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- Johansson, O., et al.
(author)
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Intramolecular charge separation in a hydrogen bonded tyrosine-ruthenium(II)-naphthalene diimide triad
- 2004
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In: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1359-7345 .- 1364-548X. ; :2, s. 194-195, s. 194-195
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Journal article (peer-reviewed)abstract
- Long-lived charge-separated states in the ns to mus range were observed upon laser flash excitation of a donor-chromophore-acceptor triad based on tris(bipyridine) ruthenium(II) as photosensitizer, naphthalene diimide as acceptor; and a hydrogen bonded phenol as donor.
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4. |
- Wolpher, H., et al.
(author)
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Synthesis of a Ru(bpy)(3)-type complex linked to a free terpyridine ligand and its use for preparation of polynuclear bimetallic complexes
- 2004
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In: Catalysis Today. - : Elsevier BV. - 0920-5861 .- 1873-4308. ; 98:4, s. 529-536:98, s. 529-536
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Journal article (peer-reviewed)abstract
- A terpyridine ligand has been covalently linked to a Ru(bpy)(3) complex via an amide bond. By using this functionalized terpyridine ligand, a series of multinuclear bimetallic complexes have been synthesized and characterized. One of these complexes has the structure of di-mu-oxobridged Mn dimer. EPR spectra of this complex showed that, depending on the procedure for the preparation, the oxidation states of the Mn dimer is either a Mn-2(III,IV) dimer or a mixture of this and Mn-2(IV,IV) dimer. Water oxidation catalyzed by this complex has been performed.
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