| 1. |
- Lund, Anja, et al.
(författare)
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Melt spinning of beta-phase poly(vinylidene fluoride) yarns with and without a conductive core
- 2011
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Ingår i: Journal of Applied Polymer Science. - : Wiley Periodicals, Inc.. - 0021-8995 .- 1097-4628. ; 120:2, s. 1080-1089
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Tidskriftsartikel (refereegranskat)abstract
- When poly(vinylidene fluoride) (PVDF) is to be used as a piezoelectric material, the processing must include the formation of polar β-phase crystallites, as well as the application of electrically conducting charge collectors, that is, electrodes. In this article, results from the melt spinning of PVDF yarns and a novel bicomponent PVDF-yarn with a conductive carbon black/polypropylene (CB/PP) core are presented. Melt spinning has been done under conditions typical for industrial large-scale fiber production. The effects on the resulting crystalline structure of varying the spinning velocity, draw rate, and draw temperature are discussed. The results show that, for maximum α-to-β phase transformation, cold drawing should take place at a temperature between 70 and 90°C, and both the draw ratio and the draw rate should be as high as possible. It was observed that the cold drawing necessary to form β-phase crystallinity simultaneously leads to a decrease in the core conductivity of the bicomponent yarns. In this work, the melt spinning of bicomponent fibers with high-β-phase PVDF in the sheath and a CB/PP core was successfully accomplished. The core material remained electrically conductive, paving the way for the use of a CB-polymer compound as inner electrode in the melt spinning of piezoelectric bicomponent fibers.
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| 2. |
- Lund, Anja, et al.
(författare)
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Melt spinning of poly(vinylidene fluoride) fibers and the influence of spinning parameters on beta-phase crystallinity
- 2010
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Ingår i: Journal of Applied Polymer Science. - : Wiley Periodicals, Inc. - 0021-8995 .- 1097-4628. ; 116:5, s. 2685-2693
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Tidskriftsartikel (refereegranskat)abstract
- The effect of melt spinning and cold drawing parameters on the formation of β-phase crystallinity in Poly(Vinylidene Fluoride) (PVDF) fibres, and ways of increasing such crystallinity, were studied. Fibres were melt-spun using four different melt draw ratios, and subsequently cold-drawn at different draw ratios. The maximum draw ratio in cold drawing was dependent on the draw ratio used in the melt spinning. The crystalline structure of the fibres was studied mainly by DSC and XRD. Results showed that the degree of crystallinity in the fibres was determined by the melt draw ratio, and that before cold drawing the crystalline structure of the fibres was predominantly in the α form. By cold drawing, α-phase crystallites could be transformed into the β-phase. It was established that, at certain conditions of melt spinning and cold drawing, PVDF fibres containing up to 80% of mainly β form crystallinity can be prepared. It is further proposed that fibres spun at a sufficiently high melt draw ratio consist to a large extent of extended-chain crystals, and this greatly affects the melting point of the PVDF. Thus DSC melting point data were shown to be insufficient to determine the crystalline phase of PVDF.
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| 3. |
- Lund, Anja, et al.
(författare)
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Piezoelectric polymeric bicomponent fibers produced by melt spinning
- 2012
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Ingår i: Journal of Applied Polymer Science. - : Wiley Periodicals, Inc.. - 0021-8995 .- 1097-4628. ; 126:2, s. 490-500
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Tidskriftsartikel (refereegranskat)abstract
- Melt spinning of a novel piezoelectric bicomponent fiber, with poly(vinylidene fluoride) as the electroactive sheath component, has been demonstrated. An electrically conductive compound of carbon black (CB) and high density polyethylene was used as core material, working as an inner electrode. A force sensor consisting of a number of fibers embedded in a soft CB/polyolefin elastomer matrix was manufactured for characterization. The fibers showed a clear piezoelectric effect, with a voltage output (peak-to-peak) of up to 40 mV under lateral compression. This continuous all-polymer piezoelectric fiber introduces new possibilities toward minimal single fiber sensors as well as large area sensors produced in standard industrial weaving machines.
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| 4. |
- Nilsson, Erik, 1976, et al.
(författare)
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Poling and characterization of piezoelectric polymer fibers for use in textile sensors
- 2013
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Ingår i: Sensors and Actuators A-Physical. - : Elsevier S.A.. - 0924-4247 .- 1873-3069. ; 201, s. 477-486
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Tidskriftsartikel (refereegranskat)abstract
- This study reports on the poling and characteristics of a melt-spun piezoelectric bicomponent fiber with poly(vinylidene fluoride) (PVDF) as its sheath component and a conductive composite with carbon black (CB) and high density polyethylene (HDPE) as its core component. The influence of poling conditions on the piezoelectric properties of the fibers has been investigated. The poling parameters temperature, time and poling voltage have been varied and the piezoelectric effect of both contact- and corona-poled yarns have been evaluated. The results show that a high piezoelectric effect is achieved when the poling voltage is high as possible and the poling temperature is between 60°C and 120°C. It was also shown that permanent polarization is achieved in a time as short as 2 second in corona-poled fibers. A yarn exposed to a sinusoidal axial tension of 0.07% strain (the corresponding force amplitude was 0.05 N) shows an intrinsic voltage output of 4 V. The mean power from a 25 mm length of yarn is estimated to be 15nW. To demonstrate the fibers sensor properties, they are woven into a textile fabric from which a force sensor is manufactured and used to detect the heartbeat of a human.
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