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Sökning: WFRF:(Choi I. J.) > Linnéuniversitetet

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1.
  • Hwang, JH, et al. (författare)
  • Effect of pH and sulfate concentration on hydrogen production using anaerobic mixed microflora
  • 2009
  • Ingår i: International journal of hydrogen energy. - : Elsevier BV. - 0360-3199 .- 1879-3487. ; 34:24, s. 9702-9710
  • Tidskriftsartikel (refereegranskat)abstract
    • The effects of varying sulfate concentrations with pH on continuous fermentative hydrogen production were studied using anaerobic mixed cultures growing on a glucose substrate in a chemostat reactor. The maximum hydrogen production rate was 2.8 L/day at pH 5.5 and sulfate concentration of 3000 mg/L. Hydrogen production and residual sulfate level decreased with increasing the pH from 5.5 to 6.2. The volatile fatty acids (VFAs) and ethanol fractions in the effluent were in the order of butyric acid (HBu) > acetic acid (HAc) > ethanol > propionic acid (HPr). Fluorescence In Situ Hybridization (FISH) analysis revealed the presence of hydrogen producing bacteria (HPB) under all pH ranges while sulfate reducing bacteria (SRB) were present at pH 5.8 and 6.2. The inhibition in hydrogen production by SRB at pH 6.2 diminished entirely by lowering to pH 5.5, at which activity of SRB is substantially suppressed.
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2.
  • Hwang, J.W., et al. (författare)
  • Effect of COD/SO42- ratio and Fe(II) under the variable hydraulic retention time (HRT) on fermentative hydrogen production
  • 2009
  • Ingår i: Water Research. - : Elsevier BV. - 0043-1354 .- 1879-2448. ; 43, s. 3525-3533
  • Tidskriftsartikel (refereegranskat)abstract
    • The effect of chemical oxygen demand/sulfate (COD/SO42−) ratio on fermentative hydrogen production using enriched mixed microflora has been studied. The chemostat system maintained with a substrate (glucose) concentration of 15 g COD L−1 exhibited stable H2 production at inlet sulfate concentrations of 0–20 g L−1 during 282 days. The tested COD/SO42− ratios ranged from 150 to 0.75 (with control) at pH 5.5 with hydraulic retention time (HRT) of 24, 12 and 6 h. The hydrogen production at HRT 6 h and pH 5.5 was not influenced by decreasing the COD/SO42− ratio from 150 to 15 (with control) followed by noticeable increase at COD/SO42− ratios of 5 and 3, but it was slightly decreased when the COD/SO42− ratio further decreased to 1.5 and 0.75. These results indicate that high sulfate concentrations (up to 20,000 mg L−1) would not interfere with hydrogen production under the investigated experimental conditions. Maximum hydrogen production was 2.95, 4.60 and 9.40 L day−1 with hydrogen yields of 2.0, 1.8 and 1.6 mol H2 mol−1 glucose at HRTs of 24, 12 and 6 h, respectively. The volatile fatty acid (VFA) fraction produced during the reaction was in the order of butyrate > acetate > ethanol > propionate in all experiments. Fluorescence In Situ Hybridization (FISH) analysis indicated the presence of Clostridium spp., Clostridium butyricum, Clostridium perfringens andRuminococcus flavefaciens as hydrogen producing bacteria (HPB) and absence of sulfate reducing bacteria (SRB) in our study.
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refereegranskat (2)
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Choi, J. (2)
Bhatnagar, Amit (2)
Jeon, B.H. (2)
Abou-Shanab, R.A.I. (2)
Kim, Y. J. (1)
Song, H. (1)
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Kim, D. J. (1)
Kumar, E (1)
Min, B. (1)
Choi, JA (1)
Chung, H.K. (1)
Lee, D. S. (1)
Hwang, J. W. (1)
Hwang, JH (1)
Lee, E.S. (1)
Um, S. (1)
Cha, G.C. (1)
Jeong, T.Y. (1)
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