| 51. |
- Soerensen, Anne L., et al.
(författare)
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Deciphering the Role of Water Column Redoxclines on Methylmercury Cycling Using Speciation Modeling and Observations From the Baltic Sea
- 2018
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Ingår i: Global Biogeochemical Cycles. - : American Geophysical Union (AGU). - 0886-6236 .- 1944-9224. ; 32:10, s. 1498-1513
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Tidskriftsartikel (refereegranskat)abstract
- Oxygen-depleted areas are spreading in coastal and offshore waters worldwide, but the implication for production and bioaccumulation of neurotoxic methylmercury (MeHg) is uncertain. We combined observations from six cruises in the Baltic Sea with speciation modeling and incubation experiments to gain insights into mercury (Hg) dynamics in oxygen depleted systems. We then developed a conceptual model describing the main drivers of Hg speciation, fluxes, and transformations in water columns with steep redox gradients. MeHg concentrations were 2-6 and 30-55 times higher in hypoxic and anoxic than in normoxic water, respectively, while only 1-3 and 1-2 times higher for total Hg (THg). We systematically detected divalent inorganic Hg (Hg-II) methylation in anoxic water but rarely in other waters. In anoxic water, high concentrations of dissolved sulfide cause formation of dissolved species of Hg-II: HgS2H(aq)- and Hg (SH)(2)(0)((aq)). This prolongs the lifetime and increases the reservoir of Hg-II readily available for methylation, driving the high MeHg concentrations in anoxic zones. In the hypoxic zone and at the hypoxic-anoxic interface, Hg concentrations, partitioning, and speciation are all highly dynamic due to processes linked to the iron and sulfur cycles. This causes a large variability in bioavailability of Hg, and thereby MeHg concentrations, in these zones. We find that zooplankton in the summertime are exposed to 2-6 times higher MeHg concentrations in hypoxic than in normoxic water. The current spread of hypoxic zones in coastal systems worldwide could thus cause an increase in the MeHg exposure of food webs.
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| 52. |
- Staal, Arie, et al.
(författare)
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Global terrestrial moisture recycling in Shared Socioeconomic Pathways
-
Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- The global water cycle has undergone considerable changes since pre-industrial times due to global climate change and land-use changes. These drivers will almost certainly continue to change during the course of this century. However, where, how, and to which extent terrestrial moisture recycling will change as a result remains unclear.Mutually consistent scenarios of climate change and land-use changes for the 21st century are provided by the Shared Socioeconomic Pathways (SSPs). The SSPs provide a framework of five different narratives involving varying degrees of challenges associated with mitigation or adaptation. From each narrative follow different implications for emissions, energy, and land use. The SSPs serve as the conceptual framework behind the sixth generation of the Coupled Model Intercomparison Project, CMIP6.Terrestrial moisture recycling is often assessed using atmospheric moisture tracking models. An example is UTrack, a Lagrangian model to track moisture through three-dimensional space. Here we present a new forward-tracking version of UTrack that is forced by output of a CMIP6 model to study how terrestrial moisture recycling may change across the globe until the end of the 21st century in a range of SSPs, from mild to severe: SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5. For this forcing, we chose the Norwegian Earth System Model version 2, or NorESM2. It has a temporal resolution of one day and a spatial resolution of 1.25° × 0.9375° at eight pressure levels.We find that across the 21st century, the global terrestrial moisture recycling ratio decreases with the severity of the Shared Socioeconomic Pathways (SSPs). We calculate a decrease in global terrestrial precipitation recycling by 2.1% with every degree of global warming. Because the SSPs represent internally consistent scenarios of both global warming and global land cover changes, it is hard to distinguish the relative contributions of these two, but the evidence points at a major influence of global warming on moisture recycling.We find spatial differences in trends in recycling ratios, but which are broadly consistent among SSPs. If a change in precipitation (either drying or wetting) coincides with an increase in terrestrial precipitation recycling ratio, we call it land-dominated. We call the change in precipitation ocean-dominated if it coincides with a decrease in terrestrial precipitation recycling ratio. Land dominance tends to occur in regions with already large terrestrial precipitation recycling ratios, mainly interior South America (land-dominated drying) and eastern Asia (land-dominated wetting). Land-dominated drying may also happen in eastern Europe, in central America and in subtropical sub-Saharan Africa. Ocean-dominance, mainly in the form of wetting, is found primarily in the high northern latitudes and in central Africa.We also simulated the changes in basin recycling for the 27 major river basins of the world, confirming the overall tendency of decreasing recycling with severity of the SSP, as well as its spatial variations.
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| 53. |
- Arellano, Santiago, 1981
(författare)
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Studies of Volcanic Plumes with Remote Spectroscopic Sensing Techniques -DOAS and FTIR measurements on volcanoes of the Network for Observation of Volcanic and Atmospheric Change-
- 2014
-
Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Volcanism is a rich geodynamical process, closely linked to the origin and ongoing evolution of the lithosphere, atmosphere, hydrosphere and biosphere. Humans have benefited from the resources provided by volcanoes but also been threatened by the dangers of volcanic eruptions, which accurate prediction remains elusive. This is partly due to the inherent complexity of volcanic systems and partly because of the difficulty of conducting key observations to characterize them. In particular, since the segregation and escape of magmatic volatiles are essential mechanisms behind volcanic eruptions, monitoring the intensity and composition of the resulting emissions in the atmosphere is essential to characterize the state of volcanic activity; however, their direct measurement is not always feasible.Remote spectroscopic sensing, whereby gas species can be quantified by their spectral signatures in electromagnetic radiation gathered at a prudent distance from the plume, offers the possibility to conduct reliable and sustainable monitoring of volcanic emissions. To expand the remote sensing capabilities of volcanological observatories the Network for Observation of Volcanic and Atmospheric Change (NOVAC) was established in 2005. The central theme of this thesis is the acquisition, analysis and interpretation of measurements of volcanic gas emissions on volcanoes of NOVAC. Measurements of the mass flow rate of SO2 and the molar ratios of SO2 against BrO and HCl were obtained by scanning-Differential Optical Absorption Spectroscopy (DOAS) of scattered solar ultraviolet radiation and by Fourier-Transform Spectroscopy (FTIR) of direct solar infrared radiation. The uncertainty of the measurements is characterized and methods for combining observations from different sensors implemented. Statistical and physical models of degassing are proposed for selected volcanoes of the network. The resulting time-series of emission on 16 volcanoes is one of the more detailed compilations of volcanic degassing in the last decade, particularly from passive emissions which are difficult to detect from satellite platforms. This work aims at advancing our knowledge of volcanic eruptions for a better mitigation of their risks.
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| 54. |
- Alvarez, Belinda, et al.
(författare)
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Assessing the potential of sponges (Porifera) as indicators of ocean dissolved Si concentrations
- 2017
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Ingår i: Frontiers in Marine Science. - : Frontiers Media SA. - 2296-7745. ; 4
-
Tidskriftsartikel (refereegranskat)abstract
- We explore the distribution of sponges along dissolved silica (dSi) concentration gradients to test whether sponge assemblages are related to dSi and to assess the validity of fossil sponges as a palaeoecological tool for inferring dSi concentrations of the past oceans. We extracted sponge records from the publically available Global Biodiversity Information Facility (GBIF) database and linked these records with ocean physiochemical data to evaluate if there is any correspondence between dSi concentrations of the waters sponges inhabit and their distribution. Over 320,000 records of Porifera were available, of which 62,360 met strict quality control criteria. Our analyses was limited to the taxonomic levels of family, order and class. Because dSi concentration is correlated with depth in the modern ocean, we also explored sponge taxa distributions as a function of depth. We observe that while some sponge taxa appear to have dSi preferences (e.g., class Hexactinellida occurs mostly at high dSi), the overall distribution of sponge orders and families along dSi gradients is not sufficiently differentiated to unambiguously relate dSi concentrations to sponge taxa assemblages. We also observe that sponge taxa tend to be similarly distributed along a depth gradient. In other words, both dSi and/or another variable that depth is a surrogate for, may play a role in controlling sponge spatial distribution and the challenge is to distinguish between the two. We conclude that inferences about palaeo-dSi concentrations drawn from the abundance of sponges in the stratigraphic records must be treated cautiously as these animals are adapted to a great range of dSi conditions and likely other underlying variables that are related to depth. Our analysis provides a quantification of the dSi ranges of common sponge taxa, expands on previous knowledge related to their bathymetry preferences and suggest that sponge taxa assemblages are not related to particular dSi conditions.
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| 55. |
- Barrientos, Natalia, 1985-
(författare)
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Arctic Ocean benthic foraminifera preservation and Mg/Ca ratios : Implications for bottom water palaeothermometry
- 2018
-
Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Reconstructions of Arctic Ocean palaeotemperatures are needed to disentangle natural variability from anthropogenic changes and understand the role of ocean heat transport in forcing or providing feedbacks on Arctic climate change. Despite known complications with calcareous microfossil preservation in Arctic Ocean sediments, calcareous benthic foraminifera can be common in interglacial sequences. However, thus far they have been underutilized in palaeoceanographic studies. This thesis explores the application of the Mg/Ca palaeothermometry proxy for reconstructing bottom water temperatures (BWT) in the Arctic Ocean during the late Quaternary. This method, which is supported by previous empirical studies demonstrating a strong temperature control on trace Mg inclusion into foraminiferal shell calcite, has been applied in many ocean regions and time intervals. Until now its application in the Arctic Ocean has been sparingly explored.The results of this doctoral thesis are based on benthic foraminifera retrieved from marine sediment cores covering a wide geographical Arctic Ocean area including both the shallow and vast continental shelves and slopes to the intermediate-to-deep waters of the Lomonosov Ridge and Morris Jesup Rise. These provide the first benthic foraminifera Mg/Ca ratios from the central Arctic Ocean region. In the first study, mechanisms that could affect Mg incorporation in Arctic benthic foraminifera are investigated using oceanographic field data and six 'live' modern Arctic species (Elphidium clavatum, Nonionella labradorica, Cassidulina neoteretis, Oridorsalis tener, Cibicidoides wuellerstorfi and Quinqueloculina arctica). The result is new species-specific Mg/Ca–BWT field calibrations that provide important constraints at the cold end of the BWT spectrum (-2 to 1°C) (Paper I). Using the new Mg/Ca–BWT equation for E. clavatum, a palaeotemperature record was generated for the late Holocene (past ca. 4100 yr) from the western Chukchi Sea. The data showed BWT fluctuations from -2 to 1°C that are interpreted as showing pulses of warmer Pacific water inflow at 500–1000 yr periods, thus revealing multi-centennial variability in heat transport into the Arctic Ocean driven by low latitude forcings (Paper II). Complications with foraminiferal calcite preservation that limit Mg/Ca palaeothermometry in the Arctic were discovered and these are tackled in two additional papers. Anomalously high Mg content in benthic foraminifera from the central Arctic Ocean is linked to diagenetic contamination as a result of the unique oceanographic, sedimentary and geochemical environment (Paper III). Lastly, the dramatic post-recovery dissolution of foraminifera from a Chukchi Shelf sediment core during core storage is investigated and attributed to acidification driven by sulphide oxidation in this organic rich and calcite poor shelf setting (Paper IV).The findings of this thesis demonstrate that benthic foraminiferal Mg/Ca-palaeothermometry can be applied in the Arctic Ocean and capture small BWT change (on the order of -2 to 2°C) even at low temperatures. In practice, preservational complexities can be limiting and require special sample handling or analysis due to the high potential for diagenetic contamination in the central Arctic Ocean and rapid post coring calcite dissolution in the seasonally productive shelf seas. This Ph.D. project is a component of the multidisciplinary SWERUS-C3 (Swedish-Russian-US Arctic Ocean Climate-Cryosphere- Carbon Interactions) project that included an expedition with Swedish icebreaker Oden to the East Siberian Arctic Ocean.
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| 56. |
- Erlandsson, M., et al.
(författare)
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Spatial and temporal variations of base cation release from chemical weathering on a hillslope scale
- 2016
-
Ingår i: Chemical Geology. - : Elsevier BV. - 0009-2541 .- 1872-6836. ; 441, s. 1-13
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Tidskriftsartikel (refereegranskat)abstract
- Cation release rates to catchment runoff from chemical weathering were assessed using an integrated catchment model that included the soil's unsaturated, saturated and riparian zones. In-situ mineral dissolution rates were calculated in these zones as a function of pH, aluminum and dissolved organic carbon (DOC) concentrations along a hillslope in Northern Sweden where soil water was monitored over nine years. Three independent sets of mineral dissolution equations of varying complexity were used: PROFILE, Transition-State Theory (TST), and the Palandri & Kharaka database. Normalization of the rate-coefficients was necessary to compare the equations, as published rate-coefficients gave base cation release rates differing by several orders of magnitude. After normalizing the TST- and Palandri & Kharaka-rate coefficients to match the base cation release rates calculated from the PROFILE-equations, calculated Ca2 + and Mg2 + release rates are consistent with mass balance calculations, whereas those of Na+ and K+ are overestimated. Our calculations further indicate that a significant proportion of base cations are released from the organic soils in the near-stream zone, in part due to its finer texture. Of the three sets of rate equations, the base cation release rates calculated from the normalized TST-equations were more variable than those calculated using the other two sets of equations, both spatially and temporally, due to its higher sensitivity to pH. In contrast, the normalized Palandri & Kharaka-equations were more sensitive to variations in soil temperature.
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| 57. |
- Ljungberg, Wilma, 1998, et al.
(författare)
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Carbon Outwelling and Uptake Along a Tidal Glacier-Lagoon-Ocean Continuum
- 2024
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Ingår i: Journal of Geophysical Research (JGR): Biogeosciences. - 2169-8953 .- 2169-8961. ; 129:e2023JG007895
-
Tidskriftsartikel (refereegranskat)abstract
- Tidewater glaciers are highly vulnerable to climate change due to warming from both atmospheric and seawater sources. Most tidewater glaciers are rapidly retreating, but little is known about how glacial melting modifies coastal biogeochemical cycles. Here, we investigate carbonate and nutrient dynamics and fluxes in an expanding proglacial tidal lagoon connected to Europe's largest glacier in Iceland (Vatnajökull). The lagoon N:P:Si ratios (2:1:30) imply a system deficient in nitrogen. The large variations in the freshwater endmembers highlighted the complexity of resolving sources and transformations. The lagoon acted as a sink of dissolved inorganic carbon (DIC). Floating chamber incubations revealed a CO2 uptake of 26±15mmolm−2d−1. Lagoon waters near the glacier had a 170% higher CO2 uptake than near the lagoon mouth, likely driven by primary production stimulated by nitrogen-rich bottom water upwelling. The lateral DIC and total alkalinity (TA) flux rates (outwelling) from the lagoon to the ocean were −1.5±0.1 (export to ocean) and 23±5mmolm−2d−1 (import into the lagoon) respectively. All samples were undersaturated with respect to aragonite due to glacial meltwater dilution of TA and CO2 uptake. This implies dilution of oceanic alkalinity, lowering the nearshore buffering capacity against ocean acidification.
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| 58. |
- Peacock, Mike, et al.
(författare)
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Spatial and Seasonal Variations in Dissolved Methane Across a Large Lake
- 2023
-
Ingår i: Journal of Geophysical Research - Biogeosciences. - : American Geophysical Union (AGU). - 2169-8953 .- 2169-8961. ; 128:8
-
Tidskriftsartikel (refereegranskat)abstract
- Lakes process large volumes of organic carbon (OC), are important sources of methane (CH4), and contribute to climatic warming. However, there is a lack of data from large lakes >500 km(2), which creates uncertainty in global budgets. In this data article, we present dissolved CH4, OC bioreactivity measurements, water chemistry, and algal biovolumes at 11 stations across Lake Malaren, the third largest (1,074 km(2)) Swedish lake. Total phosphorus concentrations show that during the study period the lake was classed as mesotrophic/eutrophic. Overall mean CH4 concentration from all stations, sampled five times to cover seasonal variation, was 2.51 mu g l(-1) (0.98-5.39 mu g l(-1)). There was no significant seasonal variation although ranges were greatest during summer. Concentrations of CH4 were greatest in shallow waters close to anthropogenic nutrient sources, whilst deeper, central basins had lower concentrations. Methane correlated positively with measures of lake productivity (chlorophyll a, total phosphorus), and negatively to water depth and oxygen concentration, with oxygen emerging as the sole significant driver in a linear mixed effects model. We collated data from other lakes >500 km(2) (n = 21) and found a significant negative relationship between surface area and average CH4 concentration. Large lakes remain an understudied contributor to the global CH4 cycle and future research efforts should aim to quantify the spatial and temporal variation in their diffusive and ebullitive emissions, and associated drivers. Plain Language Summary Lakes contribute to climatic warming, because they emit large amounts of the powerful greenhouse gas methane into the atmosphere. This occurs because lake bottom sediments and lake waters are home to microbes that produce methane, which then travels diffusively in a dissolved form, or as bubbles, through the lake water and into the air. There is large uncertainty about how much methane is released by lakes on a global scale, and more measurements are required to reduce this uncertainty, particularly from very large lakes. In our study, we measured dissolved methane from 11 sampling locations across a very large Swedish lake, and repeated this five times over a year. Levels of methane within the lake were generally low, but they varied over space and time. Higher methane levels occurred in shallower waters near large towns and cities, and were associated with greater concentrations of nutrients such as phosphorus, which act as food for the methane-producing microbes.
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| 59. |
- Teutschbein, Claudia, 1985-, et al.
(författare)
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Future Riverine Inorganic Nitrogen Load to the Baltic Sea From Sweden : An Ensemble Approach to Assessing Climate Change Effects
- 2017
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Ingår i: Global Biogeochemical Cycles. - : American Geophysical Union (AGU). - 0886-6236 .- 1944-9224. ; 31:11, s. 1674-1701
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Tidskriftsartikel (refereegranskat)abstract
- The dramatic increase of bioreactive nitrogen entering the Earth’s ecosystems continues toattract growing attention. Increasingly large quantities of inorganic nitrogen are flushed from land towater, accelerating freshwater, and marine eutrophication. Multiple, interacting, and potentiallycountervailing drivers control the future hydrologic export of inorganic nitrogen. In this paper, we attempt toresolve these land-water interactions across boreal/hemiboreal Sweden in the face of a changing climatewith help of a versatile modeling framework to maximize the information value of existing measurementtime series. We combined 6,962 spatially distributed water chemistry observations spread over 31 years withdaily streamflow and air temperature records. An ensemble of climate model projections, hydrologicalsimulations, and several parameter parsimonious regression models was employed to project future riverineinorganic nitrogen dynamics across Sweden. The median predicted increase in total inorganic nitrogenexport from Sweden (2061–2090) due to climate change was 14% (interquartile range 0–29%), based on theensemble of 7,500 different predictions for each study site. The overall export as well as the seasonal patternof inorganic nitrogen loads in a future climate are mostly influenced by longer growing seasons and morewinter flow, which offset the expected decline in spring flood. The predicted increase in inorganic nitrogenloading due to climate change means that the political efforts for reducing anthropogenic nitrogen inputsneed to be increased if ambitions for reducing the eutrophication of the Baltic Sea are to be achieved.
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| 60. |
- Rämö, Robert, et al.
(författare)
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Sediment Remediation Using Activated Carbon: Effects of Sorbent Particle Size and Resuspension on Sequestration of Metals and Organic Contaminants.
- 2022
-
Ingår i: Environmental toxicology and chemistry. - : Wiley. - 1552-8618 .- 0730-7268. ; 41:4, s. 1096-1110
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Tidskriftsartikel (refereegranskat)abstract
- Thin-layer capping using activated carbon (AC) has been described as a cost-effective in situ sediment remediation method for organic contaminants. In this study, we compare the capping efficiency of powdered AC (PAC) against granular AC (GAC) using contaminated sediment from Oskarshamn harbor, Sweden. The effects of resuspension on contaminant retention and cap integrity were also studied. Intact sediment cores were collected from the outer harbor and brought to the laboratory. Three thin-layer caps, consisting of PAC or GAC mixed with clay, or clay only, were added to the sediment surface. Resuspension was created using a motor-driven paddle to simulate propeller wash from ship traffic. Passive samplers were placed in the sediment and in the water column to measure the sediment-to-water release of PAHs, PCBs, and metals. Our results show that a thin-layer cap with PAC reduced sediment-to-water fluxes of PCBs by 57 % under static conditions and 91 % under resuspension. Thin-layer capping with GAC was less effective than PAC, but reduced fluxes of high-molecular weight PAHs. Thin-layer capping with AC was less effective in retaining metals, except for Cd, which release was significantly reduced by PAC. Resuspension generally decreased water concentrations of dissolved cationic metals, perhaps due to sorption to suspended sediment particles. Sediment resuspension in treatments without capping increased fluxes of PCBs with log Kow > 7 and PAHs with log Kow 5 6, but resuspension reduced PCB and PAH fluxes through the PAC thin-layer cap. Overall, PAC performed better than GAC, but adverse effects on the benthic community and transport of PAC to non-target areas are drawbacks that favor the use of GAC. This article is protected by copyright. All rights reserved.© 2022 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.
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