| 1. |
- Dahl, Leif, et al.
(författare)
-
Catalytic behavior and characterization of (CuO)1-z(La2O3)z/2 based catalysts deposited on γ-Al2O3 and prepared in situ with 0.0≤z≤1.00 with and without addition of Pd
- 1996
-
Ingår i: Catalysis Letters. - 1572-879X .- 1011-372X. ; 37:1-2, s. 69-77
-
Tidskriftsartikel (refereegranskat)abstract
- (CuO)(1-z)(La2O3)(z/2) based catalysts with 0.0 less than or equal to z less than or equal to 1.0 supported on gamma-Al2O3 have been prepared in situ and the phases formed have been identified by XRD, SEM and TEM/EDS studies. The catalyst with z = 0.5 exhibited the best catalytic activity for oxidation of CO (T-50 = 295 and 390 degrees C with degrees of conversions of 93 and 92% at 450 degrees C under rich and lean conditions, respectively) and C3H6 (291 and 414 degrees C; 93 and 83%) and reduction of NO (405 degrees C; 60 and 0%). This catalyst contained appreciable amounts of the perovskite phase LaAl1-xCuxO3 and the enhanced catalytic properties are ascribed to the presence of this phase. Addition of Pd to this catalyst implied that the degree of conversion of NO increased and that the light-off temperatures for all involved gas species decreased. Ageing experiments revealed that LaAl1-xCuxO3 decomposed and that Cu containing Pd particles were formed during this procedure which in turn deteriorated the catalytic properties of the catalyst.
|
|
| 2. |
- Lin, Pei-yan, et al.
(författare)
-
Catalytic purification of car exhausts over cobalt- and copper-based metal oxides promoted with platinum and rhodium
- 1995
-
Ingår i: Applied Catalysis B: Environmental. - : Elsevier BV. - 0926-3373 .- 1873-3883. ; 6:3, s. 237-319
-
Tidskriftsartikel (refereegranskat)abstract
- 25 Alumina-and silica-supported oxide-based catalysts were prepared, with the overall metal composition La(0.45)Sr(0.15)Ce(0.35)Zr(0.05)M(1.0) (M=Co or Cu) and promoted with 0-0.5 mg Pt-Rh per gram catalyst. The catalysts were evaluated with respect to light-off temperatures and redox characteristics, using NO/CO/C3H6/O2/N2 gas mixtures to simulate car exhaust. The activities for complete oxidation of propene and carbon monoxide increased with increasing content of metal oxides and noble metals. The catalysts were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) combined with energy-dispersive spectroscopy (EDS) analysis, temperature-programmed reduction (TPR), and specific surface area measurements (BET). SEM/TEM/XRD revealed that the alumina-supported catalysts contained well dispersed oxides of the added elements, whereas the silica-supported catalysts contained significantly larger particles of the copper or cobalt oxides, The TPR peak for reduction of cobalt oxide shifted toward lower temperatures with increasing content of Pt-Rh, indicating hydrogen spill-over from the noble metals to the cobalt oxide. The catalytic activity of the Co-based oxides supported on alumina and promoted with 0.49 mg Pt-Rh per gram catalysts was comparable to the activity of a commercial three-way catalyst (TWC), containing more than 4 times as much Pt-Rh.
|
|
| 3. |
- Skoglundh, Magnus, 1965, et al.
(författare)
-
Characterization and catalytic properties of perovskites with nominal compositions La1-xSrxAl1-2yCuyRuyO3
- 1994
-
Ingår i: Applied Catalysis B: Environmental. ; 3:4, s. 259-274
-
Tidskriftsartikel (refereegranskat)abstract
- Nine different metal oxide catalysts were prepared by impregnating alumina washcoats with water solutions containing La3+, Sr2+, Cu2+ and Ru3+ ions and calcining them at 900-degrees-C. The produced samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) studies combined with energy-dispersive spectroscopy (EDS) analysis, X-ray powder diffraction and specific surface area measurements. A perovskite phase of the nominal composition La1-xSrxAl1-2yCuRuyO3 was found in all samples, in increasing amount in the samples with increasing contents of strontium and ruthenium. The catalysts were evaluated with respect to light-off temperatures and redox characteristics using two gas mixtures, one containing NO/CO/C3H6/O2/N2 and the other NO/CO/N2. The light-off temperatures for nitric oxide reduction decreased from 534 to 333-degrees-C for the catalysts without and with strontium and ruthenium, respectively. In the presence of oxygen the conversion of nitric oxide declined rapidly under oxidative conditions whereas in absence of oxygen this decline was less pronounced and found to be linear over the entire redox interval studied. These studies suggest that the perovskite phase takes an active part in the conversion of nitric oxide and carbon monoxide to nitrogen and carbon dioxide.
|
|
