| 1. |
- Almjashev, V.I., et al.
(författare)
-
Eutectic crystallization in the FeO(1.5)-UO(2+x)-ZrO(2) system
- 2009
-
Ingår i: Journal of Nuclear Materials. - : Elsevier BV. - 0022-3115 .- 1873-4820. ; 389:1, s. 52-56
-
Tidskriftsartikel (refereegranskat)abstract
- Results of the investigation of the FeO(1.5)-UO(2+x)-ZrO(2) system in air are presented. The eutectic position and the content of the phases crystallized at this point have been determined. The temperature and the composition of the ternary eutectic are 1323 +/- 7 degrees C and 67.4 +/- 1.0 FeO(1.5), 30.5 +/- 1.0 UO(2+x), 2.1 +/- 0.2 ZrO(2) mol.%, respectively. The solubilities of FeO(1.5) and ZrO(2) in the UO(2+x)(FeO(1.5), ZrO(2)) solid solution correspond to respectively 3.2 and 1.1 mol.%. The solubilities of UO(2) and ZrO(2) in FeO(1.5) are not significant. The existence of a solid solution on the basis of U(Zr)FeO(4) compound is found. The ZrO(2) Solubility in this solid solution is 7.0 mol.%.
|
|
| 2. |
- Almjashev, V.I., et al.
(författare)
-
Phase equilibria in the FeO(1+x)-UO(2)-ZrO(2) system in the FeO(1+x)-enriched domain
- 2010
-
Ingår i: Journal of Nuclear Materials. - : Elsevier BV. - 0022-3115 .- 1873-4820. ; 400:2, s. 119-126
-
Tidskriftsartikel (refereegranskat)abstract
- Experimental results of the investigation of the FeO(1+x)UO(2)-ZrO(2) system in neutral atmosphere are presented. The ternary eutectic position and the composition of the phases crystallized at this point have been determined. The phase diagram is constructed for the FeO(1+x)-enriched region and the onset melting temperature of 1310 degrees C probably represents a local minimum and so will be a determining factor in this system and its application to safety studies in nuclear reactors.
|
|
| 3. |
- Almjashev, V.I., et al.
(författare)
-
Ternary eutectics in the systems FeO-UO2-ZrO2 and Fe2O3-U3O8-ZrO21
- 2011
-
Ingår i: Radiochemistry. - 1066-3622. ; 53:1, s. 13-18
-
Tidskriftsartikel (refereegranskat)abstract
- The systems FeO–UO2–ZrO2 (in inert atmosphere) and Fe2O3–U3O8–ZrO2 (in air) were studied. Forthe FeO–UO2–ZrO2 system, the eutectic temperature was found to be 1310°С, with the following componentconcentrations (mol %): 91.8 FeO, 3.8 UO2, and 4.4 ZrO2. For the Fe2O3–U3O8–ZrO2 system, the eutectictemperature was found to be 1323°С, with the following component concentrations (mol %): 67.4 FeO1.5,30.5 UO2.67, and 2.1 ZrO2. The solubility limits of iron oxides in the phases based on UO2(ZrO2,FeO) andUO2.67(ZrO2,FeO1.5) were determined
|
|
| 4. |
- Bechta, Sevostian, et al.
(författare)
-
CORPHAD and METCOR ISTC projects
- 2005
-
Ingår i: Proceedings of The first European Review Meeting on Severe Accident Research (ERMSAR-2005).
-
Konferensbidrag (refereegranskat)abstract
- The ongoing CORPHAD Project (Phase Diagrams for Multicomponent SystemsContaining Corium and Products of its Interaction with NPP Materials) started in August2001. The main aim of the project is to experimentally determine the relevantphysicochemical data on phase diagrams of binary, ternary, quaternary and prototypic multicomponent systems, which are important for analysis and modelling of a severe accident (SA)and efficient planning of severe accident management (SAM) measures. The data should bedirectly used for the European NUCLEA database development and validation. The followingsystems are in the focus of the project: (1) UO2 – FeO, (2) ZrO2 – FeO, (3) SiO2– Fe2O3, (4)UO2 – SiO2, (5) UO2 – ZrO2-FeO, (6) UO2 – ZrO2-FeOy, (7) U-O-Fe, (8) Zr-O-Fe, (9) U-OZr, (10) U-Zr-Fe-O, (11) complex corium mixtures.The experimentally determined data of the listed diagrams include: coordinates ofcharacteristic points (eutectics, peritectics and others); liquidus and solidus concentrationcurves; component solubility limits in the solid phase; tie line coordinates and temperatureconcentration regions of the miscibility gap. Different methodologies are used for the phasediagram study. Classical methods of thermal analysis, like DTA and DSC are combined withmethods specifically developed for corium studies.The METCOR project (Investigation of Corium Melt Interaction with NPP ReactorVessel Steel) started in April 1999. The objectives of the project are to qualify and to quantifyphysico-chemical phenomena of corium melt interaction with reactor vessel steel cooled fromthe outside. The variable parameters of the interaction tests are: oxygen potential in thesystem, corium composition, interaction interface temperature and heat flux from corium tosteel. The medium scale tests with corium mass of about 2 kg are carried out by using highfrequency induction heating of the corium melt in a cold crucible.The METCOR & CORPHAD work-packages are performed by Russian partners inclose collaboration with leading European scientific institutes in the area of corium researchas well as with the European nuclear industry.This paper briefly describes the results obtained in both projects and their possibleapplication for SA analysis and SAM. The paper concludes with recommendations for futureresearch activities in the framework of METCOR and CORPHAD projects.
|
|
| 5. |
- Bechta, Sevostian, et al.
(författare)
-
Corrosion of vessel steel during its interaction with molten corium : Part 2. Model development
- 2006
-
Ingår i: Nuclear Engineering and Design. - : Elsevier BV. - 0029-5493 .- 1872-759X. ; 236:13, s. 1362-1370
-
Tidskriftsartikel (refereegranskat)abstract
- An experimental examination of the cooled vessel steel corrosion during the interaction with molten corium is presented. The experiments havebeen conducted on “Rasplav-2” test facility and followed up with physico-chemical and metallographic analyses of melt samples and coriumspecimeningots. The results discussed in the first part of the paper have revealed specific corrosion mechanisms for air and inert atmosphere abovethe melt. Models have been proposed based on this information and approximate curves constructed for the estimation of the corrosion rate orcorrosion depth of vessel steel in conditions simulated by the experiments.
|
|
| 6. |
- Bechta, Sevostian, et al.
(författare)
-
Corrosion of vessel steel during its interaction with molten corium : Part 1. Experimental
- 2006
-
Ingår i: Nuclear Engineering and Design. - : Elsevier BV. - 0029-5493 .- 1872-759X. ; 236:17, s. 1810-1829
-
Tidskriftsartikel (refereegranskat)abstract
- This paper is concerned with corrosion of a cooled vessel steel structure interacting with molten corium in air and neutral (nitrogen) atmospheresduring an in-vessel retention scenario. The data on corrosion kinetics at different temperatures on the heated steel surface, heat flux densities andoxygen potential in the system are presented. The post-test physico-chemical and metallographic analyses of melt samples and the corium–specimeningot have clarified certain mechanisms of steel corrosion taking place during the in-vessel melt interaction.
|
|
| 7. |
- Bechta, Sevostian, et al.
(författare)
-
Experimental studies of oxidic molten corium-vessel steel interaction
- 2001
-
Ingår i: Nuclear Engineering and Design. - 0029-5493 .- 1872-759X. ; 210:1-3, s. 193-224
-
Tidskriftsartikel (refereegranskat)abstract
- The experimental results of molten corium-steel specimen interaction with molten corium on the 'Rasplav-2' test facility are presented. In the experiments, cooled vessel steel specimens positioned on the molten pool bottom and uncooled ones lowered into the molten pool were tested. Interaction processes were studied for different corium compositions, melt superheating and in alternative (inert and air) overlying atmosphere. Hypotheses were put forward explaining the observed phenomena and interaction mechanisms. The studies presented in the paper were aimed at the detection of different corium-steel interaction mechanisms. Therefore certain identified phenomena are more typical of the ex-vessel localization conditions than of the in-vessel corium retention. Primarily, this can be referred to the phenomena of low-temperature molten corium-vessel steel interaction in oxidizing atmosphere.
|
|
| 8. |
- Bechta, Sevostian, et al.
(författare)
-
Experimental study of interactions between suboxidized corium and reactor vessel steel
- 2006
-
Ingår i: Proceedings of the 2006 International Congress on Advances in Nuclear Power Plants, ICAPP'06. - 0894486985 - 9780894486982 ; , s. 1355-1362
-
Konferensbidrag (refereegranskat)abstract
- One of the critical factors in the analysis of in-vessel melt retention is the vessel strength. It is, in particular, sensitive to the thickness of intact vessel wall, which, in its turn, depends on the thermal conditions and physicochemical interactions with corium. Physicochemical interaction of prototypic UO2-ZrO2-Zr corium melt and VVER vessel steel was examined during the 2nd Phase of the ISTC METCOR Project. Rasplav-3 test facility was used for conducting four tests, in which the Zr oxidation degree and interaction front temperature were varied; in one of the tests, stainless steel was added to the melt. Direct experimental measurements and posttest analyses were used for determining corrosion kinetics and maximum corrosion depth (i.e. the physicochemical impact of corium on the cooled vessel steel specimens), as well as the steel temperature conditions during the interaction, and finally the structure and composition of crystallized ingots, including the interaction zone. The minimum temperature on the interaction front boundary, which determined its final position and maximum corrosion depth was ∼ 1090°C. An empirical correlation for calculation of corrosion kinetics has been derived.
|
|
| 9. |
- Bechta, Sevostian, et al.
(författare)
-
Interaction between molten corium UO2+X-ZrO2-FeO y and VVER vessel steel
- 2009
-
Ingår i: Proceeding of International Conference on Advances in Nuclear Power Plants, ICAPP 2008. - : Curran Associates, Inc.. - 9781605607870 ; , s. 210-218
-
Konferensbidrag (refereegranskat)abstract
- In case of an in-vessel corium retention (1VR) the deterioration of vessel steel properties can be caused both by the steel melting and by its physicochemical interaction with corium. The interaction behavior has been studied in the medium-scale experiments with a prototypic corium within the METCOR project. The resulting experimental data give an insight into the steel corrosion during its interaction with U02+x- Zr02- FeOy melt in air and steam. It has been observed that the corrosion rate is almost the same in air and steam atmosphere; if the temperature on the interaction interface increases beyond a certain level, corrosion intensifies, which is explained by the formation of liquid phases in the interaction zone. The available experimental data have been used for developing a correlation of corrosion rate versus temperature and heat flux.
|
|
| 10. |
- Bechta, Sevostian, et al.
(författare)
-
INTERACTION BETWEEN MOLTEN CORIUM UO2+x-ZrO2-FeOy AND VVER VESSEL STEEL
- 2010
-
Ingår i: Nuclear Technology. - : American Nuclear Society. - 0029-5450 .- 1943-7471. ; 170:1, s. 210-218
-
Tidskriftsartikel (refereegranskat)abstract
- In case of in-vessel corium retention during a severe accident in a light water reactor, weakening of the vessel wall and deterioration of the vessel steel properties can be caused both by the melting of the steel and by its physicochemical interaction with corium. The interaction behavior has been studied in medium-scale experiments with prototypic corium. The experiments yielded data for the steel corrosion rate during interaction with UO2+x-ZrO2-FeOy melt in air and steam at different steel surface temperatures and heat fluxes from the corium to the steel. It has been observed that the corrosion rates in air and steam atmosphere are almost the same. Further, if the temperature at the interface increases beyond a certain level, corrosion intensifies. This is explained by the formation of liquid phases in the interaction zone. The available experimental data have been used to develop a correlation for the corrosion rate as afunction of temperature and heat flux.
|
|
