Sök i SwePub databas

  Utökad sökning

Träfflista för sökning "Hålenius mat:art lärosäte:nrm språk:eng "

Utökad sökning > Hålenius mat:art lärosäte:nrm språk:eng

  • Resultat 51-75 av 114
  • Föregående 12[3]45Nästa
Sortera/gruppera träfflistan
  • Lenaz, Davide, et al. (författare)
  • Structural parameters of Cr-bearing spinels and pleonaste from the Cuillin Igneous Complex (Isle of Skye, Scotland): Implications for metamorphic and cooling history
  • 2016
  • Ingår i: Mineralogical magazine. - 0026-461X. ; 80:5, s. 749-764
  • Tidskriftsartikel (refereegranskat)abstract
    • The Outer Layered Suite of the Cuillin Igneous Complex (Isle of Skye, NW Scotland) comprises a Peridotite Series and a younger Allivalite Series (the latter comprising troctolites, eucrites and gabbros). Close to the junction between the Peridotite and the Allivalite Series (but wholly contained within the latter), an ultramafic breccia unit containing abundant peridotite xenoliths crops out. In the Peridotite Series, reddish-brown Cr-bearing spinels are present as disseminated crystals in the peridotite and also as chromitite seams, while in the peridotite xenoliths of the breccia unit, green pleonaste occurs in both of these modes of textural occurrence. Optical absorption spectroscopy reveals that the colour difference between the two spinel phases is related mainly to variable Al, Cr and Fe contents, while crystal structural analysis shows that the cooling rate calculated utilizing the oxygen positional parameter is comparable for all samples. The intracrystalline closure temperature for the Cr-spinel in the Peridotite Series is different for the disseminated and seam textural occurrences of the spinels, while the temperatures yielded by pleonaste in the peridotite xenoliths are the same for both textural occurrences. Our dataset suggests that the pleonaste in the peridotite xenoliths has been heated and equilibrated under subsolidus conditions, probably during breccia formation. During this heating, homogenization of the closure temperatures of pleonaste spinels occurred.
  • D'Ippolito, Veronica, et al. (författare)
  • Color mechanisms in spinel: cobalt and iron interplay for the blue color
  • 2015
  • Ingår i: Physics and chemistry of minerals. - 0342-1791. ; 42:6, s. 431-439
  • Tidskriftsartikel (refereegranskat)abstract
    • Six natural, blue colored spinel crystals were studied chemically by electron microprobe and laser ablation inductively coupled plasma mass spectrometry (LAICP-MS) techniques and optically by UV–VIS–NIR–MIR spectroscopy in the range 30,000–2,000 cm−1  to investigate the causes of their blue color hues. The positions of the absorption bands vary only marginally with the principal composition of the samples (gahnite vs. spinel s.s .). Although blue colors in spinels are frequently the result of various electronic processes in Fe cations, we demonstrate by comparison with synthetic Co-bearing samplesthat Co acts as an important chromophore also in natural spinels. Already at concentration levels of a few ppm (e.g.,>10 ppm), cobalt gives rise to absorption bands at ~18,000, 17,000 and 16,000 cm−1  that result in distinct blue coloration. In spinels with insignificant Co contents, different shades of paler blue (from purplish to greenish blue) colors are caused by electronic transitions in TFe2+, MFe2+, MFe3+ and Fe2+–Fe3+  cation pairs.
  • Hålenius, Ulf, et al. (författare)
  • Gatedalite, Zr(Mn2+2Mn3+4)SiO12, a new mineral species of the braunite group from Långban, Sweden
  • 2015
  • Ingår i: Mineralogical magazine. - 0026-461X. ; 79:3, s. 625-634
  • Tidskriftsartikel (refereegranskat)abstract
    • Gatedalite, Zr(Mn2+2Mn3+4)SiO12, is a new mineral of the braunite group. It is found in hausmannite impregnated skarn together with jacobsite, Mn-bearing calcite, tephroite, Mn-bearing phlogopite,långbanite, pinakiolite and oxyplumboroméite at the Långban Mn-Fe oxide deposit, Värmland, central Sweden. The mineral occurs as very rare, small ≤60 µm), grey, submetallic, irregularly rounded anhedral grains. Gatedalite has a calculated density of 4.783 g/cm3. It is opaque and weakly anisotropic with reflectivity in air varying between 17.1 and 20.8% in the visible spectral range. Gatedalite is tetragonal, space group I41/acd, with the unit-cell parameters a = 9.4668(6) Å , c = 18.8701(14) Å , V = 1691.1(2) Å3 and Z = 8. The crystal structure was refined to an R1 index of 5.09% using 1339 unique reflections collected with MoKa X-ray radiation. The five strongest powder X-ray diffraction lines [d in Å, (I), (hkl)] are: 2.730(100)(224), 2.367(12)(040), 1.6735(12)(440), 1.6707(29)(048) and 1.4267(16)(264). Gatedalite is a member of the braunite group (general formula AB6SiO12). It is related to braunite (Mn2+Mn3+6SiO12) through the net cation exchange (Zr4++Mn2+)➝2Mn3+, which results from the substitutions Zr4+ ➝ Mn2+ at the 8-fold coordinated site (A in the general formula) coupled with a 2Mn2+ ➝ 2Mn3+ substitution at the 6-fold coordinated sites (B in the general formula).
  • Nyquist, Susanne, et al. (författare)
  • An EELS study of near edge structures of the oxygen K-edge in spinels
  • 2014
  • Ingår i: Physics and chemistry of minerals. - 0342-1791. ; 41:4, s. 255-265
  • Tidskriftsartikel (refereegranskat)abstract
    • Spectra of seven aluminate, ferrite and chromate spinels were collected at the oxygen K-edge in order to examine the effect of octahedral ion composition on the near edge structures and explore whether these may shed some light on previously reported major variations in the optical absorption coefficient (epsilon) for the spin-allowed d-d band transitions due to tetrahedrally coordinated Fe2+ in optical spectra of oxide spinels. Interpretation of the energy loss near edge structure (ELNES) spectra was aided using the multiple scattering code FEFF8.40. For the chromate samples spin polarised calculations were included. Gold's iterative deconvolution method was utilized to improve on energy resolution, resulting in spectra equal in merit to those recorded by technically superior instruments. Results include absolute energy positions and interpretation of ELNES features in terms of transitions to available states. We conclude that the major causes of differences in the optical absorption coefficient mentioned above are hybridization between oxygen p- and octahedral metal orbitals. Our study does not support the idea presented by other authors that there exists a local antiferromagnetic ordering in MgCr2O4 at room temperature.
Skapa referenser, mejla, bekava och länka
  • Resultat 51-75 av 114
  • Föregående 12[3]45Nästa
fritt online (16)
Typ av publikation
tidskriftsartikel (114)
Typ av innehåll
refereegranskat (88)
övrigt vetenskapligt (26)
Hålenius, Ulf, (113)
Bosi, Ferdinando, (43)
Pasero, Marco, (33)
Skogby, Henrik (32)
Hatert, Frédéric, (27)
Mills, Stuart J., (22)
visa fler...
Andreozzi, Giovanni ... (8)
Kristiansson, Per, (6)
D'Ippolito, Veronica ... (6)
Reznitskii, Leonid (6)
Grew, Edward S., (6)
Andreozzi, Giovanni, (5)
Ros, Linus, (4)
Biagioni, Cristian, (4)
Fregola, Rosa Anna, (4)
Edén, Mattias, (3)
Bindi, Luca, (3)
Billström, Kjell, (3)
Holtstam, Dan (3)
Demitri, Nicola, (3)
Halenius, Ulf (3)
Barbier, Jacques, (3)
Eriksson, Lars, (2)
Pallon, Jan, (2)
Elfman, Mikael, (2)
Nilsson, Charlotta, (2)
Mörth, Carl-Magnus, (2)
Jansson, Kjell, (2)
Häussermann, Ulrich, (2)
Johansson, Åke (2)
Andersson, Per S., (2)
Mansfeld, Joakim, (2)
Mauro, Daniela, (2)
Miyawaki, Ritsuro, (2)
Noreus, Dag, (2)
Ciriotti, Marco, (2)
Naitza, Stefano, (2)
Secchi, Francesco, (2)
Conte, Aida M., (2)
De La Rosa, Nathaly, (2)
Nilsson, E.J. Charlo ... (2)
Dekov, Vesselin, (2)
Boycheva, Tanya, (2)
Stummeyer, Jens, (2)
Dekov, Vesselin M., (2)
Munnik, Frans, (2)
Kamenov, George D., (2)
Fernandez Diaz, Mari ... (2)
Gatta, G. Diego, (2)
Yates, Martin G., (2)
visa färre...
Naturhistoriska riksmuseet (114)
Stockholms universitet (6)
Lunds universitet (4)
Uppsala universitet (2)
Luleå tekniska universitet (1)
Kungliga Tekniska Högskolan (1)
Engelska (114)
Forskningsämne (UKÄ/SCB)
Naturvetenskap (114)


pil uppåt Stäng

Kopiera och spara länken för att återkomma till aktuell vy