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| 2. |
- Bieron, Jacek, et al.
(författare)
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Multiconfiguration Dirac-Hartree-Fock calculations of the electric dipole moment of radium induced by the nuclear Schiff moment
- 2009
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Physical Society. - 1050-2947 .- 1094-1622. ; 80:1
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Tidskriftsartikel (refereegranskat)abstract
- The multiconfiguration Dirac-Hartree-Fock theory has been employed to calculate the electric dipole moment of the 7s6d 3D2 state of radium induced by the nuclear Schiff moment. The results are dominated by valence and core-valence electron correlation effects. We show that the correlation effects can be evaluated in a converged series of multiconfiguration expansions.
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| 3. |
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| 4. |
- Filippin, Livio, et al.
(författare)
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Multiconfiguration calculations of electronic isotope shift factors in Al I
- 2016
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Physical Society. - 1050-2947 .- 1094-1622. ; 94:6 : 062508
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Tidskriftsartikel (refereegranskat)abstract
- The present work reports results from systematic multiconfiguration Dirac–Hartree–Fock calculations of electronic isotope shift factors for a set of transitions between low-lying levels of neutral aluminium. These electronic quantities together with observed isotope shifts between different pairs of isotopes provide the changes in mean-square charge radii of the atomic nuclei. Two computational approaches are adopted for the estimation of the mass- and field-shift factors. Within these approaches, different models for electron correlation are explored in a systematic way to determine a reliable computational strategy and to estimate theoretical error bars of the isotope shift factors.
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| 5. |
- Froese Fischer, Charlotte, et al.
(författare)
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Doublet-quartet energy separation in boron : a partitioned-correlationfunction- interaction method
- 2013
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Physical Society. - 1050-2947 .- 1094-1622. ; 88:6
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Tidskriftsartikel (refereegranskat)abstract
- No lines have been observed for transitions between the doublet and quartet levels of B I. Consequently, energy levels based on observation for the latter are obtained through extrapolation of wavelengths along the isoelectronic sequence for the 2s22p 2Po 3/2 – 2s2p2 4P5/2 transition. In this paper, accurate theoretical excitation energies from a partitioned-correlation-function-interaction (PCFI) method are reported for B I that include both relativistic effects in the Breit-Pauli approximation and a finite mass correction. Results are compared with extrapolated values from observed data. For B I our estimate of the excitation energy 28 959 ± 5 cm−1 is in better agreement with the values obtained by Edl´en et al. (1969) than those reported by Kramida and Ryabtsev (2007). Our method is validated by applying the same procedure to the separation of these levels in C II.
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| 7. |
- Grumer, Jon, et al.
(författare)
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The effect of an external magnetic field on the determination of E1M1 two-photon decay rates in Be-like ions
- 2013
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Physical Society. - 1050-2947 .- 1094-1622. ; 88
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Tidskriftsartikel (refereegranskat)abstract
- In this work we report on ab initio theoretical results for the magnetic-field-induced 2s 2p 3P0 → 2s2 1S0 E1 transition for ions in the beryllium isoelectronic sequence between Z = 5 and 92. It has been proposed that the rate of the E1M1 two-photon transition 2s 2p 3P0 → 2s2 1S0 can be extracted from the lifetime of the 3P0 state in Be-like ions with zero nuclear spin by employing resonant recombination in a storage ring. This experimental approach involves a perturbing external magnetic field. The effect of this field needs to be evaluated in order to properly extract the two-photon rate from the measured decay curves. The magnetic-field-induced transition rates are carefully evaluated, and it is shown that, with a typical storage-ring field strength, it is dominant or of the same order as the E1M1 rate for low- and mid-Z ions. Results for several field strengths and ions are presented, and we also give a simple Z-dependent formula for the rate. We estimate the uncertainties of our model to be within 5% for low- and mid-Z ions and slightly larger for more highly charged ions. Furthermore we evaluate the importance of including both perturber states, 3P1 and 1P1, and it is s
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| 8. |
- Guise, Nicholas, et al.
(författare)
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Measurement of the Kr XVIII 3d 2D5/2 lifetime in a unitary Penning Trap
- 2014
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Institute of Physics (AIP). - 1050-2947 .- 1094-1622. ; 89:4
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Tidskriftsartikel (refereegranskat)abstract
- A different technique is used to study the radiative decay of a metastable state in multiply ionized atoms.With use of a unitary Penning trap to selectively capture Kr17+ ions from an ion source at NIST, the decay of the 3d 2D5/2 metastable state is measured in isolation at low energy, without any active cooling. The highly ionized atoms are trapped in the fine structure of the electronic ground configuration with an energy spread of 4(1) eV, which is narrower than within the ion source by a factor of about 100. By observing the visible 637-nm photon emission of the forbidden transition from the 3d 2D5/2 level to the ground state, we measured its radiative lifetime to be τ = 24.48 ms ± 0.28stat. ms ± 0.14syst. ms. Remarkably, various theoretical predictions for this relativistic Rydberg atom are in agreement with our measurement at the 1% level.
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| 9. |
- Hartman, Henrik, et al.
(författare)
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Experimental and theoretical lifetimes and transition probabilities in Sb i
- 2010
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Physiological Society. - 1050-2947 .- 1094-1622. ; 82:5
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Tidskriftsartikel (refereegranskat)abstract
- We present experimental atomic lifetimes for 12 levels in Sb i. The levels belong to the 5p2(3P)6s 2P, 4P, and 5p2(3P)5d 4P, 4F, and 2F terms. The lifetimes were measured using time-resolved laser-induced fluorescence. In addition, we report calculations of transition probabilities in Sb i using a multiconfigurational Dirac-Hartree-Fock method. The physical model was tested through comparisons between theoretical and experimental lifetimes for 5d and 6s levels. The lifetimes of the 5d 4F3/2,5/2,7/2 levels (19.5, 7.8, and 54 ns, respectively) depend strongly on the J value. This is explained by different degrees of level mixing for the different levels in the 4F term.
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| 10. |
- Li, Jiguang, et al.
(författare)
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Effects of the electron correlation and Breit and hyperfine interactions on the lifetime of the 2p53s states in neutral neon
- 2012
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : Americal Physical Society. - 1050-2947 .- 1094-1622. ; 86:5
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Tidskriftsartikel (refereegranskat)abstract
- In the framework of the multiconfiguration Dirac-Hartree-Fock method, we investigate the transition properties of four excited states in the 2p53s configuration of neutral neon. The electron correlation effects are taken into account systematically by using the active space approach. The effect of higher-order correlation on fine structures is shown. We also study the influence of the Breit interaction and find that it reduces the oscillator strength of the 3 P1o-1 S0 transition by 17%. It turns out that the inclusion of the Breit interaction is essential even for such a light atomic system. Our ab initio calculated line strengths, oscillator strengths, and transition rates are compared with other theoretical values and experimental measurements. Good agreement is found except for the 3 P2o-1 S0 M2 transition for which discrepancies of around 15% between theories and experiments remain. In addition, the impact of hyperfine interactions on the lifetimes of the 3 P0o and 3 P2o metastable states is investigated for the 21Ne isotope (I=3/2). We find that hyperfine interactions reduce the lifetimes drastically. For the 3 P0o state the lifetime is decreased by a factor of 630.
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