| 1. |
- Björklund, Sebastian, et al.
(författare)
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Humidity scanning quartz crystal microbalance with dissipation monitoring setup for determination of sorption-desorption isotherms and rheological changes
- 2015
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Ingår i: Review of Scientific Instruments. - : American Institute of Physics (AIP). - 0034-6748 .- 1089-7623. ; 86:5
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Tidskriftsartikel (refereegranskat)abstract
- A new method to determine water sorption-desorption isotherms with high resolution in the complete range of water activities (relative humidities) is presented. The method is based on quartz crystal microbalance with dissipation monitoring (QCM-D). The QCM-D is equipped with a humidity module in which the sample film is kept in air with controlled humidity. The experimental setup allows for continuous scanning of the relative humidity from either dry to humid conditions or vice versa. The amount of water sorbed or desorbed from the sample is determined from the resonance frequencies of the coated quartz sensor, via analysis of the overtone dependence. In addition, the method allows for characterization of hydration induced changes of the rheological properties from the dissipation data, which is closely connected to the viscoelasticity of the film. The accuracy of the humidity scanning setup is confirmed in control experiments. Sorption-desorption isotherms of pig gastric mucin and lysozyme, obtained by the new method, show good agreement with previous results. Finally, we show that the deposition technique used to coat the quartz sensor influences the QCM-D data and how this issue can be used to obtain further information on the effect of hydration. In particular, we demonstrate that spin-coating represents an attractive alternative to obtain sorption-desorption isotherms, while drop-coating provides additional information on changes of the rheological properties during hydration.
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| 2. |
- Hartman, Henrik, et al.
(författare)
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First storage of ion beams in the Double Electrostatic Ion-Ring Experiment : DESIREE
- 2013
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Ingår i: Review of Scientific Instruments. - : American Institute of Physics (AIP). - 0034-6748 .- 1089-7623. ; 84:5
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Tidskriftsartikel (refereegranskat)abstract
- We report on the first storage of ion beams in the Double ElectroStatic Ion Ring ExpEriment, DESIREE, at Stockholm University. We have produced beams of atomic carbon anions and small carbon anion molecules (Cn-, n = 1, 2, 3, 4) in a sputter ion source. The ion beams were accelerated to 10 keV kinetic energy and stored in an electrostatic ion storage ring enclosed in a vacuum chamber at 13 K. For 10 keV C2- molecular anions we measure the residual-gas limited beam storage lifetime to be 448 s +/- 18 s with two independent detector systems. Using the measured storage lifetimes we estimate that the residual gas pressure is in the 10-14 mbar range. When high current ion beams are injected, the number of stored particles does not follow a single exponential decay law as would be expected for stored particles lost solely due to electron detachment in collision with the residual-gas. Instead, we observe a faster initial decay rate, which we ascribe to the effect of the space charge of the ion beam on the storage capacity.
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| 3. |
- Yongliang, Cheng, et al.
(författare)
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An Improved Separation Method of Multi-Components Signal for Sensing Based on Time-Frequency Representation
- 2019
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Ingår i: Review of Scientific Instruments. - : American Institute of Physics (AIP). - 0034-6748 .- 1089-7623. ; 6:90
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Tidskriftsartikel (refereegranskat)abstract
- In many situations, it is essential to analyze a nonstationary signal for sensing whose components not only overlapped in time-frequency domain (TFD) but also have different durations. In order to address this issue, an improved separation method based on the time-frequency distribution is proposed in this paper. This method computes the time-frequency representation (TFR) of the signal and extracts the instantaneous frequency (IF) of components by a two-dimensional peak search in a limited area in which normalized energy is greater than the set threshold value. If there is more than one peak from a TFR, IFs of components can be determined and linked by a method of minimum slope difference. After the IFs are obtained, the improved time-frequency filtering algorithm is used to reconstruct the component of the signal. We continue this until the residual energy in the TFD is smaller than a fraction of the initial TFD energy. Different from previous methods, the improved method can separate the signal whose components overlapped in TFR and have different time durations. Simulation results have shown the effectiveness of the proposed method.
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