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- Samec, Joseph S. M., et al.
(författare)
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Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions.
- 2006
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Ingår i: Chemical Society Reviews. - : Royal Society of Chemistry (RSC). - 0306-0012 .- 1460-4744. ; 35:3, s. 237-248
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Tidskriftsartikel (refereegranskat)abstract
- A review. In this tutorial review recent mechanistic studies on transition metal-catalyzed hydrogen transfer reactions are discussed. A common feature of these reactions is that they involve metal hydrides, which may be monohydrides or dihydrides. An important question is whether the substrate coordinates to the metal (inner-sphere hydrogen transfer) or if there is a direct concerted transfer of hydrogen from the metal to substrate (outer-sphere hydrogen transfer). Both exptl. and theor. studies are reviewed. [on SciFinder(R)]
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