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- Fu, Q. X., et al.
(författare)
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Doped ceria-chloride composite electrolyte for intermediate temperature ceramic membrane fuel cells
- 2002
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Ingår i: Materials letters (General ed.). - 0167-577X .- 1873-4979. ; 53:3, s. 186-192
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Tidskriftsartikel (refereegranskat)abstract
- A kind of oxide-salt composite electrolyte, gadolinium-doped ceria (GDC)-LiCl-SrCl2, prepared with hot-press technique, shows superior ionic conductivity, which is 2-10 times higher than that of GDC itself at the temperature range of 400-600 degreesC. More interestingly, not like the GDC electrolyte, which has some extent of electronic conduction under reducing atmosphere, the composite electrolyte is almost a pure ionic conductor, evidenced by the fuel cell's (FC) open circuit voltage (OCV) close to the theoretical one. The fuel cells based on this composite electrolyte show excellent power density output even at temperature as low as 500 degreesC (240 mW cm(-2)) in spite of the relatively thick electrolyte (0.4 mm). Such high performance, in combination with its low cost in both raw materials and fabrication process, make this kind of composite electrolyte a good candidate electrolyte material for future ultra-low-cost intermediate temperature ceramic membrane fuel cells (IT-CMFCs).
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| 2. |
- Fu, Q. X., et al.
(författare)
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Intermediate temperature fuel cells based on doped ceria-LiCl-SrCl2 composite electrolyte
- 2002
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Ingår i: Journal of Power Sources. - 0378-7753 .- 1873-2755. ; 104:1, s. 73-78
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Tidskriftsartikel (refereegranskat)abstract
- A new type of oxide-salt composite electrolyte, gadolinium-doped ceria (GDC)-LiCl-SrCl2, was developed and demonstrated its promising use for intermediate temperature (400-700 degreesC) fuel cells (ITFCs). The dc electrical conductivity of this composite electrolyte (0.09-0.13 S cm(-1) at 500-650 degreesC) was 3-10 times higher than that of the pure GDC electrolyte, indicating remarkable proton or oxygen ion conduction existing in the LiCl-SrCl2 chloride salts or at the interface between GDC and the chloride salts. Using this composite electrolyte, peak power densities of 260 and 510 mW cm(-2), with current densities of 650 and 1250 mA cm(-2) were achieved at 550 and 625 degreesC, respectively. This makes the new material a good candidate electrolyte for future low-cost ITFCs.
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| 3. |
- Zhu, Bin, et al.
(författare)
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LiF-MgF2 composite electrolyte for advanced ceramic fuel cells : structure, electrical properties and applications
- 2002
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Ingår i: Solid State Ionics. - 0167-2738 .- 1872-7689. ; 148:04-mar, s. 583-589
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Tidskriftsartikel (refereegranskat)abstract
- The two-phase composite, LiF-MgF2, has been discovered to have high ionic conductivity within a wide composition range, e.g., 10(-2)-10(-1) S cm(-1) at 600-800 degreesC, which is several orders of magnitude higher than that of pure LiF or MgF2. In addition, the activation energy of the composite is much lower than that of the pure phases. The remarkable conductivity enhancement as well as the low activation energy is attributed to the composite effect, i.e., the conduction takes place mainly in the interfacial region between LiF and MgF2 grains. The agreements of conductivity derived from two different methods, impedance spectra and fuel cell characterisation, in combination of the ESR results, show a possibility that proton (plus hydride ion) conduction dominates the electrical conduction in the LiF-MgF2 system under the H-2/air fuel cell environments.
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