| 1. |
|
|
| 2. |
|
|
| 3. |
|
|
| 4. |
|
|
| 5. |
|
|
| 6. |
|
|
| 7. |
- Kristiansson, Per, et al.
(author)
-
The implementation of a DSSSD in the upgraded boron analysis at LIBAF for applications in geochemistry
- 2014
-
In: Nuclear Instruments & Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms. - : Elsevier BV. - 0168-583X .- 1872-9584. ; 332, s. 207-211
-
Journal article (peer-reviewed)abstract
- Interest in high spatial resolution boron analyses from a geochemical perspective is related to the recognition of boron as an important tracer of chemical recycling in the Earth, due to the high solubility of boron in aqueous fluids and silicate melts. Although boron is not a nominal component in common silicates they may still contain significant B-concentrations and hence constitute important boron reservoirs in the deeper parts of the Earth. Boron analyses have been performed at the Lund Ion Beam Analytical Facility for almost 20 years. For the analysis the nuclear reaction p+B-11 is used with beam energy just below 700 keV where the reaction has a broad resonance. In this paper we describe an upgrade of the system with a double sided silicon strip detector, which allows for much higher count rates compared to the old annular surface detector based system. A gain close to 20 in the data rate allows for high resolution mapping of boron distributions in crystals. This is illustrated by a number of examples. In addition, the detection limits for boron in geological samples are improved, now around 5 ppmw. In this work we address issues with data quality, especially charge normalization, lifetime correction and subtraction of different background components. (C) 2014 The Authors. Published by Elsevier B.V.
|
|
| 8. |
- Nyquist, Susanne, et al.
(author)
-
An EELS study of near edge structures of the oxygen K-edge in spinels
- 2014
-
In: Physics and chemistry of minerals. - : Springer Science and Business Media LLC. - 0342-1791 .- 1432-2021. ; 41:4, s. 255-265
-
Journal article (peer-reviewed)abstract
- Spectra of seven aluminate, ferrite and chromate spinels were collected at the oxygen K-edge in order to examine the effect of octahedral ion composition on the near edge structures and explore whether these may shed some light on previously reported major variations in the optical absorption coefficient (epsilon) for the spin-allowed d-d band transitions due to tetrahedrally coordinated Fe2+ in optical spectra of oxide spinels. Interpretation of the energy loss near edge structure (ELNES) spectra was aided using the multiple scattering code FEFF8.40. For the chromate samples spin polarised calculations were included. Gold's iterative deconvolution method was utilized to improve on energy resolution, resulting in spectra equal in merit to those recorded by technically superior instruments. Results include absolute energy positions and interpretation of ELNES features in terms of transitions to available states. We conclude that the major causes of differences in the optical absorption coefficient mentioned above are hybridization between oxygen p- and octahedral metal orbitals. Our study does not support the idea presented by other authors that there exists a local antiferromagnetic ordering in MgCr2O4 at room temperature.
|
|
| 9. |
|
|
| 10. |
|
|
| 11. |
|
|
| 12. |
|
|
| 13. |
- D'Ippolito, Veronica, et al.
(author)
-
Crystallographic and spectroscopic characterisation of a natural Zn-rich spinel approaching the endmember gahnite (ZnAl2O4) composition
- 2013
-
In: Mineralogical magazine. - : Mineralogical Society. - 0026-461X .- 1471-8022. ; 77, s. 2941-2953
-
Journal article (peer-reviewed)abstract
- The crystal chemistry of a natural, gem-quality, blue-grey Zn-rich spinel crystal from Jemaa, Kaduna State, Nigeria, was studied using electron microprobe, single-crystal X-ray diffraction, optical absorption and Raman spectroscopies. The composition of the crystal approaches the gahnite endmember (ZnAl2O4), ∼94 mol.%, with the remainder being dominated by a hercynite component (FeAl2O4). The unit-cell dimension is 8.0850(3) Å and the tetrahedral and octahedral bond distances are determined asT–O 1.9485(6) Å andM–O 1.9137(3) Å. Crystal chemical analysis resulted in the empirical structural formulaT(Zn0.94Fe2+0.03Al0.03)M(Al1.96Fe2+0.03Fe3+0.01)O4, which shows Zn and Al almost fully ordered in the tetrahedrally and octahedrally coordinatedTandMsites, respectively. Raman spectra obtained using the excitation of the blue 473.1 nm line of a Nd:YAG laser display three of the five Raman-active modes predicted for the general oxide spinel group of minerals. These are the Egmode at 420.6 cm–1and the T2gmodes at 510 cm–1and 661 cm–1, due to vibrations in the AlO6octahedra. Optical absorption spectra recorded in the UV/VIS-NIR-MIR range 2000 29000 cm–1show a dominant absorption band at ∼5000 cm–1which is caused by spin-allowed electronicd–dtransitions in Fe2+located at theTsites. The blue-grey hue exhibited by the sample is mainly due to spin-forbidden electronic transitions inTFe2+and toMFe2+↔MFe3+intervalence charge transfer, and the poor saturation of the colour is due to the small concentration of Fe2+and Fe3+.
|
|
| 14. |
- Grew, Edward S., et al.
(author)
-
Nomenclature of the garnet supergroup
- 2013
-
In: American Mineralogist. - : Mineralogical Society of America. - 0003-004X .- 1945-3027. ; 98, s. 785-811
-
Journal article (peer-reviewed)
|
|
| 15. |
|
|
| 16. |
- Hålenius, Ulf, et al.
(author)
-
Oxyplumboroméite, Pb2Sb2O7, a new mineral species of the pyrochlore supergroup from Harstigen Mine, Värmland, Sweden
- 2013
-
In: Mineralogical magazine. - : Mineralogical Society. - 0026-461X .- 1471-8022. ; 77:7, s. 2931-2939
-
Journal article (peer-reviewed)abstract
- Oxyplumboroméite, Pb2Sb2O7, is a new mineral of the roméite group of the pyrochlore supergroup (IMA 2013-042). It is found together with calcite and leucophoenicite in fissure fillings in tephroite skarn at the Harstigen mine, Värmland, Sweden. The mineral occurs as yellow to brownish yellow rounded grains or imperfect octahedra. Oxyplumboroméite has a Mohs hardness of ∼5, a calculated density of 6.732 g/cm3 and is isotropic with a calculated refractive index of 2.061. Oxyplumboroméite is cubic, space group Fdm, with the unit-cell parameters a = 10.3783(6) Å, V = 1117.84(11) Å3 and Z = 8. The strongest five X-ray powder-diffraction lines [d in Å(I)(hkl)] are: 2.9915(100)(222), 2.5928(32)(400), 1.8332(48)(440), 1.5638(38)(622) and 1.1900(12)(662). The crystal structure of oxyplumboroméite was refined to an R1 index of 3.02% using 160 unique reflections collected with MoKα radiation. Electron microprobe analyses in combination with crystal-structure refinement, infrared, Mössbauer and electronic absorption spectroscopy resulted in the empirical formula A(Pb0.92Ca0.87Mn0.09Sr0.01Na0.05)Σ1.93B(Sb1.73Fe3+0.27)Σ2.00X+Y[O6.64(OH)0.03]Σ6.67. Oxyplumboroméite is the Pb analogue of oxycalcioroméite, ideally Ca2Sb2O7.
|
|
| 17. |
|
|
| 18. |
|
|
| 19. |
|
|
| 20. |
|
|
| 21. |
|
|
| 22. |
|
|
| 23. |
- Johansson, Åke, et al.
(author)
-
Petrogenesis and geotectonic setting of early Svecofennian arc cumulates in the Roslagen area, east-central Sweden
- 2012
-
In: Geological Journal. - : Wiley. - 0072-1050 .- 1099-1034. ; 47:6, s. 557-593
-
Journal article (peer-reviewed)abstract
- Several intrusions of ultrabasic to basic composition occur in the Roslagen area of east-central Sweden in close spatial and temporal association with the surrounding 1.90-1.87Ga old early orogenic Svecofennian granitoids. An imprecise Sm-Nd WR errorchron yields an age of 1895±71Ma. In spite of the penetrative deformation in the granitoids, the basic-ultrabasic rocks mostly appear undeformed and largely preserve magmatic textures with plagioclase, olivine (in some rock types), orthopyroxene and clinopyroxene, and amphibole as major constituents. The plagioclase is typically very anorthitic (ca. An 90). The Roslagen intrusions range in composition from primitive to evolved (Mg# 80 to 49) but contain only 40-50wt% SiO 2. Many samples are highly elevated in Al 2O 3 (up to 30wt%), CaO (up to 16wt%) and Sr (up to 800ppm), with strongly positive Eu and Sr anomalies, in line with being plagioclase cumulates. Although masked by cumulus effects, the relative trace element contents indicate a volcanic arc signature. The initial Nd isotope composition is homogeneously 'mildly depleted', with ε Nd of +0.3 to +1.1, and the initial Sr isotope composition 'mildly enriched', with ε Sr of +8 to +15. Non-cumulus rocks with small Eu and Sr anomalies can be used to deduce the composition of the parental magma. This LILE- and LREE-enriched and HFSE-depleted high-alumina basalt magma, with Mg# of ca. 50-60 and Ca# of ca. 80, most likely formed by partial melting of mantle material, enriched by fluids in a subduction environment, at 1.9Ga. The cumulate rocks apparently crystallized from a somewhat more evolved water-rich magma with Mg# of ca. 40. Crystallization was followed by the development of late-magmatic to post-magmatic coronas between olivine and plagioclase in the presence of H 2O-rich fluids. The subduction-related setting would make these intrusions Palaeoproterozoic counterparts of Alaskan-type ultramafic intrusions, but they differ from those in being plagioclase enriched, possibly reflecting different levels of exposure.
|
|
| 24. |
|
|
| 25. |
|
|
