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1.
  • Stanicic, Ivana, 1994, et al. (creator_code:aut_t)
  • Fate of lead, copper, zinc and antimony during chemical looping gasification of automotive shredder residue
  • 2021
  • record:In_t: Fuel. - : Elsevier BV. - 0016-2361 .- 1873-7153. ; 302
  • swepub:Mat_article_t (swepub:level_refereed_t)abstract
    • Gasification experiments in this study were performed in a 2–4 MW indirect gasifier coupled to a semi-commercial CFB combustor at Chalmers University of Technology. Experiments were carried out during 13 days with automotive shredder residue (ASR), giving a unique opportunity to investigate the bed material under realistic conditions and with long residence times. The metal rich ash was accumulated in the bed, gaining some oxygen carrying capabilities, creating a chemical looping gasification (CLG) process. This study aims to expand the knowledge about the chemistry of zinc, copper, lead and antimony during CLG of ASR. Several experimental methods have been utilized, such as XRD, SEM-EDX and XPS along with detailed thermodynamic calculations to study chemical transformations that can occur in the system. Thermodynamic calculations showed that the reduction potential affect the phase distribution of these elements, where highly reduction conditions result in heavy metals dissolving in the slag phase. Copper and zinc ferrites, lead silicates and antimony oxides were identified at the particle surfaces in the bottom ash. The formation of an iron rich ash layer plays an important role, especially for copper and zinc speciation. The main pathways in the complex CLG system have been discussed in detail.
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2.
  • Shafiq, ur Réhman, 1978-, et al. (creator_code:aut_t)
  • Using Vibrotactile Language for Multimodal Human Animals Communication and Interaction
  • 2014
  • record:In_t: Proceedings of the 2014 Workshops on Advances in Computer Entertainment Conference, ACE '14. - New York, NY, USA : Association for Computing Machinery (ACM). - 9781450333146 ; , s. 1:1-1:5
  • swepub:Mat_conferencepaper_t (swepub:level_refereed_t)abstract
    • In this work we aim to facilitate computer mediated multimodal communication and interaction between human and animal based on vibrotactile stimuli. To study and influence the behavior of animals, usually researchers use 2D/3D visual stimuli. However we use vibrotactile pattern based language which provides the opportunity to communicate and interact with animals. We have performed experiment with a vibrotactile based human-animal multimodal communication system to study the effectiveness of vibratory stimuli applied to the animal skin along with audio and visual stimuli. The preliminary results are encouraging and indicate that low-resolution tactual displays are effective in transmitting information.
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3.
  • Khan, Muhammad Sikandar Lal, 1988- (creator_code:aut_t)
  • Presence through actions : theories, concepts, and implementations
  • 2017
  • swepub:Mat_doctoralthesis_t (swepub:level_scientificother_t)abstract
    • During face-to-face meetings, humans use multimodal information, including verbal information, visual information, body language, facial expressions, and other non-verbal gestures. In contrast, during computer-mediated-communication (CMC), humans rely either on mono-modal information such as text-only, voice-only, or video-only or on bi-modal information by using audiovisual modalities such as video teleconferencing. Psychologically, the difference between the two lies in the level of the subjective experience of presence, where people perceive a reduced feeling of presence in the case of CMC. Despite the current advancements in CMC, it is still far from face-to-face communication, especially in terms of the experience of presence.This thesis aims to introduce new concepts, theories, and technologies for presence design where the core is actions for creating presence. Thus, the contribution of the thesis can be divided into a technical contribution and a knowledge contribution. Technically, this thesis details novel technologies for improving presence experience during mediated communication (video teleconferencing). The proposed technologies include action robots (including a telepresence mechatronic robot (TEBoT) and a face robot), embodied control techniques (head orientation modeling and virtual reality headset based collaboration), and face reconstruction/retrieval algorithms. The introduced technologies enable action possibilities and embodied interactions that improve the presence experience between the distantly located participants. The novel setups were put into real experimental scenarios, and the well-known social, spatial, and gaze related problems were analyzed.The developed technologies and the results of the experiments led to the knowledge contribution of this thesis. In terms of knowledge contribution, this thesis presents a more general theoretical conceptual framework for mediated communication technologies. This conceptual framework can guide telepresence researchers toward the development of appropriate technologies for mediated communication applications. Furthermore, this thesis also presents a novel strong concept – presence through actions - that brings in philosophical understandings for developing presence- related technologies. The strong concept - presence through actions is an intermediate-level knowledge that proposes a new way of creating and developing future 'presence artifacts'. Presence- through actions is an action-oriented phenomenological approach to presence that differs from traditional immersive presence approaches that are based (implicitly) on rationalist, internalist views.
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4.
  • Lundin, Mikael, et al. (creator_code:aut_t)
  • Development and validation of a method aimed at estimating building performance parameters
  • 2004
  • record:In_t: Energy and Buildings. - Lausanne : Elsevier. - 0378-7788 .- 1872-6178. ; 36:9, s. 905-914
  • swepub:Mat_article_t (swepub:level_refereed_t)abstract
    • This paper presents a method for estimating the total heat loss coefficient, the total heat capacity and the gain factor based on measured data for the internal-external temperature difference, the domestic load and the supplied heat. Knowledge of these performance parameters is essential for a reliable energy demand forecast, close guidance and the accurate analysis of efficiency actions in buildings. The method was validated on measurements from a test cell. The values obtained for the performance parameters were in good agreement with a lumped capacitance analysis of the heating and cooling of the test cell. The deviation in the total heat loss coefficient, expressed in terms of the root mean square error, was between 2.5 and 9.4%. The values obtained for the total heat capacity were on average 9.8% higher than the reference value and for the gain factor the average deviation was 12.5%. The method shows promising signs of becoming a robust and accurate tool for extracting both the magnitude and the variation of the performance parameters, based on easily accessible data.
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5.
  • Sandström, Robin, et al. (creator_code:aut_t)
  • Evaluation of Fluorine and Sulfonic Acid Co-functionalized Graphene Oxide Membranes in Hydrogen Proton Exchange Membrane Fuel Cell Conditions
  • 2019
  • record:In_t: Sustainable Energy & Fuels. - : Royal Society of Medicine Press. - 2398-4902. ; 3:7, s. 1790-1798
  • swepub:Mat_article_t (swepub:level_refereed_t)abstract
    • The use of graphene oxide (GO) based membranes consisting of self-assembled flakes with a lamellar structure represents an intriguing strategy to spatially separate reactants while facilitating proton transport in proton exchange membranes (PEM). Here we chemically modify GO to evaluate the role of fluorine and sulfonic acid groups on the performance of H2/O2 based PEM fuel cells. Mild fluorination is achieved by the presence of hydrogen fluoride during oxidation and subsequent sulfonation resulted in fluorine and SO3- co-functionalized GO. Membrane electrode assembly performance in low temperature and moderate humidity conditions suggested that both functional groups contribute to reduced H2 crossover compared to appropriate reference membranes. Moreover, fluorine groups promoted an enhanced hydrolytic stability while contributing to prevent structural degradation after constant potential experiments whereas sulfonic acid demonstrated a stabilizing effect by preserving proton conductivity.
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6.
  • Sandström, Robin, 1988- (creator_code:aut_t)
  • Innovations in nanomaterials for proton exchange membrane fuel cells
  • 2019
  • swepub:Mat_doctoralthesis_t (swepub:level_scientificother_t)abstract
    • Hydrogen technologies are rapidly receiving increased attention as it offers a renewable energy alternative to the current petroleum-based fuel infrastructure, considering that continued large-scale use of such fossil fuels will lead to disastrous impacts on our environment. The proton exchange membrane fuel cell should play a significant role in a hydrogen economy since it enables convenient and direct conversion of hydrogen into electricity, thus allowing the use of hydrogen in applications particularly suited for the transportation industry. To fully realize this, multiple engineering challenges as well as development of advanced nanomaterials must however be addressed.In this thesis, we present discoveries of new innovative nanomaterials for proton exchange membrane fuel cells by targeting the entire membrane electrode assembly. Conceptually, we first propose new fabrication techniques of gas diffusion electrodes based on helical carbon nanofibers, where an enhanced three-phase boundary was noted in particular for hierarchical structures. The cathode catalyst, responsible for facilitating the sluggish oxygen reduction reaction, was further improved by the synthesis of platinum-based nanoparticles with an incorporated secondary metal (iron, yttrium and cobalt). Here, both solvothermal and high-temperature microwave syntheses were employed. Catalytic activities were improved compared to pure platinum and could be attributed to favorably shifted oxygen adsorption energies as a result of successful incorporation of the non-precious metal. As best exemplified by platinum-iron nanoparticles, the oxygen reduction reaction was highly sensitive to both metal composition and the type of crystal structure. Finally, a proton exchange membrane based on fluorine and sulfonic acid functionalized graphene oxide was prepared and tested in hydrogen fuel cell conditions, showing improvements such as lowered hydrogen permeation and better structural stability. Consequently, we have demonstrated that there is room for improvement of multiple components, suggesting that more powerful fuel cells can likely be anticipated in the future.
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7.
  • Augustian, Midhumol, et al. (creator_code:aut_t)
  • EEG Analysis from Motor Imagery to Control a Forestry Crane
  • 2018
  • record:In_t: Intelligent Human Systems Integration (IHSI 2018). - Cham : Springer. - 9783319738871 - 9783319738888 ; , s. 281-286
  • swepub:Mat_conferencepaper_t (swepub:level_refereed_t)abstract
    • Brain-computer interface (BCI) systems can provide people with ability to communicate and control real world systems using neural activities. Therefore, it makes sense to develop an assistive framework for command and control of a future robotic system which can assist the human robot collaboration. In this paper, we have employed electroencephalographic (EEG) signals recorded by electrodes placed over the scalp. The human-hand movement based motor imagery mentalization is used to collect brain signals over the motor cortex area. The collected µ-wave (8–13 Hz) EEG signals were analyzed with event-related desynchronization/synchronization (ERD/ERS) quantification to extract a threshold between hand grip and release movement and this information can be used to control forestry crane grasping and release functionality. The experiment was performed with four healthy persons to demonstrate the proof-of concept BCI system. From this study, it is demonstrated that the proposed method has potential to assist the manual operation of crane operators performing advanced task with heavy cognitive work load.
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8.
  • Chen, Yuqing, et al. (creator_code:aut_t)
  • A review of lithium-ion battery safety concerns : the issues, strategies, and testing standards
  • 2021
  • record:In_t: Journal of Energy Chemistry. - : Elsevier. - 2095-4956 .- 2096-885X. ; 59, s. 83-99
  • swepub:Mat_article_t (swepub:level_refereed_t)abstract
    • Efficient and reliable energy storage systems are crucial for our modern society. Lithium-ion batteries (LIBs) with excellent performance are widely used in portable electronics and electric vehicles (EVs), but frequent fires and explosions limit their further and more widespread applications. This review summarizes aspects of LIB safety and discusses the related issues, strategies, and testing standards. Specifically, it begins with a brief introduction to LIB working principles and cell structures, and then provides an overview of the notorious thermal runaway, with an emphasis on the effects of mechanical, electrical, and thermal abuse. The following sections examine strategies for improving cell safety, including approaches through cell chemistry, cooling, and balancing, afterwards describing current safety standards and corresponding tests. The review concludes with insights into potential future developments and the prospects for safer LIBs.
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9.
  • Hagman, Henrik, 1980- (creator_code:aut_t)
  • Co-firing complex biomass in a CFB boiler : ash transformation, corrosion control and materials selection
  • 2018
  • swepub:Mat_doctoralthesis_t (swepub:level_scientificother_t)abstract
    • The effects of greenhouse gas net emissions on global warming, stricter legislation on waste handling, and the pursuit of ever cheaper heat- and power production are all important factors driving the introduction of complex fuels in incineration plants. However - without fundamental knowledge regarding ash transformation, corrosion control, and materials selection – this introduction of potentially economically and environmentally beneficial fuels, might instead cause economic loss and environmentally adverse effects.The present work is a contribution to the transition from today's CO2 net generating energy conversion system, to a more environmentally friendly and cost-efficient one. This is done using scientific methods to generate knowledge concerning mechanisms of ash transformation, corrosion control, and materials selection, in a co-fired industrial scale circulating fluidized bed (CFB) boiler, using a novel and biomass-based fuel mix, rich in Na, K, Cl, N, S, P, Ca and Si. Fuel fractions, ashes, flue gas, deposits, and construction material samples have been collected and analyzed using various techniques, including scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and X-ray Diffraction (XRD). The experimental results have been evaluated and interpreted using chemical equilibrium calculations.The results of this work include:1) An analysis of; the failure and preventive maintenance statistics of the industrial scale CFB boiler at hand; the elemental composition of boiler ashes and deposits, the flue gas composition and elemental composition of a multitude of fuel fractions; correlations between boiler design, operational parameters, elemental composition of deposits and boiler availability; a boiler elemental mass balance revealing details regarding deposit buildup mechanisms; properties of the fly ash relevant to flue gas filter design; and findings regarding the nitrogen chemistry of the novel and nitrogen-rich fuel mix.2) Speciation and description of the overall ash transformation and fireside alloy interaction, enabling the implementation of on-line corrosion control which significantly inhibits superheater and dew-point corrosion in the boiler; and, an equation describing the sulfation potential of the fuel mix, as a result of the direct and indirect interactions between all major ash-forming elements.3) A literature review relevant for the co-fired CFB cyclone vortex finder alloy selection and corrosion at 880 °C; An alloy selection study including long term exposures of several commercially available alloys identifying materials that are more than twice as cost-efficient as the often used alloy 253MA; a suggestion of novel methods for both systematic comparison of heavily degraded alloys, and for alloy service-life estimations; a detailed analysis of heavily degraded alloys 310S, 800H/HT and 600, identifying the driving corrosion mechanisms of the VF alloy degradation, including aspects of how the alloy internal mass transport and fireside surface interaction develops over time.The knowledge gained during this project has been used in the improvement work of the Perstorp 50 MWth CFB boiler, improving the boiler availability with 7 %, reducing the overall energy conversion costs with around 1.7 MEUR/year.
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10.
  • Jogi, Ramakrishna, et al. (creator_code:aut_t)
  • Understanding the formation of phenolic monomers during fractionation of birch wood under supercritical ethanol over iron based catalysts
  • 2020
  • record:In_t: Journal of the Energy Institute. - : Elsevier. - 1743-9671 .- 1746-0220. ; 93:5, s. 2055-2062
  • swepub:Mat_article_t (swepub:level_refereed_t)abstract
    • The liquefaction of biomass in ethanol, at the critical point, has high potential due to low temperature and pressure (243 °C, 63 bar) when compared with water (374 °C, 220 bar). The current study deals with the fractionation of birch wood powder which was liquefied under supercritical ethanol over acidic or non-acidic catalysts, 5 wt % Fe-Beta-H-150 and 5 wt % Fe–SiO2, respectively. Based on the results, the reaction mechanism for the formation of lignin degradation products was proposed. The main phenolic product was isoeugenol over 5 wt % Fe-Beta-H-150 while intermediate products, i.e. such as coniferyl, and sinapyl alcohol, 4-propenyl syringol, syringaresinol, as well as syringyldehyde reacted rapidly further. The thermodynamic analysis was performed by Joback approach and using Gibbs-Helmholtz equation supporting the obtained results.
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