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41.
  • Di, Jing, et al. (författare)
  • A novel composite electrolyte based on CeO2 for low temperature solid oxide fuel cells
  • 2008
  • Ingår i: Journal of Inorganic Materials. - 1000-324X. ; 23:3, s. 573-577
  • Tidskriftsartikel (refereegranskat)abstract
    • <p>A novel composite material based on mixture of samarium-doped ceria (SDC)-carbonate was studied as electrolyte in low temperature solid oxide fuel cells. The phase and microstructures of composite electrolyte were examined by XRD and SEM. The electrical conductivity was investigated by AC impedance spectroscopy at 400-700 degrees C in different atmospheres. An abrupt change in the conductivity at about 500 degrees C indicates that different mechanisms affect transfer in different temperature ranges. The conductivity increases with the carbonate fraction above 500 degrees C. The conductivity in reduce atmosphere is higher than that in oxide atmosphere. An anode-supported fuel cell using SDC-carbonate as electrolyte was fabricated and tested. The result shows that all the composite electrolytes exhibit better performance than pure SDC electrolyte. The electrolyte with 20wt% carbonate can achieve the highest power density of 415mW center dot cm(-2) and an open circuit voltage of 1.00V at 500 degrees C.</p>
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42.
  • Di, J., et al. (författare)
  • Low temperature solid oxide fuel cells with SDC-carbonate electrolytes
  • 2010
  • Ingår i: Chinese Ceramics Communications. - Trans Tech Publications Inc.. - 0878492755 - 978-087849275-6 ; s. 687-690
  • Konferensbidrag (refereegranskat)abstract
    • <p>Composites consisting of Ce0.8Sm0.2O1.9 (SDC)-carbonate were developed as electrolytes for low temperature solid oxide fuel cells (LTSOFC). The SDC power was prepared by sol-gel method. The carbonates were binary eutectics of (Li/Na)2CO3, (Li/K)2CO3 and (K/Na)2CO3. Conductivity measurements showed that the conductivities were depended on the type of carbonates. Discontinuities were found in the Arrhenius plots for both SDC-(Li/Na)2CO3 and SDC-(Li/K)2CO3. For SDC-(Na/K)2CO3 composite electrolyte, the conductivity increased as temperature rose following one slope. Single cells based on various composites were fabricated by a uniaxial die-press method and tested at 450-600 °C. The results showed all cells exhibited improved performances upon that of pure SDC-based cell. The best power density of 532 mW cm -2 at 600 °C was achieved for LTSOFC using composite of SDC and (Li/Na)2CO3. Conductivity mechanism was also discussed.</p>
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43.
  • Di, Jing, et al. (författare)
  • Samarium doped ceria-(Li/Na)(2)CO3 composite electrolyte and its electrochemical properties in low temperature solid oxide fuel cell
  • 2010
  • Ingår i: Journal of Power Sources. - 0378-7753 .- 1873-2755. ; 195:15, s. 4695-4699
  • Tidskriftsartikel (refereegranskat)abstract
    • <p>A composite of samarium doped ceria (SDC) and a binary carbonate eutectic (52 mol% Li2CO3/48 mol% Na2CO3) is investigated with respect to its morphology, conductivity and fuel cell performances. The morphology study shows the composition could prevent SDC particles from agglomeration. The conductivity is measured under air, argon and hydrogen, respectively. A sharp increase in conductivity occurs under all the atmospheres, which relates to the superionic phase transition in the interface phases between SDC and carbonates. Single cells with the composite electrolyte are fabricated by a uniaxial die-press method using NiO/electrolyte as anode and lithiated NiO/electrolyte as cathode. The cell shows a maximum power density of 590 mW cm(-2) at 600 degrees C, using hydrogen as the fuel and air as the oxidant. Unlike that of cells based on pure oxygen ionic conductor or pure protonic conductor, the open circuit voltage of the SDC-carbonate based fuel cell decreases with an increase in water content of either anodic or cathodic inlet gas, indicating the electrolyte is a co-ionic (H+/O2-) conductor. The results also exhibit that oxygen ionic conductivity contributes to the major part of the whole conductivity under fuel cell circumstances. (C) 2010 Elsevier B.V. All rights reserved.</p>
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44.
  • Dong, Wenjing, et al. (författare)
  • Charge transport study of perovskite solar cells through constructing electron transport channels
  • 2017
  • Ingår i: Physica Status Solidi (a) applications and materials science. - Wiley-VCH Verlagsgesellschaft. - 1862-6300 .- 1862-6319. ; 214:10
  • Tidskriftsartikel (refereegranskat)abstract
    • <p>Perovskite solar cells (PSC) have attracted much attention in the recent years. It is important to understand their working principle in order to uncover the reasons behind their high efficiency. In this study, the carrier transport mechanism of PSC by controlling the structure of a scaffold is investigated. CeO2 is used as an electron blocking material in PSCs to study the electron transport behavior for the first time. The influence of light absorption can be excluded because CeO2 has a similar bandgap to TiO2. A variety of scaffolds are constructed using nano-TiO2 and CeO2. The results show that electrons can transport from light absober (perovskite) to FTO electrode (external circuit) through two kinds of channels. The energy band level, as well as the electronic conductivity of the scaffolds, is are key issues that affect electron transport. Although perovskites are able to transport both electrons and holes, it is still necessary to have effective electron transport channels (ETCs) between perovskite and external circuit for the sake of high efficiency. Electrochemical impedance spectroscopy analysis suggests that the lack of such channels will result in high recombination. The number of ETCs and effecient electron-hole separation are also proven to be important for cell performance.</p>
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45.
  • Elsik, Christine G., et al. (författare)
  • The Genome Sequence of Taurine Cattle : A Window to Ruminant Biology and Evolution
  • 2009
  • Ingår i: Science. - 0036-8075 .- 1095-9203. ; 324:5926, s. 522-528
  • Tidskriftsartikel (refereegranskat)abstract
    • <p>To understand the biology and evolution of ruminants, the cattle genome was sequenced to about sevenfold coverage. The cattle genome contains a minimum of 22,000 genes, with a core set of 14,345 orthologs shared among seven mammalian species of which 1217 are absent or undetected in noneutherian (marsupial or monotreme) genomes. Cattle-specific evolutionary breakpoint regions in chromosomes have a higher density of segmental duplications, enrichment of repetitive elements, and species-specific variations in genes associated with lactation and immune responsiveness. Genes involved in metabolism are generally highly conserved, although five metabolic genes are deleted or extensively diverged from their human orthologs. The cattle genome sequence thus provides a resource for understanding mammalian evolution and accelerating livestock genetic improvement for milk and meat production.</p>
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46.
  • Fan, Jin, et al. (författare)
  • Design of Novel Flat Bend Crossed Dipole for Wideband Phased Array Feed Applications
  • 2019
  • Ingår i: 2019 International Symposium on Antennas and Propagation, ISAP 2019 - Proceedings.
  • Konferensbidrag (refereegranskat)abstract
    • This paper presents a novel Phased Array Feed (PAF) element based on flat bend crossed dipole fed by 50-Ohm coaxial line. The PAF element is dual-polarized and made from all-metal to minimize Ohmic losses and simplify cryogenic integration. It is optimized for 4- 8 GHz band aiming to possible later integration in the SKA pathfinder PHAROS2. The proposed design can also be a good element candidate of PAF for the Five hundred meter Aperture Spherical Telescope (FAST) and Qi Tai Telescope (QTT) as well as other large radio telescopes.
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47.
  • Fan, Jin, et al. (författare)
  • Design of Octave-bandwidth Phased Array Feed for Large Radio Telescope
  • 2019
  • Ingår i: 2019 13TH EUROPEAN CONFERENCE ON ANTENNAS AND PROPAGATION (EUCAP). - 2164-3342. - 978-8-8907-0188-7
  • Konferensbidrag (refereegranskat)abstract
    • This paper presents design scenarios of Octave-bandwidth Phase Array Feed (PAF) based on a novel wideband dual polarized tightly-fed Bowtie antenna element. The PAF is optimized for the 4 - 8GHz band aiming to possible later integration in the SKA pathfinder PHAROS2. The proposed design can be a good candidate of PAF for the Five hundred meter Aperture Spherical Telescope (FAST) and Qi Tai Telescope (QTT) as well as other large radio telescopes.
48.
  • Fan, Liangdong, et al. (författare)
  • Electrolysis study of ceria-carbonate composite for effective H2 production
  • 2013
  • Ingår i: EFC 2013 - Proceedings of the 5th European Fuel Cell Piero Lunghi Conference. - 978-888286297-8 ; s. 79-80
  • Konferensbidrag (refereegranskat)abstract
    • <p>The hybrid ionic conduction of ceria-carbonate composite is an interesting field that has attracted plenty attention in the past decade. However, it has not reached universal agreement among the researcher. Novel characterization method is still needed to reveal this complex system and benefit the future advanced materials design and development. In this work, the electrolysis operation is employed to investigate the possible ionic conduction behavior of ceria-carbonate. The other goal is to optimize the processing technology to maximum the kinetics rate for efficient hydrogen production. An impressive current density of 1.2 A cm-2 has been achieved at 600 °C under voltage of 1.6 V at the absolute humidity of 3% and oxygen ionic operational mode.</p>
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49.
  • Fan, Liangdong, 1985-, et al. (författare)
  • High performance transition metal oxide composite cathode for low temperature solid oxide fuel cells
  • 2012
  • Ingår i: Journal of Power Sources. - 0378-7753 .- 1873-2755. ; 203:1, s. 65-71
  • Tidskriftsartikel (refereegranskat)abstract
    • <p>Low temperature solid oxide fuel cells (SOFCs) with metal oxide composite cathode on the ceria–carbonate composite electrolyte have shown promising performance. However, the role of individual elements or compound is seldom investigated. We report here the effect of the ZnO on the physico-chemical and electrochemical properties of lithiated NiO cathode. The materials and single cells are characterized by X-ray diffraction, scanning electron microscopy, DC polarization electrical conductivity, electrochemical impedance spectroscopy and fuel cell performance. The ZnO modified lithiated NiO composite materials exhibit smaller particle size and lower electrical conductivity than lithiated NiO. However, improved electro-catalytic oxygen reduction activity and power output are achieved after the ZnO modification. A maximum power density of 808 mW cm<sup>−2</sup> and the corresponding interfacial polarization resistance of 0.22 Ω cm<sup>2</sup> are obtained at 550 °C using ZnO modified cathode and 300 μm thick composite electrolyte. The single cell keeps reasonable stability over 300 min at 500 °C. Thus, ZnO modified lithiated NiO is a promising cathode candidate for low temperature SOFCs.</p>
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50.
  • Fan, Liangdong, et al. (författare)
  • Low temperature ceramic fuel cells using all nano-composite materials
  • 2011
  • Ingår i: EFC 2011 - Proceedings of the 4th European Fuel Cell Piero Lunghi Conference and Exhibition. - 9788882862541 ; s. 175-176
  • Konferensbidrag (refereegranskat)abstract
    • <p>Nano-structural components have attracted increasing attention in intermediate/low temperature ceramic fuel cell. We reported here a ceramic fuel cell with a configuration of (Ni/Fe)-NSDC/NSDC/LiNiZnO-NSDC by all nano-composite materials and operated at low temperature range of 500-600°C. The prepared nanocomposite materials are characterized by X-ray diffraction (XRD), Emission scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). Electrochemical performances were studied by current -Voltage, power density characteristics and Ac impedance spectroscopy. The short term stability of fuel cell was also investigated in 100 min. The high fuel cell performance and reasonable stability demonstrated that the all nanocomposite fuel cell concept is feasible and may have great potential in future study.</p>
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