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- Ukleev, V., et al.
(författare)
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Self-assembly of a binary mixture of iron oxide nanoparticles in Langmuir film : X-ray scattering study
- 2017
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Ingår i: Materials Chemistry and Physics. - : Elsevier BV. - 0254-0584 .- 1879-3312. ; 202, s. 31-39
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Tidskriftsartikel (refereegranskat)abstract
- In present study we exploited Langmuir technique to produce self-assembled arrays composed of monodisperse iron oxide nanoparticles 10 nm and 20 nm in diameter and of their binary mixture. A combination of in-situ X-ray reflectometry and Grazing-incident small-Angle X-ray scattering was used to obtain in-plane and out-of-plane structure of the arrays directly on the water surface. Surface pressure isotherms and X-ray reflectometry analysis showed that monodisperse 10 nm nanoparticles form a highly ordered monolayer, while 20 nm particles pack in three-dimensional clusters with a short-range (nearest-neighbor) correlations between the particles. In a binary mixture of 10 nm and 20 nm nano particles composed in proportion 3:1 the self-assembly process results in a structure where the monolayer of 10 nm particles is perturbed by the larger particles. Non-trivial mixing causes an enlargement of interparticle distance but keeps the symmetry of two-dimensional lattice of smaller nanoparticles. Estimation of the acting interactions and micromagnetic simulation suggest the optimal formation for monodisperse and binary ensembles.
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