| 1. |
- Backstrand, K., et al.
(författare)
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Total hydrocarbon flux dynamics at a subarctic mire in northern Sweden
- 2008
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Ingår i: Journal of Geophysical Research. - 0148-0227 .- 2156-2202. ; 113, s. G03026-
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Tidskriftsartikel (refereegranskat)abstract
- This is a study of the spatial and temporal variability of total hydrocarbon (THC) emissions from vegetation and soil at a subarctic mire, northern Sweden. THCs include methane (CH4) and nonmethane volatile organic compounds (NMVOCs), both of which are atmospherically important trace gases and constitute a significant proportion of the carbon exchange between biosphere and atmosphere. Reliable characterization of the magnitude and the dynamics of the THC fluxes from high latitude peatlands are important when considering to what extent trace gas emissions from such ecosystems may change and feed back on climate regulation as a result of warmer climate and melting permafrost. High frequency measurements of THC and carbon dioxide (CO2) were conducted during four sequential growing seasons in three localities representing the trophic range of plant communities at the mire. The magnitude of the THC flux followed the moisture gradient with increasing emissions from a dry Palsa site (2.2 +/- 0.1 mgC m(-2) d(-1)), to a wet intermediate melt feature with Sphagnum spp. (28 +/- 0.3 mgC m(-2) d(-1)) and highest emissions from a wet Eriophorum spp. site (122 +/- 1.4 mgC m(-2) d(-1)) (overall mean +/- 1 SE, n = 2254, 2231 and 2137). At the Palsa site, daytime THC flux was most strongly related to air temperature while daytime THC emissions at the Sphagnum site had a stronger relation to ground temperature. THC emissions at both the wet sites were correlated to net ecosystem exchange of CO2. An overall spatial correlation indicated that areas with highly productive vegetation communities also had high THC emission potential.
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| 2. |
- Bäckstrand, Kristina, et al.
(författare)
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Non-methane volatile organic compound flux from a subarctic mire in Northern Sweden
- 2008
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Ingår i: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 60:2, s. 226-237
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Tidskriftsartikel (refereegranskat)abstract
- Biogenic NMVOCs are mainly formed by plants and microorganisms. They have strong impact on the local atmospheric chemistry when emitted to the atmosphere. The objective of this study was to determine if there are significant emissions of non-methane volatile organic compounds (NMVOCs) from a subarctic mire in northern Sweden. Subarctic peatlands in discontinuous permafrost regions are undergoing substantial environmental changes due to their high sensitivity to climate warming and there is need for including NMVOCs in the overall carbon budget. Automatic and manual chamber measurements were used to estimate NMVOC fluxes from three dominating subhabitats on the mire during three growing seasons. Emission rates varied and were related to plant species distribution and seasonal net ecosystem exchange of carbon dioxide. The highest fluxes were observed from wetter sites dominated by Eriophorum and Sphagnum spp. Total NMVOC emissions from the mire (similar to 17 ha) is estimated to consist of similar to 150 kgC during a growing season with 150 d. NMVOC fluxes can account for similar to 5% of total net carbon exchange (-3177 kgC) at the mire during the same period. NMVOC emissions are therefore a significant component in a local carbon budget for peatlands.
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| 3. |
- Conley, Daniel, et al.
(författare)
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Past, present and future state of the biogeochemical Si cycle in the Baltic Sea
- 2008
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Ingår i: Journal of Marine Systems. - : Elsevier BV. - 0924-7963 .- 1879-1573. ; 73:3-4, s. 338-346
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Tidskriftsartikel (refereegranskat)abstract
- The Baltic Sea is one of many aquatic ecosystems that show long-term declines in dissolved silicate (DSi) concentrations due to anthropogenic alteration of the biogeochemical Si cycle. Reductions in DSi in aquatic ecosystems have been coupled to hydrological regulation reducing inputs, but also with eutrophication, although the relative significance of both processes remains unknown for the observed reductions in DSi concentrations. Here we combine present and historical data on water column DSi concentrations, together with estimates of present river DSi loads to the Baltic, the load prior to damming together with estimates of the long-term accumulation of BSi in sediments. In addition, a model has been used to evaluate the past, present and future state of the biogeochemical Si cycle in the Baltic Sea. The present day DSi load to the Baltic Sea is 855 ktons y(-1). Hydrological regulation and eutrophication of inland waters can account for a reduction of 420 ktons y(-1) less riverine DSi entering the Baltic Sea today. Using published data on basin-wide accumulation rates we estimate that 1074 ktons y(-1) of biogenic silica (BSi) is accumulating in the sediments, which is 36% higher than earlier estimates from the literature (791 ktons y(-1)). The difference is largely due to the high reported sedimentation rates in the Bothnian Sea and the Bothnian Bay. Using river DSi loads and estimated BSi accumulation, our model was not able to estimate water column DSi concentrations as burial estimates exceeded DSi inputs. The model was then used to estimate the BSi burial from measured DSi concentrations and DSj load. The model estimate for the total burial of BSi in all three basins was 620 ktons y(-1), 74% less than estimated from sedimentation rates and sediment BSi concentrations. The model predicted 20% less BSi accumulation in the Baltic Proper and 10% less in the Bothnian Bay than estimated, but with significantly less BSi accumulation in the Bothnian Sea by a factor of 3. The model suggests there is an overestimation of basin-wide sedimentation rates in the Bothnian Bay and the Bothnian Sea. In the Baltic Proper, modelling shows that historical DSi concentrations were 2.6 times higher at the turn of the last century (ca. 1900) than at present. Although the DSi decrease has leveled out and at present there are only restricted areas of the Baltic Sea with limiting DSi concentrations, further declines in DSi concentrations will lead to widespread DSi limitation of diatoms with severe implications for the food web.
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| 4. |
- Hodgins, Sheelagh, et al.
(författare)
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A multisite study of community treatment programs for mentally ill offenders with major mental disorders : Design, measures, and the forensic sample
- 2007
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Ingår i: Criminal justice and behavior. - : SAGE Publications. - 0093-8548 .- 1552-3594. ; 34:2, s. 211-228
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Tidskriftsartikel (refereegranskat)abstract
- This article presents reasons for undertaking ""The Comparative Study of the Prevention of Crime and Violence by Mentally Ill Persons"" and reasons for decisions regarding the study design and choice of measures. A brief portrait of the forensic patients that have been recruited is also presented. Community treatment programs could offer long-term cost-effective care for offenders with major mental disorders (MMDs). The study aims to identify the necessary ingredients of an effective program. Sites are selected in four countries where identification of most, if not all, persons with MMD who commit crimes within the catchment area was possible. Within each site, two samples of patients with MMD are recruited, one from a forensic hospital and one from a general psychiatric hospital. Assessments are completed prior to discharge. Participants are followed during a 5-year period. Comparisons of the forensic patients recruited in the four sites indicate many more similarities than differences.
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| 5. |
- Humborg, Christoph, et al.
(författare)
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Silicon and the Baltic Sea Long-term Si decrease in the Baltic Sea - A conceivable ecological risk?
- 2008
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Ingår i: Journal of Marine Systems. - : Elsevier. - 0924-7963 .- 1879-1573. ; 73:3-4, s. 221-222
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- Since the pioneering work of Schelske and Stoermer (1971) and Schelske et al., 1983 C.L. Schelske, E.F. Stoermer, D.J. Conley, J.A. Robbins and R.M. Glover, Early eutrophication in the Lower Great-Lakes — new evidence from biogenic silica in sediments, Science 222 (1983), pp. 320–322. View Record in Scopus | Cited By in Scopus (56)Schelske et al. (1983) it has been known that eutrophication of aquatic systems leads to depletion in dissolved silicate (DSi). Early studies on the Nile River have shown that the construction of dams leads to DSi decrease downstream due to the formation of additional deposition sites of biogenic silica (BSi) that was thought to consist mainly of diatoms. In the Baltic Sea there was a perception in the scientific community that DSi concentrations were high and therefore, that DSi concentrations were not limiting for diatom growth. Long-term trend analyses on DSi concentrations in the Baltic have shown decreasing trends in the 1970s and 1980s, whereas similar analysis for the 1990s concluded that DSi concentrations were no longer decreasing, but rather levelling off. Consequently, observations of reduced abundance of diatoms in the early 1990s were attributed to mild winters rather than low DSi concentrations, i.e., a low turbulence regime in the water column favouring non-siliceous algae. However, decadal nutrient trends in the Baltic Sea are significantly influenced by the large and varying internal Si pools in the sediments and deep water masses similar to that described for P dynamics in the Baltic Sea. No one seriously addressed the longer trends in DSi concentrations over the last century, whereas many studies estimated these changes for N and P.The EU funded research project SIBER (Silicate and Baltic Sea Ecosystem Response; EVK3-CT-2002-00069) began in 2002 with the objectives of understanding the major changes in Si dynamics in the Baltic Sea during the last century. The SIBER project addressed various aspects of the biogeochemical Si cycle in the Baltic Sea including constraining Si budgets for the Baltic Sea and its catchment, experiments describing the growth characteristics of Baltic diatoms related to the long-term trends in monitoring data of Baltic Sea diatoms.Si budgets are addressed by several papers in this special issue. Humborg et al. and Sferratore et al. describe riverine Si fluxes. Pastuszak et al. address estuarine Si fluxes. Redfield ratios including DSi and their development in the Baltic Sea are described by Danielsson et al.Possible ecosystem effects of changes in Redfield nutrient ratios are analysed in the paper by Olli et al. who examine phytoplankton responses in the Gulf of Riga and by Wasmund et al. who investigate long-term trends in phytoplankton species in the Kiel Bight. Spilling and Markager describe growth characteristics of Baltic Sea diatoms. Finally, in their paper Conley et al. present a long-term Si budget for the entire Baltic Sea for the first time.The Baltic Sea biogeochemical Si cycle has been fundamentally changed within the last century not only as a consequence of river regulation and lake eutrophication, but also through increases in the sediment accumulation of BSi (Conley et al.). Sediment accumulation of BSi has increased by a factor on 1.9 due to increased diatom growth from marine eutrophication. Results from the SIBER project indicate that DSi concentration were ca. 36 µM a century ago in the Baltic proper compared to ca. 13 µM observed today (Conley et al.). In fact, DSi concentrations have changed much more dramatically compared to N and P regarding the total changes in the available nutrient stocks. Similar changes have occurred in other large water bodies with respect to size and volume, i.e. the North American Great Lakes with long residence times where DSi decreased from 80–100 µM to ca. 25 µM. Surprisingly, such a major change in nutrient inventories has not been reported earlier in this well investigated coastal system. We are only starting to understand the possible ecological consequences, such as the occurrence of different diatom species that are less silicified and its implication for the sedimentation fluxes and carbon flux to benthic communities. The SIBER project has shown that a dramatic change in DSi concentrations is possible within a very short time period, although the situation appears stable today, perhaps since the drivers for this change, i.e. eutrophication and river regulation, have not changed within the last 30 years. However, even a slight increase in N and P loads and/or further damming of rivers may drive the Baltic Sea into Si-limitation.
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