| 41. |
- Börjesson, Karl, 1982, et al.
(författare)
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Functionalized Nanostructures: Redox-Active Porphyrin Anchors for Supramolecular DNA Assemblies
- 2010
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Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-086X .- 1936-0851. ; 4:9, s. 5037-5046
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Tidskriftsartikel (refereegranskat)abstract
- We have synthesized and studied a supramolecular system comprising a 39-mer DNA with porphyrin-modified thymidine nucleosides anchored to the surface of large unilamellar vesicles (liposomes). Liposome porphyrin binding characteristics, such as orientation, strength, homogeneity, and binding site size, was determined, suggesting that the porphyrin is well suited as a photophysical and redox-active lipid anchor, in comparison to the inert cholesterol anchor commonly used today. Furthermore, the binding characteristics and hybridization capabilities were studied as a function of anchor size and number of anchoring points, properties that are of importance for our future plans to use the addressability of these redox-active nodes in larger DNA-based nanoconstructs. Electron transfer from photoexcited porphyrin to a lipophilic benzoquinone residing in the lipid membrane was characterized by steady-state and time-resolved fluorescence and verified by femtosecond transient absorption.
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| 42. |
- Börjesson, Karl, 1982, et al.
(författare)
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Membrane-Anchored DNA Assembly for Energy and Electron Transfer
- 2009
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Ingår i: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 1520-5126 .- 0002-7863. ; 131:8, s. 2831-2839
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Tidskriftsartikel (refereegranskat)abstract
- In this work we examine the trapping and conversion of visible light energy into chemical energy using a supramolecular assembly. The assembly consists of a light-absorbing antenna and a porphyrin redox center, which are covalently attached to two complementary 14-mer DNA strands, hybridized to form a double helix and anchored to a lipid membrane. The excitation energy Is finally trapped In the lipid phase of the membrane as a benzoquinone radical anion that could potentially be used In subsequent chemical reactions. In addition, In this model complex, the hydrophobic porphyrin moiety acts as an anchor into the liposome positioning the DNA construct on the lipid membrane surface. The results show the suitability of our system as a prototype for DNA-based light-harvesting devices, In which energy transfer from the aqueous phase to the interior of the lipid membrane Is followed by charge separation. © 2009 American Chemical Society.
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| 43. |
- Carlberg, Patrick, et al.
(författare)
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Nanoimprint - a tool for realizing nano-bio research
- 2004
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Ingår i: 2004 4th IEEE Conference on Nanotechnology. - 0780385365 ; , s. 199-200
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Konferensbidrag (refereegranskat)abstract
- In this paper, we present a status report on how implementation of nanoimprint lithography has advanced our research. Contact guidance nerve growth experiments have so far primarily been done on micrometer-structured surfaces. We have made a stamp with 17 areas of different, submicron, line width and spacing covering a total 2.6 mm
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| 44. |
- Carlsson, Georg, et al.
(författare)
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Perennial species mixtures for multifunctional production of biomass on marginal land
- 2017
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Ingår i: GCB Bioenergy. - : Wiley. - 1757-1693 .- 1757-1707. ; 9:1, s. 191-201
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Tidskriftsartikel (refereegranskat)abstract
- Multifunctional agriculture provides noncommodity functions and services along with food, feed and bioenergy feedstocks, for example by preserving or promoting biodiversity, improving soil fertility, mitigating climate change and environmental degradation, and contributing to the socio-economic viability of rural areas. Producing biomass for bioenergy from low-input perennial species mixtures on marginal land has the potential to support biodiversity and soil carbon sequestration in synergy with greenhouse gas mitigation. We compared biomass production in species-rich mixtures of perennial grasses, legumes and forbs with pure-stand grasses and relatively species-poor mixtures under different nitrogen fertilization regimes. Field experiments were performed on different types of marginal land, that is agricultural field margins and land with poor soil fertility, at four sites in southernmost and western Sweden. Biomass production was measured for three years in perennial grasses grown as pure stands, in legume-grass mixtures, and legume-grass-forb mixtures across a species richness gradient. In unfertilized species-rich mixtures, average biomass yields per experimental site and year were in the range from 3 to 9 metric ton DM ha−1 yr−1. While the most productive pure-stand grasses fertilized with 60–120 kg N ha−1 yr−1 often produced higher biomass yields than unfertilized mixtures, these differences were generally smaller than the variations between years and sites. Calculations of climate impact using the harvested biomass for conversion to biogas as vehicle fuel showed that the average greenhouse gas emissions per energy unit were about 50% lower in unfertilized systems than in treatments fertilized with 100–120 kg N ha−1 yr−1. Our findings thereby show that unfertilized species-rich perennial plant mixtures on marginal land provide resource-efficient biomass production and contribute to the mitigation of climate change. Perennial species mixtures managed with low inputs thus promote synergies between productivity and biodiversity in the perspective of climate-smart and multifunctional biomass production.
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| 45. |
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| 46. |
- Carnerud, Daniel, 1983-, et al.
(författare)
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On the inclusion of sustainability and digitalisation in quality management : an overview from past to present
- 2020
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Ingår i: Total Quality Management and Business Excellence. - : Taylor & Francis. - 1478-3363 .- 1478-3371.
-
Tidskriftsartikel (refereegranskat)abstract
- The aim of this study is to explore whether trends in sustainability and digitalisation from the 1980s until today have left any significant practical or epistemological footprints on the quality management paradigm. The study design consists of a mixed-methods approach that applies a data-mining methodology and content analysis to the digital archives of eight scientific journals: six within the quality management (QM) domain and two with a focus on operations management (OM). The data set contains an unbroken time series of over 12,000 research paper abstracts, the first of them published in 1980, giving the study a coverage of almost 40 years. The findings show that sustainability came onto the scholarly scene in 1996 and has since become an increasingly popular research area. In regard to digitalisation, the story is quite different, as the concept is currently absent from the scholarly QM and OM literatures. However, a search for information technology (IT) and information systems (IS) revealed that these topics have been gaining attention since the 1980s. However, it was found that QM research only addresses one part of digitalisation, omitting several interesting dimensions. One example is that the QM and OM literatures address IS mainly in relation to standardised guidelines and business processes within organisations. At the same time, we found a handful of studies combining QM and topics related to modern digitisation, like social media.
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| 47. |
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| 48. |
- Chen, Jianing, et al.
(författare)
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Surface-enhanced Raman scattering of rhodamine 6G on nanowire arrays decorated with gold nanoparticles
- 2008
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Ingår i: Nanotechnology. - : IOP Publishing. - 0957-4484 .- 1361-6528. ; 19:27, s. 5-275712
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Tidskriftsartikel (refereegranskat)abstract
- We investigate the surface-enhanced Raman scattering (SERS) of rhodamine 6G (R6G) adsorbed on Au nanoparticles attached to InP nanowires. We find that nanowire arrays act as frameworks for effective SERS substrates with a significantly higher Raman signal sensitivity than a planar framework of Au nanoparticles adsorbed two-dimensionally on a flat surface. The SERS signal displays a clear polarization-dependent effect when the nanowires are arranged in a row. We also find that the SERS signal increases with time during continuous laser illumination. The plasmon-enhanced optical forces between Au nanoparticles may either move pairs of nanoparticles closer together or attract adsorbed molecules by moving them to the junctions of Au nanoparticle aggregates. Such effects by plasmon optical forces may cause the observed increase of the SERS signal with continuous laser illumination.
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| 49. |
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| 50. |
- del Rio, J. S., et al.
(författare)
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CEPA: A LaBr 3 (Ce)/LaCl 3 (Ce) phoswich array for simultaneous detection of protons and gamma radiation emitted in reactions at relativistic energies
- 2014
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Ingår i: EPJ Web of Conferences. - : EDP Sciences. - 2101-6275 .- 2100-014X. ; 66
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Konferensbidrag (refereegranskat)abstract
- A prototype CEPA4, made of four optically isolated phoswich-crystals of LaBr3(Ce)+LaCl3(Ce) packed together in one can of Al, was tested with high energy protons (70-230 MeV) at the cyclotron of Krakow. Further, the response to different gamma radiation standard sources and cosmic muons was determined. Shape analysis of the pulses derived from the four individually coupled PM-tubes was performed and were used as input functions for Monte Carlo simulations in order to simulate the efficiencies and resolutions of a final detector design consisting of 750 such phoswich crystals arranged in a cylindrical disc. © Owned by the authors, published by EDP Sciences, 2014.
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