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| 3. |
- Mansurbeg, Howri, et al.
(författare)
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Meteoric-water diagenesis in late Cretaceous canyon-fill turbidite reservoirs from the Espirito Santo Basin, eastern Brazil
- 2012
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Ingår i: Marine and Petroleum Geology. - : Elsevier BV. - 0264-8172 .- 1873-4073. ; 37:1, s. 7-26
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Tidskriftsartikel (refereegranskat)abstract
- Parameters controlling the diagenetic evolution of passive margin, marine turbidites, which are important targets of hydrocarbon exploration, are poorly constrained in the literature. This study aims to unravel the conditions of diagenesis and its impact on the reservoir quality evolution from late Cretaceous canyon-filling turbiditic sandstones of the onshore portion of Espirito Santo Basin, eastern Brazil. Kaolinization (delta O-18 = +13.3 parts per thousand to +15.2 parts per thousand; delta D = 96.6 parts per thousand to -79.6 parts per thousand) and dissolution of framework silicate grains is attributed to meteoric water incursion during eodiagenesis in response to a considerable fall in relative sea-level. Eogenetic alterations also include cementation by siderite (average delta O-18 = -72 parts per thousand; delta C-13 = +9.3 parts per thousand) and pyrite. Progressive sediment burial (present depths = 1530-2027 m) resulted in the formation of poikilotopic calcite, ferroan dolomite-ankerite (average delta O-18 = -7.9 parts per thousand; delta C-13 = +2.9 parts per thousand), minor amounts of quartz overgrowths and in partial dickitization of kaolinite. Isotopic values of calcite and dolomite-ankerite follow two trends of co-variance of delta C-13 with decreasing delta O-18 and increasing temperature. From a composition closer to marine (approximate to 0 parts per thousand), one trend goes towards positive delta C-13 values (up to +22.4 parts per thousand for calcite; +18.6 parts per thousand for dolomite-ankerite), indicating increasing input of carbonate from methanogenic fermentation. The other trend develops towards negative delta C-13 values (down to -17.2 parts per thousand for calcite; 15 parts per thousand for dolomite-ankerite), suggesting increasing contribution from thermal decarboxylation with increasing temperature and depth. Despite the presence of various cement types, mechanical compaction was more important than cementation in reducing depositional porosity in the onshore Urucutuca sandstones.
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- Morad, Sadoon, et al.
(författare)
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Hydrothermal alteration of plagioclase in granitic rocks from Proterozoic basement of SE Sweden
- 2010
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Ingår i: Geological Journal. - : Wiley. - 0072-1050 .- 1099-1034. ; 45:1, s. 105-116
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Tidskriftsartikel (refereegranskat)abstract
- Petrographic examinations and electron microprobe analyses of Proterozoic granitic rocks, SE Sweden aimed to characterize and unravel the mechanisms and conditions of plagioclase alterations. These alterations include saussuritization, albitization and replacement of plagioclase by K-feldspar. The hydrothermal alterations, which are inferred to have occurred at ca. 250-400°C, resulted in concomitant formation of Alrich titanite, epidote, calcite, pumpellyite, prehnite and iron oxides. Replacement of plagioclase by K-feldspar occurs in red-stained zones, which have developed close to thin fractures owing to the precipitation of tiny Fe-oxide pigment particles within the altered plagioclase, whereas saussuritized plagioclase has less systematic spatial relationships to these fractures. Albitization of plagioclase occurred in rocks that are poor in biotite compared to rocks that suffered extensive saussuritization. The chemical and textural characterization of various types of plagioclase alterations allows elucidation of the granitic hydrothermal systems. Features of feldspar alteration in the granitic rocks are similar to those encountered in feldspathic sandstones and should hence be considered in studies on diagenetic changes of siliciclastic successions during basin evolution.
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| 5. |
- El-Khatri, F., et al.
(författare)
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Diagenetic Alterations and Reservoir Quality Evolution of Lower Cretaceous Fluvial Sandstones : Nubian Formation, Sirt Basin, North-Central Libya
- 2015
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Ingår i: Journal of Petroleum Geology. - : Wiley. - 0141-6421 .- 1747-5457. ; 38:2, s. 217-239
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Tidskriftsartikel (refereegranskat)abstract
- Lower Cretaceous meandering and braided fluvial sandstones of the Nubian Formation form some of the most important subsurface reservoir rocks in the Sirt Basin, north-central Libya. Mineralogical, petrographical and geochemical analyses of sandstone samples from well BB6-59, Sarir oilfield, indicate that the meandering fluvial sandstones are fine- to very fine-grained subarkosic arenites (av. Q(91)F(5)L(4)), and that braided fluvial sandstones are medium- to very coarse-grained quartz arenites (av. Q(96)F(3)L(1)). The reservoir qualities of these sandstones were modified during both eodiagenesis (ca. <70 degrees C; <2 km) and mesodiagenesis (ca. >70 degrees C; >2 km). Reservoir quality evolution was controlled primarily by the dissolution and kaolinitization of feldspars, micas and mud intraclasts during eodiagenesis, and by the amount and thickness of grain-coating clays, chemical compaction and quartz overgrowths during mesodiagenesis. However, dissolution and kaolinitization of feldspars, micas and mud intraclasts resulted in the creation of intercrystalline micro- and mouldic macro-porosity and permeability during eodiagenesis, which were more widespread in braided fluvial than in meandering fluvial sandstones. This was because of the greater depositional porosity and permeability in the braided fluvial sandstones which enhanced percolation of meteoric waters. The development of only limited quartz overgrowths in the braided fluvial sandstones, in which quartz grains are coated by thick illite layers, retained high porosity and permeability (12-23% and 30-600 mD). By contrast, meandering fluvial sandstones underwent porosity loss as a result of quartz overgrowth development on quartz grains which lack or have thin and incomplete grain-coating illite (2-15% and 0-0.1 mD). Further loss of porosity in the meandering fluvial sandstones occurred as a result of chemical compaction (pressure dissolution) induced by the occurrence of micas along grains contacts. Other diagenetic alterations, such as the growth of pyrite, siderite, dolomite/ankerite and albitization, had little impact on reservoir quality. The albitization of feldspars may have had minor positive influence on reservoir quality through the creation of intercrystalline micro-porosity between albite crystals. The results of this study show that diagenetic modifications of the braided and meandering fluvial sandstones in the Nubian Formation, and resulting changes in reservoir quality, are closely linked to depositional porosity and permeability. They are also linked to the thickness of grain-coating infiltrated clays, and to variations in detrital composition, particularly the amounts of mud intraclasts, feldspars and mica grains as well as climatic conditions.
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| 7. |
- Mansurbeg, Howri, et al.
(författare)
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Diagenetic evolution and porosity destruction of turbiditic hybrid arenites and siliciclastic sandstones of foreland basins: Evidence from the Eocene Hecho Group, Pyrenees, Spain
- 2009
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Ingår i: Journal of Sedimentary Research. - : Society for Sedimentary Geology. - 1527-1404 .- 1938-3681. ; 79:9-10, s. 711-735
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Tidskriftsartikel (refereegranskat)abstract
- This study aims to unravel the impact of diagenetic alterations on porosity loss of foreland-basin turbiditic hybrid arenites and associated siliciclastic sandstones of the Eocene Hecho Group (south-central Pyrenees, Spain). In this succession, hybrid arenites and calclithites are extensively cemented by mesogenetic calcite cement (delta O-18(VPDB) = -10.0 parts per thousand to -5.8 parts per thousand; T-h, mode = 80 degrees C salinity mode = 18.8 wt% eq. NaCl), Fe-dolomite (delta(18)(OVPDB) = -8.5 parts per thousand to -6.3 parts per thousand) and trace amounts of siderite. The extent of carbonate cementation is interpreted to be related to the amounts of extrabasinal and intrabasinal carbonate grains, which provided nuclei and sources for the precipitation and growth of carbonate cements. Other diagenetic alterations, such as pyrite and albitization, had no impact on reservoir quality. Scarce early diagenetic cements, coupled with abundant ductile carbonate and siliciclastic framework grains, have led to rapid porosity loss owing to compaction. Conversely, abundant quartz in the sandstones prevented rapid loss of porosity by mechanical compaction. Reservoir quality was affected by mesogenetic cementation by quartz overgrowths, calcite and dolomite intergranular pressure dissolution of quartz grains, and formation of fracture-filling calcite cement (delta O-18(V-PDB) values from -10.4 parts per thousand to -7.8 parts per thousand; T-h temperatures of approximate to 150 degrees C), which are attributed to deep circulation of hot meteoric waters during extensional stages of tectonism. The results of this study illustrate that diagenetic evolution pathways of the arenites and sandstones are closely linked to the variation in detrital composition, particularly the proportion and types of extrabasinal noncarbonates, extrabasinal carbonates, and intrabasinal carbonate grains. These insights suggest that marine turbiditic hybrid arenites and calclithites of foreland basins are subjected to more rapid and extensive porosity loss owing to compaction and cementation than associated siliciclastic sandstones. Degradation of reservoir quality makes these hybrid arenites, calclithites, and sandstones suitable as tight gas reservoirs, but only if fracture porosity and permeability develop during tectonic deformation.
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| 8. |
- Morad, Sadoon, et al.
(författare)
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Chloritization in Proterozoic granite from the Äspö Laboratory, southeastern Sweden : record of hydrothermal alterations and implications for nuclear waste storage
- 2011
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Ingår i: Clay minerals. - : Mineralogical Society. - 0009-8558 .- 1471-8030. ; 46:3, s. 495-513
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Tidskriftsartikel (refereegranskat)abstract
- Hydrothermal alteration of Proterozoic granitic rocks in the Aspo underground laboratory, southestern Sweden, resulted in the formation of chlorite with large variations in textural and chemical characteristics, which reflect differences in formation temperatures, fluid composition, and reaction mechanisms. The mineral assemblage associated with chlorite, including Ca-Al silicates (prehnite, pumpellyite, epidote, and titanite), Fe-oxides, calcite, albite and K-feldspar, suggests that chloritization occurred at temperatures of between 200-350 degrees C during various hydrothermal events primarily linked to magmatism and rock deformation. Petrographic and electron microprobe analyses revealed that chlorite replaced biotite, amphibole and magnetite, and hydrothermal chlorite phases filled fractures and vugs in the granitic rocks. While fracture-filling chlorite reduces fracture permeability, chloritization reactions in the host granite resulted in the formation of new localized microporosity that should thus be taken into consideration when evaluating the safety of the granitic basement rocks as a repository for nuclear waste. It is also important to take into account that similar alteration reactions may occur at the site of stored nuclear waste where temperatures in excess of 100 degrees C might be encountered.
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| 9. |
- Morad, Sadoon, et al.
(författare)
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Hydrothermal alteration of magmatic titanite : Evidence from Proterozoic granitic rocks, Southeastern Sweden
- 2009
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Ingår i: Canadian Mineralogist. - : Mineralogical Association of Canada. - 0008-4476 .- 1499-1276. ; 47:4, s. 801-811
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Tidskriftsartikel (refereegranskat)abstract
- Magmatic titanite in Proterozoic granitic rocks from southeastern Sweden has been subjected to hydrothermal dissolution and replacement by finely crystalline Fe-dominant chlorite and TiO2 (± quartz ± calcite). These alteration patterns require the redistribution of the highly immobile Ti and At on the thin-section scale. The chloritization of titanite involved the formation of an intermediate Al-Fe-rich phase probably comprising intimately intergrown, submicroscopic chlorite and titanite. The creation of microporosity by the hydrothermal alteration of titanite may enhance the diffusive flux of matter, and hence the rate of reactions in granitic rocks. The alteration of titanite is most pronounced in red-stained granitic rock zones enriched in partly dissolved biotite and magnetite, which could have acted as local source of Al, Fe and Mg needed for chlorite formation.
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| 10. |
- Ali Kalefa El-ghali, Mohamed, et al.
(författare)
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Diagenetic alterations related to marine transgression and regression in fluvial deltaic and shallow marine sandstones of the Triassic Buntsandstein and Keuper formations, the Paris Basin, France
- 2009
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Ingår i: Marine and Petroleum Geology. - : Elsevier BV. - 0264-8172 .- 1873-4073. ; 26:3, s. 289-309
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Tidskriftsartikel (refereegranskat)abstract
- The distribution of diagenetic alterations in Triassic fluvio-deltaic, quartzarenitic to sublitharenitic, lowstand systems tract (LST) sandstones of the Grès á Voltzia Formation, anastomosing fluvial, quartzarenitic transgressive systems tract (TST) sandstones of the Grès á Roseaux Formation, and shallow marine, quartzarenitic to sublitharenitic, TST sandstones of the Grès Coquiller Formation, the Paris Basin (France), can be linked to transgression and regression events, and thus to the sequence stratigraphic context. Near-surface eogenetic alterations, which display a fairly systematic link to the depositional facies and sequence stratigraphic framework, include: (i) cementation by meteoric water calcite (δ18O=−8.9‰ and δ13C=−9.1‰) in the fluvio-deltaic, LST sandstones, (ii) cementation by mixed marine–meteoric calcite (δ18O=−5.3‰ to −2.6‰ and δ13C=−3.9‰ to −1.3‰) and dolomite (δ18O=−4.6‰ to −2.6‰ and δ13C=−2.9‰ to −2.3‰) in the foreshore, TST sandstones and below parasequence boundaries (PB), and transgressive surface (TS), and in the shoreface, TST sandstones below maximum flooding surfaces (MFS), being facilitated by the presence of carbonate bioclasts, (iii) dissolution of detrital silicates and precipitation of K-feldspar overgrowths and kaolinite, particularly in the fluvio-deltaic, LST sandstones owing to effective meteoric water circulation, and (vi) formation of autochthonous glauconite, which is increases in abundance towards the top of the fluvio-deltaic, LST sandstones, and along TS, and in the shoreface, TST sandstones, by alteration of micas owing to the flux of seawaters into the sandstones during transgression, whereas parautochthonous glauconite is restricted to the TS sandstones owing to marine reworking. Mesogenetic alterations, which include cementation by quartz overgrowths and illite, display fairly systematic link to fluvio-deltaic, LST sandstones. This study has revealed that linking of diagenesis to transgression and regression events enables a better understanding of the parameters that control the spatial and temporal distribution of diagenetic alterations in sandstones and of their impact on reservoir quality evolution.
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