| 1. |
- Shi, Furong, et al.
(författare)
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A Nitroxide Radical Conjugated Polymer as an Additive to Reduce Nonradiative Energy Loss in Organic Solar Cells
- 2023
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Ingår i: Advanced Materials. - : Wiley. - 0935-9648 .- 1521-4095. ; 35:23
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Tidskriftsartikel (refereegranskat)abstract
- Nonfullerene-acceptor-based organic solar cells (NFA-OSCs) are now set off to the 20% power conversion efficiency milestone. To achieve this, minimizing all loss channels, including nonradiative photovoltage losses, seems a necessity. Nonradiative recombination, to a great extent, is known to be an inherent material property due to vibrationally induced decay of charge-transfer (CT) states or their back electron transfer to the triplet excitons. Herein, it is shown that the use of a new conjugated nitroxide radical polymer with 2,2,6,6-tetramethyl piperidine-1-oxyl side groups (GDTA) as an additive results in an improvement of the photovoltaic performance of NFA-OSCs based on different active layer materials. Upon the addition of GDTA, the open-circuit voltage (VOC), fill factor (FF), and short-circuit current density (JSC) improve simultaneously. This approach is applied to several material systems including state-of-the-art donor/acceptor pairs showing improvement from 15.8% to 17.6% (in the case of PM6:Y6) and from 17.5% to 18.3% (for PM6:BTP-eC9). Then, the possible reasons behind the observed improvements are discussed. The results point toward the suppression of the CT state to triplet excitons loss channel. This work presents a facile, promising, and generic approach to further improve the performance of NFA-OSCs.
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| 2. |
- He, Yan, et al.
(författare)
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Discovering Optimal Triplets for Assessing the Uncertainties of Satellite-Derived Evapotranspiration Products
- 2023
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Ingår i: Remote Sensing. - 2072-4292. ; 15:13
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Tidskriftsartikel (refereegranskat)abstract
- Information relating to errors in evapotranspiration (ET) products, including satellite-derived ET products, is critical to their application but often challenging to obtain, with a limited number of flux towers available for the sufficient validation of measurements. Triple collocation (TC) methods can assess the inherent uncertainties of the above ET products using just three independent variables as a triplet input. However, both the severity with which the variables in the triplet violate the assumptions of zero error correlations and the corresponding impact on the error estimation are unknown. This study proposed a cross-correlation analysis approach to discover the optimal triplet of satellite-derived ET products with regard to providing the most reliable error estimation. All possible triple collocation solutions for the same product were first evaluated by the extended triple collocation (ETC), among which the optimum was selected based on the correlation between ETC-based and in-situ-based error metrics, and correspondingly, a statistic experiment based on ranked triplets demonstrated how the optimal triplet was valid for all pixels of the product. Six popular products (MOD16, PML_V2, GLASS, SSEBop, ERA5, and GLEAM) that were produced between 2003 to 2018 and which cover China’s mainland were chosen for the experiment, in which the error estimates were compared with measurements from 23 in-situ flux towers. The findings suggest that (1) there exists an optimal triplet in which a product as an input of TC with other collocating inputs together violate TC assumptions the least; (2) the error characteristics of the six ET products varied significantly across China, with GLASS performing the best (median error: 0.1 mm/day), followed by GLEAM, ERA5, and MOD16 (median errors below 0.2 mm/day), while PML_V2 and SSEBop had slightly higher median errors (0.24 mm/day and 0.27 mm/day, respectively); and (3) removing seasonal variations in ET signals has a substantial impact on enhancing the accuracy of error estimations.
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| 3. |
- Atsawawaranunt, Kamolphat, et al.
(författare)
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The SISAL database : a global resource to document oxygen and carbon isotope records from speleothems
- 2018
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Ingår i: Earth System Science Data. - : Copernicus GmbH. - 1866-3508 .- 1866-3516. ; 10:3, s. 1687-1713
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Tidskriftsartikel (refereegranskat)abstract
- Stable isotope records from speleothems provide information on past climate changes, most particularly information that can be used to reconstruct past changes in precipitation and atmospheric circulation. These records are increasingly being used to provide "out-of-sample" evaluations of isotope-enabled climate models. SISAL (Speleothem Isotope Synthesis and Analysis) is an international working group of the Past Global Changes (PAGES) project. The working group aims to provide a comprehensive compilation of speleothem isotope records for climate reconstruction and model evaluation. The SISAL database contains data for individual speleothems, grouped by cave system. Stable isotopes of oxygen and carbon (delta O-18, delta C-13) measurements are referenced by distance from the top or bottom of the speleothem. Additional tables provide information on dating, including information on the dates used to construct the original age model and sufficient information to assess the quality of each data set and to erect a standardized chronology across different speleothems. The metadata table provides location information, information on the full range of measurements carried out on each speleothem and information on the cave system that is relevant to the interpretation of the records, as well as citations for both publications and archived data.
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| 4. |
- Comas-Bru, Laia, et al.
(författare)
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Evaluating model outputs using integrated global speleothem records of climate change since the last glacial
- 2019
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Ingår i: Climate of the Past. - : Copernicus GmbH. - 1814-9324 .- 1814-9332. ; 15:4, s. 1557-1579
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Tidskriftsartikel (refereegranskat)abstract
- Although quantitative isotope data from speleothems has been used to evaluate isotope-enabled model simulations, currently no consensus exists regarding the most appropriate methodology through which to achieve this. A number of modelling groups will be running isotope-enabled palaeoclimate simulations in the framework of the Coupled Model Intercomparison Project Phase 6, so it is timely to evaluate different approaches to using the speleothem data for data-model comparisons. Here, we illustrate this using 456 globally distributed speleothem delta O-18 records from an updated version of the Speleothem Isotopes Synthesis and Analysis (SISAL) database and palaeoclimate simulations generated using the ECHAM5-wiso isotope-enabled atmospheric circulation model. We show that the SISAL records reproduce the first-order spatial patterns of isotopic variability in the modern day, strongly supporting the application of this dataset for evaluating model-derived isotope variability into the past. However, the discontinuous nature of many speleothem records complicates the process of procuring large numbers of records if data-model comparisons are made using the traditional approach of comparing anomalies between a control period and a given palaeoclimate experiment. To circumvent this issue, we illustrate techniques through which the absolute isotope values during any time period could be used for model evaluation. Specifically, we show that speleothem isotope records allow an assessment of a model's ability to simulate spatial isotopic trends. Our analyses provide a protocol for using speleothem isotope data for model evaluation, including screening the observations to take into account the impact of speleothem mineralogy on delta O-18 values, the optimum period for the modern observational baseline and the selection of an appropriate time window for creating means of the isotope data for palaeo-time-slices.
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| 5. |
- Hu, Xianfeng, et al.
(författare)
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Carbothermic reduction of synthetic chromite with/without the addition of iron powder
- 2016
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Ingår i: ISIJ International. - : Iron and Steel Institute of Japan. - 0915-1559 .- 1347-5460. ; 56:12, s. 2147-2155
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Tidskriftsartikel (refereegranskat)abstract
- Carbothermic reduction of chromite is an important industrial process for extracting chromium from the chromite. To have a better understanding of the effect of iron on the carbothermic reduction of chromite, the reduction of synthetic chromite (FeCr2O4) by graphite with/without the addition of iron powder was investigated in this paper by Thermogravimetric Analysis (TGA) in argon atmosphere. The fractional reduced samples were examined by SEM/EDS and XRD analysis, and the reduction process was thermodynamically and kinetically evaluated. The experimental results show that the iron powder addition enhances the reduction of FeCr2O4 and this effect increases when increased amounts of iron powder are added. This phenomenon is attributed to the in situ dissolution of chromium into the iron and mixed carbide (Cr,Fe)7C3, which can decrease the activity of the nascent chromium formed by the reduction of the FeCr2O4. The experimental results indicate that the reduction of FeCr2O4 with up to 80 wt.% iron powder addition is likely to be a single-step process and the kinetic analysis suggests that the reduction reaction is likely to be either (a) chemical reaction at the surface of FeCr2O4 or (b) diffusional dissolution of the product (FeCr2) into the iron/alloy particles or the mixed control of (a) and (b).
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| 6. |
- Hu, Xianfeng, et al.
(författare)
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Direct chromium alloying by chromite ore with the presence of metallic iron
- 2013
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Ingår i: Journal of Mining and Metallurgy, Section B. - 1450-5339. ; 49:2, s. 207-215
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Tidskriftsartikel (refereegranskat)abstract
- Direct chromium alloying by chromite ore in EAF operation is a promising process in stainless steel production, which has the advantage of resource-saving, energy-saving, and environment-friendly. In the present investigation, iron, carbon, and chromite ore mixture (Fe+C+FeCr2O4) were chosen as the precursor for direct chromium alloying. Thermogravimetric Analysis (TGA) experiments were carried out to investigate the effect of iron content on the reduction kinetics, and the results show that the presence of metallic iron in the precursor will increase the reduction rate of chromite. Up-scaling experiments (100 g and 500 g scale) have been carried out in the induction furnace to further test the effectiveness of using industrial chromite ore for direct chromium alloying. The induction furnace tests confirmed the necessity of adjusting composition of the slags to ensure high yield of chromium in the final products; and chromium yield can reach 90%.
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| 7. |
- Jarnerud, Tova, et al.
(författare)
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Application of Fly Ash from Pulp and Paper Industries as Slag Formers in Electric Arc Furnace Stainless Steel Production
- 2020
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Ingår i: Steel Research International. - : Wiley-VCH Verlag. - 1611-3683 .- 1869-344X. ; 91:10
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Tidskriftsartikel (refereegranskat)abstract
- During electric arc furnace (EAF) steelmaking process, burnt lime is charged together with other slag forming materials to attain a specific basicity of the slag and to achieve purification by removing unwanted elements. Herein, fly ash (FA) containing ≈60% CaO generated from pulp/paper mills is tested to partially (15–50%) replace primary lime (PL) in pilot scale EAF trials. The obtained results show good possibilities. It is found that an increased amount of FA instead of PL reduces the required amount of FeSi (up to 3 kg t−1 of scrap) and increases the sulfur content in the final slag. As a result, the amount of required slag/ton of steel can be decreased. However, the phosphorus content in the metal is slightly increased. The replacement ratio of FA will be limited by the acceptable phosphorus level in the final steel, due to higher phosphorus content in FA from pulp and paper mills compared with that in PL. Applications of FA as slag formers can reduce the consumption of natural resources in the metallurgical processes. In addition, it can reduce the amount of wastes from pulp/paper industries sent to landfill, which is important from an environmental point of view.
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| 8. |
- Peng, Shanchi, et al.
(författare)
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Global Standard Stratotype-Section and Point (GSSP) for the Base of the Jiangshanian Stage (Cambrian: Furongian) at Duibian, Jiangshan, Zhejiang, Southeast China
- 2012
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Ingår i: Episodes. - 0705-3797. ; 35:4, s. 462-477
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Tidskriftsartikel (refereegranskat)abstract
- The International Commission on Stratigraphy and the IUGS Executive Committee have recently approved a Global Standard Stratotype-section and Point (GSSP) defining the base of the second stage of the Furongian Series, Cambrian System. This stage is named the Jiangshanian Stage, after Jiangshan City, western Zhejiang Province, China, where the GSSP is located. The GSSP is exposed in a natural outcrop near Duibian Village. It is defined at the base of a limestone (wackestone) layer 108.12 m above the base of the Huayansi Formation in the Duibian B section, coinciding with the first appearance of the cosmopolitan agnostoid trilobite Agnostotes orientalis (base of the A. orientalis Zone). The GSSP is at a position of 28 degrees 48.977'N latitude and 118 degrees 36.887 'E longitude. Secondary global markers at or near the base of the stage include the first appearance of the cosmopolitan polymerid trilobite Irvingella angustilimbata, which coincides with the FAD of the primary marker in the stratotype section, and near the end of a large positive carbon isotopic excursion (SPICE excursion). Faunal turnovers close to the base of the Jiangshanian Stage have been recognized as being at the base of the Iverian Stage in Australia, the Gonggrian Stage in Korea, and the Agnostotes orientalis Irvingella perfecta Zone in Siberia, and near the base of the Aksayan Stage in Kazakhstan, the Sunwaptan Stage in Laurentia, and the Parabolina brevispina Zone in Baltica.
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| 9. |
- Shah, Suraj, et al.
(författare)
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Evaluating the added value of multi-variable calibration of SWAT with remotely sensed evapotranspiration data for improving hydrological modeling
- 2021
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Ingår i: Journal of Hydrology. - : Elsevier BV. - 0022-1694. ; 603
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Tidskriftsartikel (refereegranskat)abstract
- Hydrological processes in a watershed consist of multiple sub-processes (such as plant growth, evapotranspiration, water yield, and soil–water balance) that have complex interactions. The common practice of calibrating hydrological models against only a single variable (e.g., streamflow) can lead to parameter uncertainty (also known as equifinality), resulting in significant uncertainties in the representation and simulation of sub-processes. As multi-variable calibration can be a potential solution to this issue, we tested the integration of spatially and temporally gridded remotely sensed evapotranspiration (RS-ET) data with the Soil and Water Assessment Tool (SWAT) hydrological model. This approach was intended to reduce equifinality by enhancing related hydrological sub-processes in both space and time rather than improving the evaluation metrics at the streamflow outlet. We further introduced the principle of repeated measure design in the calibration process, where the SWAT was calibrated under two different schemes: Scheme1 (using only streamflow data) and Scheme2 (using both RS-ET and streamflow data). The model's performance was evaluated using the concept of stability at multiple spatial scales (basin outlet, sub-basins, and hydrological response units) and aspects (different model outputs and most sensitive calibrated parameters). The significance of the difference between the stabilities produced by the two schemes was estimated using the Mann–Whitney U test. Testing this approach in Meichuan Basin (China) showed that Scheme2 substantially reduced equifinality for calibrated parameters and model outputs compared to Scheme1. In addition, the model solutions and outputs for Scheme2 were significantly different from Scheme1. Our results demonstrate the added value of using increasingly available open-access RS-ET data for improving hydrological model calibration.
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| 10. |
- Wang, Zhiming, et al.
(författare)
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Stabilizing Single Ni Adatoms on a Two-Dimensional Porous Titania Overlayer at the SrTiO3(110) Surface.
- 2014
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Ingår i: Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 118:34, s. 19904-19909
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Tidskriftsartikel (refereegranskat)abstract
- Nickel vapor-deposited on the SrTiO3(110) surface was studied using scanning tunneling microscopy, photoemission spectroscopy (PES), and density functional theory calculations. This surface forms a (4 × 1) reconstruction, composed of a 2-D titania structure with periodic six- and ten-membered nanopores. Anchored at these nanopores, Ni single adatoms are stabilized at room temperature. PES measurements show that the Ni adatoms create an in-gap state located at 1.9 eV below the conduction band minimum and induce an upward band bending. Both experimental and theoretical results suggest that Ni adatoms are positively charged. Our study produces well-dispersed single-adatom arrays on a well-characterized oxide support, providing a model system to investigate single-adatom catalytic and magnetic properties.
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