| 1. |
- Sefer, Birhan, 1983-, et al.
(författare)
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Chemical Milling of Cast Ti-6Al-4V and Ti-6Al-2Sn-4Zr-2Mo Alloys in Hydrofluoric-Nitric Acid Solutions
- 2017
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Ingår i: Corrosion. - : Association for Materials Protection and Performance (AMPP). - 0010-9312 .- 1938-159X. ; 73:4, s. 394-407
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Tidskriftsartikel (refereegranskat)abstract
- The behavior of cast Ti-6Al-4V and Ti-6Al-2Sn-4Zr-2Mo during chemical milling in hydrofluoric-nitric (HF-HNO3) acid solutions with 1:3 and 1:11 molar ratios was investigated using electrochemical and atomic force microscopy (AFM) techniques. Faster corrosion rate in 1:3 solutions was measured for Ti-6Al-4V than for Ti-6Al-2Sn-4Zr-2Mo, whereas in 1:11 solution Ti-6Al-2Sn-4Zr-2Mo exhibited higher corrosion rate. Scanning Kelvin probe force microscopy measurements revealed difference in the Volta potential between the α-laths and the β-layers in the Widmansttäten microstructure indicating operation of microgalvanic cells between the microconstituents when in contact with HF-HNO3 solution. The AFM topography measurements demonstrated faster corrosion of the α-laths compared to the β-layers, in both alloys. In 1:3 solutions, higher α/β height difference was measured in Ti-6Al-4V, whereas in 1:11 solution, the difference was higher in Ti-6Al-2Sn-4Zr-2Mo. The results revealed that the chemical milling behavior of the two investigated alloys is controlled by the microscopic corrosion behavior of the individual microconstituents.
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| 2. |
- Chen, Zhe, et al.
(författare)
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Nano-scale characterization of white layer in broached Inconel 718
- 2017
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Ingår i: Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing. - Amsterdam : Elsevier BV. - 0921-5093 .- 1873-4936. ; 684, s. 373-384
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Tidskriftsartikel (refereegranskat)abstract
- The formation mechanism of white layers during broaching and their mechanical properties are not well investigated and understood to date. In the present study, multiple advanced characterization techniques with nano-scale resolution, including transmission electron microscopy (TEM), transmission Kikuchi diffraction (TKD), atom probe tomography (APT) as well as nano-indentation, have been used to systematically examine the microstructural evolution and corresponding mechanical properties of a surface white layer formed when broaching the nickel-based superalloy Inconel 718.TEM observations showed that the broached white layer consists of nano-sized grains, mostly in the range of 20–50 nm. The crystallographic texture detected by TKD further revealed that the refined microstructure is primarily caused by strong shear deformation. Co-located Al-rich and Nb-rich fine clusters have been identified by APT, which are most likely to be γ′ and γ′′ clusters in a form of co-precipitates, where the clusters showed elongated and aligned appearance associated with the severe shearing history. The microstructural characteristics and crystallography of the broached white layer suggest that it was essentially formed by adiabatic shear localization in which the dominant metallurgical process is rotational dynamic recrystallization based on mechanically-driven subgrain rotations. The grain refinement within the white layer led to an increase of the surface nano-hardness by 14% and a reduction in elastic modulus by nearly 10% compared to that of the bulk material. This is primarily due to the greatly increased volume fraction of grain boundaries, when the grain size was reduced down to the nanoscale.
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| 3. |
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| 4. |
- Hosseini Bab Anari, Elham, 1982, et al.
(författare)
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Fluorine-free salts for aqueous lithium-ion and sodium-ion battery electrolytes
- 2016
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Ingår i: RSC Advances. - : Royal Society of Chemistry (RSC). - 2046-2069. ; 6:88, s. 6, 85194-85201
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Tidskriftsartikel (refereegranskat)abstract
- A first generation of fluorine-free lithium and sodium salts based on the concept of pseudo-delocalized anions has been synthesized with both high purity and yield using water as the solvent in the reaction medium. The salts have been fully characterized by Raman and FT-IR spectroscopies, thermogravimetry, and X-ray crystallography to reveal both basic properties in terms of thermal stability and solubility as well as the local, mainly ion–ion interaction dictated, coordination details and by ionic conductivity and electrochemical stability window measurements as aqueous electrolytes. Together a picture is created of the salts' promise as components in electrolytes – primarily aiming at application in low voltage fluorinefree aqueous lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs).
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| 5. |
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| 6. |
- Åkerfeldt, Pia, et al.
(författare)
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Electron backscatter diffraction characterization of fatigue crack growth in laser metal wire deposited Ti-6Al-4V
- 2018
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Ingår i: Materials Characterization. - : Elsevier BV. - 1044-5803 .- 1873-4189. ; 135, s. 245-256
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Tidskriftsartikel (refereegranskat)abstract
- By additive manufacturing (AM) there is a feasibility of producing near net shape components in basically one step from 3D CAD model to final product. The interest for AM is high and during the past decade a lot of research has been carried out in order to understand the influence from process parameters on the microstructure and furthermore on the mechanical properties. In the present study laser metal wire deposition of Ti-6Al-4V has been studied in detail with regard to its fatigue crack propagation characteristics. Two specimen orientations, parallel and perpendicular to the deposition direction, have been evaluated at room temperature and at 250 °C. No difference in the fatigue crack growth rate could be confirmed for the two specimen orientations. However, in the fractographic study it was observed that the tortuosity varied between certain regions on the fracture surface. The local crack path characteristic could be related to the alpha colony size and/or the crystallographic orientation. Moreover, large areas exhibiting similar crystallographic orientation were observed along the prior beta grain boundaries, which were attributed to the wide alpha colonies frequently observed along the prior beta grain boundaries. © 2017 Elsevier Inc.
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| 7. |
- Åkerfeldt, Maria, 1982, et al.
(författare)
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Textile piezoelectric sensors – melt spun bi-component poly(vinylidene fluoride) fibres with conductive cores and poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate) coating as the outer electrode
- 2014
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Ingår i: Fashion and Textiles. - : Springer Science and Business Media LLC. - 2198-0802. ; 1:1
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Tidskriftsartikel (refereegranskat)abstract
- The work presented here addresses the outer electroding of a fully textile piezoelectric strain sensor, consisting of bi-component fibre yarns of β-crystalline poly(vinylidene fluoride) (PVDF) sheath and conductive high density polyethylene (HDPE)/carbon black (CB) core as insertions in a woven textile, with conductive poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate) (PEDOT:PSS) coatings developed for textile applications. Two coatings, one with a polyurethane binder and one without, were compared for the application and evaluated as electrode material in piezoelectric testing, as well as tested for surface resistivity, tear strength, abrasion resistance and shear flexing. Both coatings served their function as the outer electrodes in the system and no difference in this regard was detected between them. Omission of the binder resulted in a surface resistivity one order of magnitude less, of 12.3 Ω/square, but the surface resistivity of these samples increased more upon abrasion than the samples coated with binder. The tear strength of the textile coated with binder decreased with one third compared to the uncoated substrate, whereas the tear strength of the coated textile without binder increased with the same amount. Surface resistivity measurements and scanning electron microscopy (SEM) images of the samples subjected to shear flexing showed that the coatings without the binder did not withstand this treatment, and that the samples with the binder managed this to a greater extent. In summary, both of the PEDOT:PSS coatings could be used as outer electrodes of the piezoelectric fibres, but inclusion of binder was found necessary for the durability of the coating.
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| 8. |
- Guldris Leon, Lorena, 1983, et al.
(författare)
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Understanding Mineral Liberation during Crushing Using Grade-by-Size Analysis - A Case Study of the Penuota Sn-Ta Mineralization, Spain
- 2020
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Ingår i: Minerals. - : MDPI AG. - 2075-163X. ; 10:2
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Tidskriftsartikel (refereegranskat)abstract
- Coarse comminution test-work and modeling are powerful tools in the design and optimization of mineral processing plants and provide information on energy consumption. Additional information on mineral liberation characteristics can be used for assessing the potential of pre-concentration stages or screens in the plant design. In ores of high-value metals (e.g., Ta, W), standard techniques-such as the mineralogical quantification of grain mounts by quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN) or chemical analysis by X-ray fluorescence (XRF) can be challenging, due to the low relative abundance of such valuable minerals. The cost of QEMSCAN is also a limiting factor, especially considering the large number of samples required for the optimization of coarse comminution. In this study, we present an extended analytical protocol to a well-established mechanical test of interparticle breakage to improve the assessment of coarse mineral liberation characteristics. The liberation of ore minerals is a function of the rock texture and the difference in size and mechanical properties of the valuable minerals relative to gangue minerals and they may fraction in certain grain sizes if they behave differently during comminution. By analyzing the bulk-chemistry of the different grain size fractions produced after compressional testing, and by generating element by size diagrams, it is possible to understand the liberation characteristics of an ore. We show, based on a case study performed on a tantalum ore deposit, that element distribution can be used to study the influence of mechanical parameters on mineral liberation. This information can direct further mineralogical investigation and test work.
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| 9. |
- Stolen, Reidar, et al.
(författare)
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Solcelleteknologi og brannsikkerhet
- 2018
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- Bruken av solcelleteknologi er i stor vekst i Norge. I denne studien er branntekniske utfordringer ved bruk av solcelleteknologi undersøkt, med hensyn på brannstart, brannspredning og brannslokking. Studien danner et kunnskapsgrunnlag for å ivareta brannsikkerheten under montering, drift og under slokkeinnsats, samt for å utforme et enhetlig og tydelig regelverk. Resultatene fra studien viser:Brannstart: Solcelleinstallasjoner inneholder mange koblingspunkt, som kan være potensielle tennkilder, og en liten mengde brennbare materialer. Dermed er det som trengs til stede for å starte en brann. Det er viktig at alle kontaktpunkter i solcelleinstallasjonen er robuste og tåler den påkjenningen de blir utsatt for gjennom sin levetid uten at det oppstår dårlig kontakt som kan føre til brann.Brannspredning: For utenpåmonterte solcellemoduler er det ofte en åpen luftspalte mellom modul og bygning. Dersom det er en brann i denne luftspalten, vil varmen kunne bli akkumulert, noe som kan føre til raskere og større brannspredning enn om bygningsoverflaten ikke hadde vært tildekket. I fullskalaforsøk med solcellemoduler montert på tak spredte brannen seg under hele arealet som var dekket av moduler, men stoppet da den nærmet seg kanten av dette arealet. Dette illustrerer viktigheten av at områder med solceller utenpå en bygning blir seksjonert for å unngå brannspredning. Eventuelt kan det benyttes mindre brennbare materialer på taket under solcellemodulene for å motvirke den økte varmepåkjenningen som solcellemodulene gir. Luftspalten mellom modul og bygning kan potensielt også gi endringer i luftstrømningen langs bygget, som igjen kan påvirke brannspredningen.Brannslokking: Brannvesenet har behov for informasjon om det er solcelleinstallasjon i bygget og hvilke deler av det elektriske anlegget som kan være spenningssatt. Under slokkeinnsats må brannvesenet ta hensyn til berøringsfare, og fare for at det kan oppstå lysbuer og andre feil som kan føre til nye antennelsespunkt. Ferskvann kan brukes som slokkemiddel, dette må spyles fra minimum 1 meters avstand med spredt stråle og minimum 5 meters avstand med samlet stråle. Solcellemoduler kan komplisere brannslokking ved at de danner en fysisk barriere mellom brannvesenet og brannen, samt fordi det må tas hensyn til plassering av spenningssatte komponenter. Når disse punktene er tatt høyde for, bør ikke utenpåmonterte solcelleinstallasjoner være et problem.Videre arbeid: For utenpåmonterte solcelleinstallasjoner, er det lite forskning på vertikal montering (på fasader), og hvordan en eventuell endret branndynamikk kan påvirke brannspredning og slokking. Videre er det i dag økende bruk av bygningsintegrerte solcelleinstallasjoner, noe som gir mange mulige nye utfordringer for brannsikkerheten og for regelverk, ettersom solcellen da er en del av bygningskroppen, samtidig som den er en elektrisk komponent. Tysk statistikk tyder på at brannrisiko for slike installasjoner kan være større enn for utenpåmonterte solcelleinstallasjoner, og dette vil det derfor være viktig å undersøke nærmere.
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| 10. |
- Dimitrios, Nikas, et al.
(författare)
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Effect of annealing on microstructure in railway wheel steel
- 2022
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Ingår i: 42Nd Riso International Symposium On Materials Science. - : Institute of Physics Publishing (IOPP). ; 1249
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Konferensbidrag (refereegranskat)abstract
- Railway wheels are commonly made from medium carbon steels (similar to 0.55 wt.% C), heat treated to a near pearlitic microstructure with 5-10% pro-eutectoid ferrite. During the operation of freight trains, where block brakes are used, high thermal loads occur together with the high contact stresses, which combined can affect the mechanical properties of the material. In this study, the effects of annealing on local microstructure and mechanical properties in pearlitic railway wheel steel were investigated using electron microscopy and micro-hardness. It is found that after annealing at 650 degrees C, the room temperature hardness reduces about 25%, accompanied by significant spheroidization of cementite in the pearlitic colonies, though the size and the orientation gradients of the pearlitic colonies have not changed much. The relationship between the microstructural changes and the mechanical properties are discussed.
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