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- Chandrasekaran, Sundaram, et al.
(författare)
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Advanced opportunities and insights on the influence of nitrogen incorporation on the physico-/electro-chemical properties of robust electrocatalysts for electrocatalytic energy conversion
- 2021
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Ingår i: Coordination chemistry reviews. - : Elsevier. - 0010-8545 .- 1873-3840. ; 449
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Forskningsöversikt (refereegranskat)abstract
- The use of a wide range of methods for incorporating nitrogen atoms on robust catalysts has given rise to fundamental advances in the field of energy conversion and storage. Recently, nitrogen incorporation has proven to be able to fine-tune the electron densities of exposed active sites to create high-performance electrocatalysts. The preservation of a strong interface between the local atomic coordination of nitrogen atoms on bare carbon, single metal atoms, transition metal oxides, metal chalcogenides, and MXenes during synthesis plays an important role in producing an efficient electrocatalysts. In addition, the ability of nitrogen atoms to bind with carbon or metal atoms can be influenced by processing conditions. In this regard, this review is the first comprehensive overview of the range of synthetic strategies to form nitrogen incorporated catalysts and assess their chemical, structural, physical electronic property modification and their influence on electrocatalytic ORR, OER, and HER performance. This review will describe how specific strategies have been utilized to realise effective electrocatalytic systems, including the energy conversion of nitrogen incorporated catalysts, structural coordination, and material optimization. Finally, the main challenges to be considered in future investigations in order to initiate new research efforts in this promising research area are discussed.
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| 2. |
- Zhang, Ye, et al.
(författare)
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Application of graphdiyne oxide in photoelectrochemical-type photodetectors and ultrafast fiber lasers
- 2022
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Ingår i: Nano Today. - : Elsevier. - 1748-0132 .- 1878-044X. ; 47
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Tidskriftsartikel (refereegranskat)abstract
- Graphdiyne oxide (GDYO), the oxidized form of graphdiyne (GDY), has been widely explored for applica-tions in various technological fields owing to its fascinating properties. However, the research of GDYO for applications in photodetectors (PDs) and mode-locker has been lagging. Herein, we present experimental demonstrations of promising applications of GDYO for narrow-band photoelectrochemical (PEC)-type PDs with tunable performance. Moreover, the measured excellent nonlinear optical absorption of GDYO makes it a suitable material for mode-locking in ultrafast fiber lasers. Ultrastable pulses as short as 1.5 ps could be obtained from an Erbium-doped fiber laser based on GDYO at 1559 nm. These findings have been supported and interpreted by density functional theory (DFT) calculations as well as transient absorption dynamics studies. The presented results provide pathways for the future utilization of GDYO in high-performance optoelectronic devices.
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