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Sökning: AMNE:(NATURAL SCIENCES Chemistry Environmental chemistry) > Barker Abigail

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1.
  • Barker, Abigail, et al. (författare)
  • The magma plumbing system for the 1971 Teneguía eruption on La Palma, Canary Islands
  • 2015
  • Ingår i: Contributions to Mineralogy and Petrology. - : Springer Science and Business Media LLC. - 0010-7999 .- 1432-0967. ; 170:5-6
  • Tidskriftsartikel (refereegranskat)abstract
    • The 1971 Teneguía eruption is the most recent volcanic event of the Cumbre Vieja rift zone on La Palma. The eruption produced basanite lavas that host xenoliths, which we investigate to provide insight into the processes of differentiation, assimilation and magma storage beneath La Palma. We compare our results to the older volcanomagmatic systems of the island with the aim to reconstruct the temporal development of the magma plumbing system beneath La Palma.The 1971 lavas are clinopyroxene-olivine-phyric basanites that contain augite, sodic-augite and Aluminium augite. Kaersutite cumulate xenoliths host olivine, clinopyroxene including sodic-diopside, and calcic-amphibole, whereas an analysed leucogabbro xenolith hosts plagioclase, sodic-augite-diopside, calcic-amphibole and hauyne. Mineral and mineral-melt thermobarometry indicate that clinopyroxene and plagioclase in the 1971 Teneguía lavas crystallised at 20 to 45 km depth, coinciding with clinopyroxene and calcic-amphibole crystallisation in the kaersutite cumulate xenoliths at 25 to 45 km and clinopyroxene, calcic-amphibole and plagioclase crystallisation in the leucogabbro xenolith at 30 to 50 km.Combined mineral chemistry and thermobarometry suggest that the magmas had already crystallised, differentiated and formed multiple crystal populations in the oceanic lithospheric mantle. Notably, the magmas that supplied the 1949 and 1971 events appear to have crystallised deeper than the earlier Cumbre Vieja magmas, which suggests progressive underplating beneath the Cumbre Vieja rift zone. In addition, the lavas and xenoliths of the 1971 event crystallised at a common depth, indicating a reused plumbing system and progressive recycling of Ocean Island plutonic complexes during subsequent magmatic activity. 
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2.
  • Barker, Abigail K., et al. (författare)
  • Magmatic evolution of the Cadamosto Seamount, Cape Verde : Beyond the spatial extent of EM1
  • 2012
  • Ingår i: Contributions to Mineralogy and Petrology. - : Springer Science and Business Media LLC. - 0010-7999 .- 1432-0967. ; 163:6, s. 949-965
  • Tidskriftsartikel (refereegranskat)abstract
    • The Cadamosto Seamount is an unusual volcanic centre from Cape Verde, characterised by dominantly evolved volcanics, in contrast to the typically mafic volcanic centres at Cape Verde that exhibit only minor volumes of evolved volcanics. The magmatic evolution of Cadamosto Seamount is investigated to quantify the role of magma-crust interaction and thus provide a perspective on evolved end-member volcanism of Cape Verde. The preservation of mantle source signatures by Nd-Pb isotopes despite extensive magmatic differentiation provides new insights into the spatial distribution of mantle heterogeneity in the Cape Verde archipelago. Magmatic differentiation from nephelinite to phonolite involves fractional crystallisation of clinopyroxene, titanite, apatite, biotite and feldspathoids, with extensive feldspathoid accumulation being recorded in some evolved samples. Clinopyroxene crystallisation pressures of 0.38-0.17 GPa for the nephelinites constrain this extensive fractional crystallisation to the oceanic lithosphere, where no crustal assimilants or rafts of subcontinental lithospheric mantle are available. In turn, magma-crust interaction has influenced the Sr, O and S isotopes of the groundmass and late crystallising feldspathoids, which formed at shallow crustal depths reflecting the availability of oceanic sediments and anhydrite precipitated in the ocean crust. The Nd-Pb isotopes have not been affected by these processes of magma-crust interaction and hence preserve the mantle source signature. The Cadamosto Seamount samples have high Pb-206/Pb-204 (> 19.5), high epsilon Nd (+6 to +7) and negative Delta 8/4Pb, showing affinity with the northern Cape Verde islands as opposed to the adjacent southern islands. Hence, the Cadamosto Seamount in the west is located spatially beyond the EM1-like component found further east. This heterogeneity is not encountered in the oceanic lithosphere beneath the Cadamosto Seamount despite greater extents of fractional crystallisation at oceanic lithospheric depths than the islands of Fogo and Santiago. Our data provide new evidence for the complex geometry of the chemically zoned Cape Verde mantle source.
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3.
  • Barker, Abigail, et al. (författare)
  • Direct observation of a fossil high-temperature, fault-hosted, hydrothermal upflow zone in crust formed at the East Pacific Rise
  • 2010
  • Ingår i: Geology. - 0091-7613 .- 1943-2682. ; 38:4, s. 379-382
  • Tidskriftsartikel (refereegranskat)abstract
    • Fault zones in the ocean crust are commonly hypothesized to act as high-permeability conduits that focus fluid flow in oceanic hydrothermal systems. However, there has been little direct study of faults in crust formed at fast-spreading ridges. Here we describe the geology and geochemistry of an ∼40-m-wide fault zone within the uppermost sheeted dike complex exposed at Pito Deep (northeastern Easter microplate). Titanium in quartz thermometry gives temperatures of 392 ± 33 °C for quartz precipitation, indicating that this fault zone focused upwelling fluids at temperatures similar to those of black-smoker vent fluids. Correlated enrichment in 87Sr/86Sr and MgO in fault breccias, along with 87Sr/86Sr ratios higher than in average vent fluids, provide evidence for mixing between high-temperature upwelling fluids and a seawater-like fluid within the fault zone. Large high-temperature fluid fluxes are required to maintain high temperatures during mixing. If this fault zone is representative of upflow zones beneath hydrothermal vents on the East Pacific Rise, then it is possible that vent fluids evolve thermally and chemically during their ascent and may not record the precise conditions at the base of the hydrothermal system.
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4.
  • Barker, Abigail, et al. (författare)
  • Insights into the behaviour of sulphur in mid-ocean ridge axial hydrothermal systems from the composition of the sheeted dyke complex at Pito Deep
  • 2010
  • Ingår i: Chemical Geology. - : Elsevier BV. - 0009-2541 .- 1872-6836. ; 275:1-2, s. 105-115
  • Tidskriftsartikel (refereegranskat)abstract
    • The behaviour of seawater sulphate in hydrothermal systems at intermediate- to fast-spreading ridges is investigated using new analyses of the δ34S, sulphur concentration and Fe2O3/Fe2O3total, combined with existing 87Sr/86Sr, of sheeted dykes from the Pito Deep tectonic window. The Pito Deep sheeted dyke complex has a similar composition to the sheeted dykes drilled at ODP Hole 504B suggesting that the measured compositions are representative of sheeted dyke complexes at intermediate- to fast-spreading ridges. The dykes show only small increases in δ34S which, combined with the rock dominated δ34S of vent fluids, requires the majority of seawater sulphate to be precipitated as anhydrite before the fluid reacts with the sheeted dyke complex. This loss of sulphate from the fluid means that a much higher Fe2O3 in the sheeted dyke complex than in fresh MORB glasses cannot be explained by oxidation due to seawater sulphate reduction during fluid-rock reaction. Instead, oxidation probably occurs due to degassing of reduced species, largely H2, during dyke emplacement and solidification. A mass balance model that accounts for anhydrite precipitation and Sr partitioning into the anhydrite, as well as fitting the concentration and isotopic ratios of S and Sr in the sheeted dykes and vent fluids, suggests water/rock ratios of -1. For a 1km thick sheeted dyke complex this is equivalent to a fluid flux of ~3×106kgm-2, sufficient to remove ~60% of the latent heat of crystallization from the lower crust.
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6.
  • Peate, David, et al. (författare)
  • Compositional characteristics and spatial distribution of enriched Icelandic mantle components.
  • 2010
  • Ingår i: Journal of Petrology. - : Oxford University Press (OUP). - 0022-3530 .- 1460-2415. ; 51:7, s. 1447-1475
  • Tidskriftsartikel (refereegranskat)abstract
    • We present compositional data on a suite of 18 primitive neovolcanic alkali basalts from three flank-zone regions in Iceland (Vestmannaeyjar in the south, Snæfell in the east, and Snæfellsnes in the west) that are peripheral to the main rift zones that are dominated by tholeiitic basalts. This study integrates He isotope data with radiogenic isotope data (Sr–Nd–Pb–Hf), stable isotope data (δ18O), and trace element data to characterize the compositional features of the trace element enriched components of the Icelandic mantle. We also present high-precision Pb isotope data on an additional 57 lava samples from the flank zones (including Öræfajökull in the SE) and the Northern and Eastern rift zones. Most Icelandic lavas have negative Δ207Pb (–4 to –1), with higher values (–1 to +4) found only in samples from Öræfajökull, Snæfell, and parts of the Reykjanes Peninsula. At Snæfell, this EM1-type component is characterized by a low δ18Oolivine signature (+4·1‰ to +4·6‰), moderate 206Pb/204Pb values (18·4–18·6) and mid-ocean ridge basalt (MORB)-like 3He/4He (6·9–7·5 R/RA). Samples from Vestmannaeyjar and Snæfellsnes have mantle-like δ18Oolivine (+4·9‰ to +5·0‰), and radiogenic 206Pb/204Pb values (18·9–19·3) that fall on the Northern Hemisphere Reference Line for 208Pb/204Pb (Δ208Pb –5 to +5). Compared with the Vestmannaeyjar lavas, Snæfellsnes lavas have higher La/YbN (5–11 vs 3–5), lower εNd (5·5–6·5 vs 6·8–7·6) and lower 3He/4He (6·3–8·6 R/RA vs 11·4–13·5 R/RA). Therefore, the most trace element enriched components in the Icelandic mantle are not the carriers of the high 3He/4He values (>15 R/RA) found in some lavas on Iceland and the adjacent ridges, and instead are consistent with degassed, recycled components. Even after excluding the EM1-type high Δ207Pb samples, high-precision Pb isotope data produce a kinked array on a 206Pb/204Pb vs 208Pb/204Pb plot, which is not consistent with simple binary mixing between two end-members. This requires significant lateral heterogeneity within the Icelandic mantle and the presence of more than just two compositionally distinct local mixing end-member components. Samples from each of the main axial rift zones define different trends. Despite the tectonic continuity between the Northern Volcanic Zone and the Eastern Volcanic Zone, lavas from these two rift zones define separate sub-parallel linear arrays. Lavas from the adjacent Western Volcanic Zone and the Eastern Volcanic Zone define oblique linear arrays that converge on a common local end-member that is not involved in the magmatism of the Northern Volcanic Zone. Therefore, there is a distinct NE–SW compositional heterogeneity within the Icelandic mantle.
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