mechanism for the regioregular polymerization is also proposed.
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| 7. |
- Andersson, Mats R., et al.
(författare)
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Synthesis of poly(alkylthiophenes) for light-emitting diodes
- 1995
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Ingår i: Synthetic metals. - : Elsevier. - 0379-6779 .- 1879-3290. ; 71:1-3, s. 2183-2184
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Tidskriftsartikel (refereegranskat)abstract
- We have demonstrated a general way to tune the emission of poly(alkylthiophenes) by using steric interaction between the repeating units. Light-emitting diodes prepared of the polymers have blue to near-infrared emission.
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| 8. |
- Berggren, Magnus, et al.
(författare)
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Controlling inter-chain and intra-chain excitations of a poly(thiophene) derivative in thin films
- 1999
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Ingår i: Chemical Physics Letters. - : Elsevier. - 0009-2614 .- 1873-4448. ; 304:1-2, s. 84-90
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Tidskriftsartikel (refereegranskat)abstract
- The decay of photoexcitations in polythiophene chains has been studied in solid solutions of the polymer from room temperature to 4 K. A strong blue shift of the emission spectrum is observed in the polymer blend, as compared to the homopolymer. Dispersion of the polythiophene suppresses the non-radiative processes, which are suggested to be correlated to close contacts of polymer chains. Quantum chemistry modeling of the excited state distributed on two chains corroborate this conclusion.
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| 9. |
- Berggren, Magnus, et al.
(författare)
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Light-emitting diodes with variable colours from polymer blends
- 1994
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Ingår i: Nature. - : Nature Publishing Group. - 0028-0836 .- 1476-4687. ; 372:6505, s. 444-446
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Tidskriftsartikel (refereegranskat)abstract
- THE range of materials now available for polymer-based light-emitting diodes (LEDs) is such that electroluminescence can be obtained throughout the visible spectrum(1-12). Here we show that, by blending polymers with different emission and charge-transport characteristics, LEDs can be fabricated in which the emission colour varies as a function of the operating voltage. This phenomenon arises from the self-organizing properties of the blends, in which entropy drives phase separation of the constituent polymers and gives rise to submicrometre-sized domains having a range of compositions and emission characteristics. Emission from domains of different composition is controlled by the ease with which charge is injected, which in turn depends on the applied voltage.
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| 10. |
- Berggren, Magnus, et al.
(författare)
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White light from an electroluminescent diode made from poly[3(4‐octylphenyl)‐2,2′‐bithiophene] and an oxadiazole derivative
- 1994
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Ingår i: Journal of Applied Physics. - : American Institute of Physics (AIP). - 0021-8979 .- 1089-7550. ; 76:11, s. 7530-7534
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Tidskriftsartikel (refereegranskat)abstract
- We report on an electroluminescent diode emitting red, green, and blue light simultaneously. The device is based on a thin polymer layer, poly[3‐(4‐octylphenyl)‐2,2′‐bithiophene] and a thick molecular layer, 2‐(4‐biphenylyl)‐5‐(4‐tertbutyl‐phenyl)1,3,5‐oxadiazole. The quantum efficiency for light conversion is 0.3% and the turn‐on voltage for light emission is 7 V. In this article we present electric and spectroscopic characterizations. A mechanism for the light emission, based on electron and hole recombination between the two organic layers, is proposed
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