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- Shi, F., et al.
(författare)
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Synthesis and properties of a new donor model compound for PSII
- 2004
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Ingår i: Gaodeng xuéxiào huàxué xuébào. - 0251-0790. ; 25:9, s. 1666-1672
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Tidskriftsartikel (refereegranskat)abstract
- As a model compound for redox components on the donor side of photosystem II (PS II) in green plants, a supramolecular complex 2 was synthesized and characterized. In this complex, two {[(2-hydroxy-3-(morpholin-4-ylmethyl)-5-tert-butyl-benzyl)(pyridyl-2-methyl)amino]methyl} arms are linked to the ortho-positions of a phenol which is expected covalently to be linked to Ru(II) tris-bipyridine through an amide bond. The arms on the substituted-phenol can coordinate two Mn(III) ions. The structure of complex 2 was confirmed by electrospray ionization mass spectrometry (ESI-MS) and 2D-NMR (gCOSY, HSQC and HMBC). Its photochemical and electrochemical properties were studied. The results showed that the MLCT band of the compound was red-shifted compared to that of [Ru(byp)(3)](2+) and the luminescence quantum yield was enhanced. In addition, the oxidation potential of ruthenium was higher than the phenol(+)/phenol and Mn(III, IV)/Mn(III) which was consisted with the electron transfer sequence of the donor side of PS II in nature. All these showed that this compound was a good model to mimic the donor side of PS II.
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- Zhang, H., et al.
(författare)
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Inverse problems for three-dimensional localization of an inhomogeneity in a stratified scattering medium by using a weighted Fourier transform
- 2001
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Ingår i: Wuli xuebao. - : Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences. - 1000-3290. ; 50:8, s. 1481-1485
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Tidskriftsartikel (refereegranskat)abstract
- Characterization of the structure of spatial inhomogeneities embedded in a highly scattering medium is required in many fields. In this paper, a model of a stratified medium embedded with an inhomogeneous ball is considered. With an assumption that the ball is small enough, a perturbation solution to diffusion equation is obtained with some boundary treatments. According to the characteristics of this solution in the two-dimensional Fourier space, a new weighted Fourier transform is used to process the surface data. After this process, a singularity appears at the center of the ball. Combining with the symmetry of the surface data, the information of three-dimensional position of the ball is determined.
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