| 1. |
- Eivazihollagh, Alireza, et al.
(författare)
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On chelating surfactants : Molecular perspectives and application prospects
- 2019
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Ingår i: Journal of Molecular Liquids. - : Elsevier BV. - 0167-7322 .- 1873-3166. ; 278, s. 688-705
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Tidskriftsartikel (refereegranskat)abstract
- Chelating agents, molecules that very strongly coordinates certain metal ions, are used industrially as well as in consumer products to minimize disturbances and increase performance of reactions and applications. The widely used sequestering agents, nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA) belong to this branch of readily water-soluble compounds. When these chemical structures also have hydrophobic parts, they are prone to adsorb at air-water interfaces and to self-assemble. Such bifunctional molecules can be called chelating surfactants and will have more extended utilization prospects than common chelating agents or ordinary ionic surfactants. The present review attempts to highlight the fundamental behavior of chelating surfactants in solution and at interfaces, and their very specific interactions with metal ions. Methods to recover chelating surfactants from metal chelates are also described. Moreover, utilization of chelating surfactants in applications for metal removal in environmental engineering and mineral processing, as well as for metal control in the fields of biology, chemistry and physics, is exemplified and discussed.
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| 2. |
- Wågberg, Lars, et al.
(författare)
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The build-up of polyelectrolyte multilayers of microfibrillated cellulose and cationic polyelectrolytes
- 2008
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Ingår i: Langmuir. - : American Chemical Society (ACS). - 0743-7463 .- 1520-5827. ; 24:3, s. 784-795
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Tidskriftsartikel (refereegranskat)abstract
- A new type of nanocellulosic material has been prepared by high-pressure homogenization of carboxymethylated cellulose fibers followed by ultrasonication and centrifugation. This material had a cylindrical cross-section as shown by transmission electron microscopy with a diameter of 5-15 nm and a length of up to 1 mu m. Calculations, using the Poisson-Boltzmann equation, showed that the surface potential was between 200 and 250 mV, depending on the pH, the salt concentration, and the size of the fibrils. They also showed that the carboxyl groups on the surface of the nanofibrils are not fully dissociated until the pH has reached pH = similar to 10 in deionized water. Calculations of the interaction between the fibrils using the Derjaguin-Landau-Verwey-Overbeek theory and assuming a cylindrical geometry indicated that there is a large electrostatic repulsion between these fibrils, provided the carboxyl groups are dissociated. If the pH is too low and/or the salt concentration is too high, there will be a large attraction between the fibrils, leading to a rapid aggregation of the fibrils. It is also possible to form polyelectrolyte multilayers (PEMs) by combining different types of polyelectrolytes and microfibrillated cellulose (MFC). In this study, silicon oxide surfaces were first treated with cationic polyelectrolytes before the surfaces were exposed to MFC. The build-up of the layers was monitored with ellipsometry, and they show that it is possible to form very well-defined layers by combinations of MFC and different types of polyelectrolytes and different ionic strengths of the solutions during the adsorption of the polyelectrolyte. A polyelectrolyte with a three-dimensional structure leads to the build-up of thick layers of MFC, whereas the use of a highly charged linear polyelectrolyte leads to the formation of thinner layers of MFC. An increase in the salt concentration during the adsorption of the polyelectrolyte results in the formation of thicker layers of MFC, indicating that the structure of the adsorbed polyelectrolyte has a large influence on the formation of the MFC layer. The films of polyelectrolytes and MFC were so smooth and well-defined that they showed clearly different interference colors, depending on the film thickness. A comparison between the thickness of the films, as measured with ellipsometry, and the thickness estimated from their colors showed good agreement, assuming that the films consisted mainly of solid cellulose with a refractive index of 1.53. Carboxymethylated MFC is thus a new type of nanomaterial that can be combined with oppositely charged polyelectrolytes to form well-defined layers that may be used to form, for example, new types of sensor materials.
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| 3. |
- Brunnstrom, Kjell, 1960-, et al.
(författare)
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Statistical quality of experience analysis: on planning the sample size and statistical significance testing
- 2018
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Ingår i: Journal of Electronic Imaging (JEI). - SPIE/IS&T : IS&T - the Society for Imaging Science and Technology. - 1017-9909 .- 1560-229X. ; 27:5, s. 053013-1-053013-11
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Tidskriftsartikel (refereegranskat)abstract
- This paper analyzes how an experimenter can balance errors in subjective video quality tests betweenthe statistical power of finding an effect if it is there and not claiming that an effect is there if the effect is not there,i.e., balancing Type I and Type II errors. The risk of committing Type I errors increases with the number ofcomparisons that are performed in statistical tests. We will show that when controlling for this and at thesame time keeping the power of the experiment at a reasonably high level, it is unlikely that the number oftest subjects that are normally used and recommended by the International Telecommunication Union (ITU),i.e., 15 is sufficient but the number used by the Video Quality Experts Group (VQEG), i.e., 24 is more likelyto be sufficient. Examples will also be given for the influence of Type I error on the statistical significance ofcomparing objective metrics by correlation. We also present a comparison between parametric and nonparametricstatistics. The comparison targets the question whether we would reach different conclusions on the statisticaldifference between the video quality ratings of different video clips in a subjective test, based on thecomparison between the student T-test and the Mann–Whitney U-test. We found that there was hardly a differencewhen few comparisons are compensated for, i.e., then almost the same conclusions are reached. Whenthe number of comparisons is increased, then larger and larger differences between the two methods arerevealed. In these cases, the parametric T-test gives clearly more significant cases, than the nonparametrictest, which makes it more important to investigate whether the assumptions are met for performing a certaintest.
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| 4. |
- Ekener, Elisabeth, 1963-, et al.
(författare)
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Developing Life Cycle Sustainability Assessment methodology by applying values-based sustainability weighting - Tested on biomass based and fossil transportation fuels
- 2018
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Ingår i: Journal of Cleaner Production. - : Elsevier BV. - 0959-6526 .- 1879-1786. ; 181, s. 337-351
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Tidskriftsartikel (refereegranskat)abstract
- The production and use of transportation fuels can lead to sustainability impacts. Assessing them simultaneously in a holistic way is a challenge. This paper examines methodology for assessing the sustainability performance of products in a more integrated way, including a broad range of social impacts. Life Cycle Sustainability Assessment (LCSA) methodology is applied for this assessment. LSCA often constitutes of the integration of results from social LCA (S-LCA), environmental life cycle assessment (E-LCA) and life cycle costing (LCC). In this study, an S-LCA from an earlier project is extended with a positive social aspect, as well as refined and detailed. E-LCA and LCC results are built from LCA database and literature. Multi Criteria Decision Analysis (MCDA) methodology is applied to integrate the results from the three different assessments into an LCSA. The weighting of key sustainability dimensions in the MCDA is performed in different ways, where the sustainability dimensions are prioritized differently priority based on the assumed values of different stakeholder profiles (Egalitarian, Hierarchist, and Individualist). The developed methodology is tested on selected biomass based and fossil transportation fuels - ethanol produced from Brazilian sugarcane and US corn/maize, and petrol produced from Russian and Nigerian crude oils, where it delineates differences in sustainability performance between products assessed. The outcome in terms of relative ranking of the transportation fuel chains based on sustain ability performance differs when applying different decision-maker profiles. This result highlights and supports views that there is no one single answer regarding which of the alternatives that is most sustainable. Rather, it depends strongly upon the worldview and values held by the decision maker. A key conclusion is that sustainability assessments should pay more attention to potential differences in underlying values held by key stakeholders in relevant societal contexts. The LCSA methodology still faces challenges regarding results integration but MCDA in combination with stakeholder profiles appears to be a useful approach to build on further.
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| 5. |
- Koptyug, Andrey, 1956-, et al.
(författare)
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Electron Beam Melting: from Shape Freedom to Materials Properties Control at Macro- and Microscale
- 2021
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Ingår i: Proceedings of the THERMEC 2020, Graz, Austria. - : Trans Tech Publications. ; , s. 755-759
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Konferensbidrag (refereegranskat)abstract
- Electron beam melting (EBM) is one of the constantly developing powder bed fusion (PBF) additive manufacturing technologies (AM) offering advanced control over the manufacturing process. Freedom of component shapes is one of the AM competitive advantages already used at industrial and semi- industrial scale. Development of the additive manufacturing today is targeting both widening of the available materials classes, and introducing new enabling modalities. Present research is related to the new possibilities in tailoring different material properties within additively manufactured components effectively adding “fourth dimension to the 3D-printing”. Specific examples are given in relation to the electron beam melting, but majority of the conclusions are valid for the laser-based PBF techniques as well. Through manipulating beam energy deposition it is possible to tailor quite different material properties selectively within each manufactured component, including effective material density as well as thermal, mechanical, electrical and acoustic properties. It is also possible to acquire by choice both metal-metal composite and completely alloyed material, when blends of precursor powder are used together with the beam energy manipulation.
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| 6. |
- Pérez-Penichet, Carlos, et al.
(författare)
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Poster abstract : Augmenting WSNs with interoperable 802.15.4 sensor tags
- 2017
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Ingår i: SenSys 2017 - Proceedings of the 15th ACM Conference on Embedded Networked Sensor Systems. - New York, NY, USA : Association for Computing Machinery, Inc. - 9781450354592
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Konferensbidrag (refereegranskat)abstract
- The sensing capabilities of most sensor networks are fixed at the time of deployment. Adding new sensing capabilities to such networks is a costly and cumbersome process. We present Passive Sensor Tags, battery-free sensing devices that could be used to extend the sensing capabilities of an existing network. Sensor tags feature our new 802.15.4 receiver design which is suitable for micro-power operation, making battery-free tags possible. Because our tags can both transmit and receive 802.15.4 frames there is no need for any modification to the deployed hardware. We present preliminary measurements of transmission and reception range.
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| 7. |
- Andersson, Henrik, et al.
(författare)
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Investigation of Humidity Sensor Effect in Silver Nanoparticle Ink Sensors Printed on Paper
- 2014
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Ingår i: IEEE Sensors Journal. - 1530-437X .- 1558-1748. ; 14:3, s. Art. no. 6615915-
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Tidskriftsartikel (refereegranskat)abstract
- Thin inkjet-printed tracks of silver nanoparticles have previously been observed to show a non-reversible decrease in resistance when exposed to a high degree of relative humidity and thus providing sensor functionality with a memory effect. This paper provides a more in-depth explanation of the observed humidity sensor effect that originates from inkjet-printed silver nanoparticle sensors on a paper substrate. It is shown that the geometry of the sensor has a large effect on the sensor's initial resistance, and therefore also on the sensor's resistive dynamic range. The importance of the sensor geometry is believed to be due to the amount of solvent from the ink interacting with the coating of the paper substrate, which in turn enables the diffusion of salts from the paper coating into the ink and thus affecting the silver ink.
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| 8. |
- Barbier, Christophe, et al.
(författare)
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Folding of printed papers: experiments and numerical analysis
- 2003
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Konferensbidrag (populärvet., debatt m.m.)abstract
- Folding of digital prints has been investigated experimentally in order to determine the influence from different features on the residual strength of the folded paper. In particular, the effect of toner-layer, paper-fibre orientation and pre-creasing is investigated and the experimental results are supplemented with numerical ones based on the finite element method. The results indicate that creasing, and to a less extend also fibre orientation, is the most important factor influencing the residual tensile strength after folding
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| 9. |
- Eivazihollagh, Alireza, et al.
(författare)
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Controlled Synthesis of Cu and Cu2O NPs and Incorporation of Octahedral Cu2O NPs in Cellulose II Films
- 2018
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Ingår i: Nanomaterials. - : MDPI AG. - 2079-4991. ; 8:4
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Tidskriftsartikel (refereegranskat)abstract
- In this study, Cu and Cu2O nanoparticles (NPs) were synthesized through chemical reduction of soluble copper-chelating ligand complexes using formaldehyde as a reducing agent. The influence of various chelating ligands, such as ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), and a surface-active derivative of DTPA (C12-DTPA), as well as surfactants (i.e., hexadecyltrimethylammonium bromide (CTAB), dodecyltrimethylammonium chloride (DoTAC), sodium dodecyl sulfate (SDS), and dimethyldodecylamine-N-oxide (DDAO)), on morphology and the composition of produced NPs was investigated. In the absence of surfactants, spherical copper particles with polycrystalline structure could be obtained. X-ray diffraction (XRD) analysis revealed that, in the presence of EDTA, the synthesized NPs are mainly composed of Cu with a crystallite size on the order of 35 nm, while with DTPA and C12-DTPA, Cu2O is also present in the NPs as a minority phase. The addition of ionic surfactants to the copper–EDTA complex solution before reduction resulted in smaller spherical particles, mainly composed of Cu. However, when DDAO was added, pure Cu2O nano-octahedrons were formed, as verified by high-resolution scanning electron microscopy (HR-SEM) and XRD. Furthermore, a hybrid material could be successfully prepared by mixing the octahedral Cu2O NPs with cellulose dissolved in a LiOH/urea solvent system, followed by spin-coating on silica wafers. It is expected that this simple and scalable route to prepare hybrid materials could be applied to a variety of possible applications.
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| 10. |
- Sjöström, Mårten, et al.
(författare)
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Equivalent Circuit Model for Superconductors
- 2003
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Ingår i: IEEE transactions on applied superconductivity (Print). - 1051-8223 .- 1558-2515. ; 13:2, s. 1890-1893
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Tidskriftsartikel (refereegranskat)abstract
- We propose an equivalent circuit model that describes the behaviour of a superconductor viewed by an external user, for whom the global variables voltage and current are of interest. It is used in time-continuous simulations and it treats well both the subcritical and supercritical current regime. The model is based on Maxwell's equations, measurement results as well as on the physical structure of a superconducting tape. The incorporated circuit elements have been described in mathematical expressions: a nonlinear resistance and a nonlinear inductance (superconducting core) in parallel with a linear resistance and a linear inductance (silver sheath or by-pass material). The simplicity of the model makes it fast and easy to apply compared to existing numerical models of superconductors, based on finite element methods. Furthermore, it is wide-ranging and may represent a superconductor in many different applications depending on parameter values. Examples of applied voltage and current with non-stationary waveforms on a HTS tape are given. Calculated are the hysteresis losses (due to flux pinning) and resistive losses (due to flux creep and flux flow) in the tape in the range 0.1 to 1.8 Ic.
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