| 41. |
- Bao, Jie, 1982, et al.
(författare)
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Two-dimensional hexagonal boron nitride as lateral heat spreader in electrically insulating packaging
- 2016
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Ingår i: Journal of Physics D: Applied Physics. - : IOP Publishing. - 1361-6463 .- 0022-3727. ; 49:July 2016, s. 265501-
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Tidskriftsartikel (refereegranskat)abstract
- The need for electrically insulating materials with a high in-plane thermal conductivity for lateral heat spreading applications in electronic devices has intensified studies of layered hexagonal boron nitride (h-BN) films. Due to its physicochemical properties, h-BN can be utilised in power dissipating devices such as an electrically insulating heat spreader material for laterally redistributing the heat from hotspots caused by locally excessive heat flux densities. In this study, two types of boron nitride based heat spreader test structures have been assembled and evaluated for heat dissipation. The test structures separately utilised a few-layer h-BN film with and without graphene enhancement drop coated onto the hotspot test structure. The influence of the h-BN heat spreader films on the temperature distribution across the surface of the hotspot test structure was studied at a range of heat flux densities through the hotspot. It was found that the graphene-enhanced h-BN film reduced the hotspot temperature by about 8–10°C at a 1000 W/cm2 heat flux density, a temperature decrease significantly larger than for h-BN film without graphene enhancement. Finite element simulations of the h-BN film predict that further improvements in heat spreading ability are possible if the thermal contact resistance between the film and test chip are minimised.
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| 42. |
- Cao, Yuehan, et al.
(författare)
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Modulating electron density of vacancy site by single Au atom for effective CO2 photoreduction
- 2021
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Ingår i: Nature Communications. - : Springer Science and Business Media LLC. - 2041-1723. ; 12:1
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Tidskriftsartikel (refereegranskat)abstract
- The surface electron density significantly affects the photocatalytic efficiency, especially the photocatalytic CO2 reduction reaction, which involves multi-electron participation in the conversion process. Herein, we propose a conceptually different mechanism for surface electron density modulation based on the model of Au anchored CdS. We firstly manipulate the direction of electron transfer by regulating the vacancy types of CdS. When electrons accumulate on vacancies instead of single Au atoms, the adsorption types of CO2 change from physical adsorption to chemical adsorption. More importantly, the surface electron density is manipulated by controlling the size of Au nanostructures. When Au nanoclusters downsize to single Au atoms, the strong hybridization of Au 5d and S 2p orbits accelerates the photo-electrons transfer onto the surface, resulting in more electrons available for CO2 reduction. As a result, the product generation rate of AuSA/Cd1−xS manifests a remarkable at least 113-fold enhancement compared with pristine Cd1−xS.
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| 43. |
- Chen, Huang, et al.
(författare)
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A portable micro glucose sensor based on copper-based nanocomposite structure
- 2019
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Ingår i: New Journal of Chemistry. - : Royal Society of Chemistry (RSC). - 1369-9261 .- 1144-0546. ; 43:20, s. 7806-7813
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Tidskriftsartikel (refereegranskat)abstract
- Precisely detecting the concentration of glucose in the human body is an attractive way to prevent or treat diabetes. Portable glucose sensors with non-enzymatic catalytic materials have received great attention in recent years. Herein, a facile strategy for fabricating a high-performance electrochemical sensor is proposed. A non-enzymatic three-electrode integrated glucose sensor device based on CuO nano-coral arrays/nanoporous Cu (NCA/NPC) is designed and fabricated. The portable NCA/NPC glucose sensor device exhibits high catalytic activity for glucose. The great performance of the NCA/NPC glucose sensor device derives from the excellent conductivity of the NPC substrate and the high electrocatalytic activity of CuO nano-coral arrays. This device exhibits a high sensitivity of 1621 μA mM -1 cm -2 in the linear range of 0.0005-5.0 mM, low detection limit of 200 nM (S/N = 3), fast response time of 3 s, good anti-interference performance, excellent repeatability and considerable stability for glucose detection. This work will certainly provide an efficient structure and proper catalytic material choices for future non-enzymatic glucose sensors.
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| 44. |
- Chen, Hui, et al.
(författare)
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Association of Long-Term Body Weight Variability With Dementia : A Prospective Study
- 2021
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Ingår i: The journals of gerontology. Series A, Biological sciences and medical sciences. - : Oxford University Press (OUP). - 1079-5006 .- 1758-535X. ; 77:10, s. 2116-2122
-
Tidskriftsartikel (refereegranskat)abstract
- Background: Body weight variability (BWV) refers to intraindividual weight loss and gain over a period. The association of long-term BWV with dementia remains unclear and whether this association is beyond body weight change is undetermined.Methods: In the Health and Retirement Study, a total of 5 547 dementia-free participants (56.7% women; mean [SD] age, 71.1 [3.2] years) at baseline (2008) were followed up to 8 years (mean = 6.8 years) to detect incident dementia. Body weight was self-reported biennially from 1992 to 2008. BWV was measured as the coefficient of variation utilizing the body weight reported 9 times across 16 years before baseline. Cox-proportional hazard model was used to estimate the hazard ratio (HR) and 95% confidence interval (CI).Results: Among the 5 547 participants, a total of 427 incident dementia cases were identified during follow-up. Greater long-term BWV was significantly associated with a higher risk of dementia (HR comparing extreme quartiles: 2.01, 95% CI: 1.48-2.72; HR of each SD increment: 1.21, 95% CI: 1.10-1.32; p-trend < .001) independent of mean body weight and body weight change. This significant association was even observed for BWV estimated approximately 15 years preceding dementia diagnosis (HR of each SD increment: 1.13, 95% CI: 1.03-1.23) and was more pronounced for that closer to diagnosis.Conclusion: Our prospective study suggested that greater BWV may be a novel risk factor for dementia.
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| 45. |
- Chen, Hanwei, et al.
(författare)
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Tumor Volumes Measured From Static and Dynamic F-18-fluoro-2-deoxy-D-glucose Positron Emission Tomography-Computed Tomography Scan : Comparison of Different Methods Using Magnetic Resonance Imaging as the Criterion Standard
- 2014
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Ingår i: Journal of computer assisted tomography. - 0363-8715 .- 1532-3145. ; 38:2, s. 209-215
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Tidskriftsartikel (refereegranskat)abstract
- Objective: The objective of this study was to compare the accuracy of calculating the primary tumor volumes using a gradient-based method and fixed threshold methods on the standardized uptake value (SUV) maps and the net influx of FDG (Ki) maps from positron emission tomography-computed tomography (PET-CT) images. Materials and Methods: Newly diagnosed patients with head and neck cancer were recruited, and dynamic PET-CT scan and T2-weighted magnetic resonance imaging were performed. The maps of Ki and SUV were calculated from PET-CT images. The tumor volumes were calculated using a gradient-based method and a fixed threshold method at 40% of maximal SUV or maximal Ki. Four kinds of volumes, VOLKi-Gra (from the Ki maps using the gradient-based method), VOLKi-40% (from the Ki maps using the threshold of 40% maximal Ki), VOLSUV-Gra (from the SUV maps using the gradient-based method), and VOLSUV-40% (from the SUV maps using the threshold of 40% maximal SUV), were acquired and compared with VOLMRI (the volumes acquired on T2-weighted images) using the Pearson correlation, paired t test, and similarity analysis. Results: Eighteen patients were studied, of which 4 had poorly defined tumors (PDT). The positron emission tomography-derived volumes were as follows: VOLSUV-40%, 2.1 to 41.2 cm(3) (mean [SD], 12.3 [10.6]); VOLSUV-Gra, 2.2 to 28.1 cm(3) (mean [SD], 13.2 [8.4]); VOLKi-Gra, 2.4 to 17.0 cm(3) (mean [SD], 9.5 [4.6]); and VOLKi-40%, 2.7 to 20.3 cm(3) (mean [SD], 12.0 [6.0]). The VOLMRI ranged from 2.9 to 18.1 cm(3) (mean [SD], 9.1 [3.9]). The VOLKi-Gra significantly correlated with VOLMRI with the highest correlation coefficient (PDT included, R = 0.673, P = 0.002; PDT excluded, R = 0.841, P < 0.001) and presented no difference from VOLMRI (P = 0.672 or 0.561, respectively, PDT included and excluded). The difference between VOLKi-Gra and VOLMRI was also the smallest. Conclusions: The tumor volumes delineated on the Ki maps using the gradient-based method are more accurate than those on the SUV maps and using the fixed threshold methods.
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| 46. |
- Chen, Jie, et al.
(författare)
-
Northwestward shift of the northern boundary of the East Asian summer monsoon during the mid-Holocene caused by orbital forcing and vegetation feedbacks
- 2021
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Ingår i: Quaternary Science Reviews. - : Elsevier BV. - 0277-3791 .- 1873-457X. ; 268
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Tidskriftsartikel (refereegranskat)abstract
- The East Asian summer monsoon (EASM) northern boundary is a critical indicator of EASM variations. Movement of the boundary is modulated by both the EASM and the mid-latitude westerlies. Here, we use the Earth system model EC-Earth to quantify the contribution of orbital forcing and vegetation feedbacks in modulating the movement of EASM northern boundary. The results show that the simulated EASM northern boundary during the mid-Holocene shifts by a maximum of ∼213 km northwestward due to orbital forcing. When the model was coupled with a dynamic vegetation module LPJ-GUESS, the northern boundary shifts further northwestward by a maximum of ∼90 km, indicating the importance of vegetation feedbacks. During the mid-Holocene, temperature increased in the mid-latitude during the boreal summer due to insolation, leading to increased meridional air temperature differences (MTDs) over the region north of 45°N and to decreased MTDs to the south. The changes in the temperature gradient weakened the East Asian Westly Jet (EAWJ) and displaced it northward, resulting in an earlier transition of the Meiyu stage and a more prolonged Midsummer stage. The northward movement of EAWJ, combined with the enhanced southerly moisture flow from South China, caused more precipitation in North China and eventually to a northwestward shift of the northern boundary of the EASM. The coupled dynamic vegetation module LPJ-GUESS simulated more grassland and less forest over Northeast Asia during the mid-Holocene. The increased surface albedo tended to lower the temperature in the region, and further enhanced the MTDs in mid-latitude East Asia, leading to the further northward movement of the EAWJ and a northwestward shift of the EASM northern boundary. Although the simulated vegetation distribution in several regions may be not accurate, it reflects the substantial contribution of climate-vegetation interaction on modulating the EASM.
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| 47. |
- Chen, Jie, et al.
(författare)
-
Origin of the spatial consistency of summer precipitation variability between the Mongolian Plateau and the mid-latitude East Asian summer monsoon region
- 2020
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Ingår i: Science China. Earth Sciences. - : Springer Science and Business Media LLC. - 1674-7313 .- 1869-1897. ; 63:8, s. 1199-1208
-
Tidskriftsartikel (refereegranskat)abstract
- The Mongolian Plateau (MP) is located in the eastern part of arid Central Asia (ACA). Climatically, much of the MP is dominated by the westerly circulation and has an arid and semi-arid climate; however, the eastern part of the MP is also influenced by the East Asian summer monsoon (EASM) and has a humid and semi-humid climate. Several studies have shown that precipitation variability in the MP differs from that in western ACA but is consistent with that in the EASM region. Here we use monthly precipitation data for 1979-2016 to characterize and determine the origin of the summer precipitation variability of the MP and the EASM region. The results show that the MP and the mid-latitude EASM region exhibit a consistent pattern of precipitation variability on interannual and decadal timescales; specifically, the consistent regions are the MP and North and Northeast China. We further investigated the physical mechanisms responsible for the consistent interdecadal precipitation variability between the MP and the mid-latitude EASM region, and found that the mid-latitude wave train over Eurasia, with positive (negative) geopotential height anomalies over the North Atlantic and ACA and negative (positive) geopotential height anomalies over Europe and the MP, is the key factor responsible for the consistency of precipitation variability in the MP and the mid-latitude EASM region. The positive anomalies over the North Atlantic and ACA and negative anomalies over Europe and the MP would enhance the transport of westerly and monsoon moisture to the MP and North and Northeast China. They could also strengthen the Northeast Asian low, enhance the EASM, and trigger the anomalous ascending motion over the MP which promotes precipitation in the MP and in the mid-latitude EASM region. Overall, our results help explain the spatial variations of paleo-precipitation/humidity reconstructions in East Asia and clarify the reasons for the consistency of the regional climate.
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| 48. |
- Chen, Jie, et al.
(författare)
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Reconciling East Asia's mid-Holocene temperature discrepancy through vegetation-climate feedback
-
Ingår i: Science Bulletin. - 2095-9273.
-
Tidskriftsartikel (refereegranskat)abstract
- The term “Holocene temperature conundrum” refers to the inconsistencies between proxy-based reconstructions and transient model simulations, and it challenges our understanding of global temperature evolution during the Holocene. Climate reconstructions indicate a cooling trend following the Holocene Thermal Maximum, while model simulations indicate a consistent warming trend due to ice-sheet retreat and rising greenhouse gas concentrations. Various factors, such as seasonal biases and overlooked feedback processes, have been proposed as potential causes for this discrepancy. In this study, we examined the impact of vegetation-climate feedback on the temperature anomaly patterns in East Asia during the mid-Holocene (∼6 ka). By utilizing the fully coupled Earth system model EC-Earth and performing simulations with and without coupled dynamic vegetation, our objective was to isolate the influence of vegetation changes on regional temperature patterns. Our findings reveal that vegetation-climate feedback contributed to warming across most of East Asia, resulting in spatially diverse temperature changes during the mid-Holocene and significantly improved model-data agreement. These results highlight the crucial role of vegetation-climate feedback in addressing the Holocene temperature conundrum and emphasize its importance for simulating accurate climate scenarios.
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| 49. |
- Chen, Jie, et al.
(författare)
-
The modulation of westerlies-monsoon interaction on climate over the monsoon boundary zone in East Asia
- 2021
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Ingår i: International Journal of Climatology. - : Wiley. - 0899-8418 .- 1097-0088. ; 41:S1, s. E3049-E3064
-
Tidskriftsartikel (refereegranskat)abstract
- Monsoon boundary zone (MBZ) is a transitional zone between the arid Central Asia (ACA) and humid Asia monsoon area, located in North China-Mongolia. During boreal summer, both the mid-latitude westerlies and East Asian Summer monsoon (EASM) play essential roles in the precipitation variations in the MBZ, via causing anomalous cold air mass from the west and warm/humid air from the south to the MBZ. In this study, we defined a summer westerly index (SWI) over the key westerly domain (35 degrees-42.5 degrees N, 80 degrees-100 degrees E) and an EASM index (EASMI) over the key EASM domain (25 degrees-35 degrees N, 107.5 degrees-125 degrees E) to investigate westerlies-monsoon interaction and their effect on MBZ climate. The results show that westerlies and EASM have a synergistic effect on the precipitation in the MBZ and this synergistic effect could be amplified by the westerlies-monsoon interaction. The westerlies and EASM interaction could induce a local cyclonic anomaly in the MBZ, this cyclonic anomaly further intensifies the westerlies and monsoon flow through a dynamical amplification, favours the precipitation in the MBZ. The MBZ precipitation also contributes to maintain the cyclonic anomaly via the latent heating release. The interannual variability of westerlies is largely modulated by the mid-latitude Silk Road pattern (SRP) and the meridional displacement of the Asian westerly jet (AWJ), and the EASM variability is mainly modulated by El Nino-Southern Oscillation (ENSO), the combined effects from these mid-latitude circulation systems and tropical SST contribute to the climate variability in MBZ.
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| 50. |
- Chen, Shi-Peng, et al.
(författare)
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Guanidine-based protic ionic liquids as highly efficient intermolecular scissors for dissolving natural cellulose
- 2023
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Ingår i: Green Chemistry. - : Royal Society of Chemistry. - 1463-9262 .- 1463-9270. ; 25:22, s. 9322-9334
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Tidskriftsartikel (refereegranskat)abstract
- The development of highly efficient and environmentally friendly solvents for dissolving cellulose, which is the most abundant natural polymer on Earth, remains a challenge, hindering its full utilization. Herein, a green protic ionic liquid, 1,1,3,3-tetramethylguanidinium methoxyacetate ([TMGH][MAA]), was found to exhibit attractive capacity to dissolve natural cellulose with an appropriate TMG/MAA molar ratio of 7 : 3 at 80 degrees C. The solubility of cotton linter and ultra-high molecular weight cotton fibers reached 13% (w/w) and 3% (w/w), respectively, surpassing that of most solvent systems currently used for the dissolution of cellulose. The experimental and simulation results verified that the excellent dissolution ability of [TMGH][MAA] for cellulose is mainly attributed to the destruction of the intrinsic hydrogen-bond networks in cellulose by the synergistic interactions of the [TMGH] cations and [MAA] anions with the hydroxyl groups in the cellulose chains, acting as highly efficient "intermolecular scissors". The superiority of this novel dissolution system was further demonstrated by the remarkable comprehensive properties of the regenerated cellulose film including satisfactory thermostability, high transparency, and excellent mechanical properties. Furthermore, the satisfactory recovery performance of this solvent highlights its significant feasibility for large-scale industrial manufacturing. The proposed [TMGH][MAA] in this study exhibits great potential as a next-generation processing solvent for dissolving, and thus processing cellulose, promoting the sustainable development of high-value-added cellulose materials.
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