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Träfflista för sökning "WFRF:(Edström Kristina Professor 1958 ) ;pers:(Pettersson Jean)"

Sökning: WFRF:(Edström Kristina Professor 1958 ) > Pettersson Jean

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1.
  • Lindgren, Fredrik, et al. (författare)
  • On the Capacity Losses Seen for Optimized Nano-Si Composite Electrodes in Li-Metal Half-Cells
  • 2019
  • Ingår i: Advanced Energy Materials. - : Wiley. - 1614-6832 .- 1614-6840. ; 9:33
  • Tidskriftsartikel (refereegranskat)abstract
    • While the use of silicon‐based electrodes can increase the capacity of Li‐ion batteries considerably, their application is associated with significant capacity losses. In this work, the influences of solid electrolyte interphase (SEI) formation, volume expansion, and lithium trapping are evaluated for two different electrochemical cycling schemes using lithium‐metal half‐cells containing silicon nanoparticle–based composite electrodes. Lithium trapping, caused by incomplete delithiation, is demonstrated to be the main reason for the capacity loss while SEI formation and dissolution affect the accumulated capacity loss due to a decreased coulombic efficiency. The capacity losses can be explained by the increasing lithium concentration in the electrode causing a decreasing lithiation potential and the lithiation cut‐off limit being reached faster. A lithium‐to‐silicon atomic ratio of 3.28 is found for a silicon electrode after 650 cycles using 1200 mAhg−1 capacity limited cycling. The results further show that the lithiation step is the capacity‐limiting step and that the capacity losses can be minimized by increasing the efficiency of the delithiation step via the inclusion of constant voltage delithiation steps. Lithium trapping due to incomplete delithiation consequently constitutes a very important capacity loss phenomenon for silicon composite electrodes.
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2.
  • Rehnlund, David, 1986-, et al. (författare)
  • Lithium Trapping in Alloy forming Electrodes and Current Collectors for Lithium based Batteries
  • 2018
  • Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
    • The next generation of lithium based batteries can be expected to be based on lithium alloy forming anode materials which can store up to ten times more charge than the currently used graphite anodes. This increase in the charge storage capability has motivated significant research towards the commercialization of anode materials such as Si, Sn and Al. These alloy forming anode materials are, however, known to exhibit significant capacity losses during cycling. This is typically ascribed to the volume expansion associated with the formation of the lithium alloys (the volume expansion is e.g. about 280 % for Li3.75Si) resulting in electrode pulverization as well as continuous solid electrolyte interphase (SEI) layer formation [1-3]. While significant progress has been made to decrease the volume expansion problems by the use of e.g. nanoparticles, nanorods and thin films, and/or capacity limitations [1-3], capacity losses are still generally seen [4,5]. This and previously published data suggest that the phenomenon may be due to another effect and that this in fact could stem from lithium trapping in the electrodes [6-8].In the present work it is demonstrated (based on e.g. elemental analyses of cycled Sn, Al and Si electrodes) that lithium trapping can account for the capacity losses seen when alloy forming anode materials are cycled versus lithium electrodes, see Figure 1. It is shown that small amounts of elemental lithium are trapped within the electrode material during the cycling as a result of a two-way diffusion process [8] causing the lithium to move into the bulk material even during the delithiation step. This phenomenon, which can be explained by the lithium concentration profiles in the electrodes, makes a complete delithiation process very time consuming. As a result of the lithium trapping effect, the lithium concentration in the electrode increases continuously during the cycling. The experimental results also show that a similar effect can be seen also for commonly used current collector metals such as Cu, Ni and Ti. The latter means that these metals are unsuitable as current collector materials for lithium alloy forming materials in the absence of a thin layer of boron doped diamond serving as a lithium diffusion barrier layer [8].References1    M. N. Obrovac and V. L. Chevrier, Chem. Rev., 2014, 114, 11444.2    X. Su, Q. Wu, J. Li, X. Xiao, A. Lott, W. Lu, B. W. Sheldon and J. Wu, Adv. Energy Mater., 2014, 4, 1300882.3    J. R. Szczech and S. Jin, Energy Environ. Sci., 2011, 4, 56.4    G. Zheng, S. W. Lee, Z. Liang, H-W. Lee, K. Yan, H. Yao, H. Wang, W. Li, S. Chu and Y. Cui, Nat. Nanotechnol., 2014, 9, 618.5    K. Yan, H-W. Lee, T. Gao, G. Zheng, H. Yao, H. Wang, Z. Lu, Y. Zhou, Z. Liang, Z. Liu, S. Chu and Y. Cui, Nano Letters, 2014, 14, 6016.6    G. Oltean, C-W. Tai, K. Edström and L. Nyholm, J. Power Sources, 2014, 269, 266.7    A. L. Michan, G. Divitini, A. J. Pell, M. Leskes, C. Ducati and C. P. Grey, J. Am. Chem. Soc., 2016, 138, 7918.8    D. Rehnlund, F. Lindgren, S. Böhme, T. Nordh, Y. Zou, J. Pettersson, U. Bexell, M. Boman, K. Edström and L. Nyholm, Energy Environ. Sci., 10 (2017) 1350. 
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3.
  • Rehnlund, David, 1986-, et al. (författare)
  • Lithium trapping in microbatteries based on lithium- and Cu2O-coated copper nanorods
  • 2018
  • Ingår i: ChemistrySelect. - : Wiley. - 2365-6549. ; 3:8, s. 2311-2314
  • Tidskriftsartikel (refereegranskat)abstract
    • Microbatteries based on three-dimensional (3D) electrodes composed of thin films of Li and Cu2O coated on Cu nanorod current collectors by electrodeposition and spontaneous oxidation, respectively, are described and characterised electrochemically. High-resolution scanning electron microscopy (HR-SEM) data indicate that the Li electrodeposition resulted in a homogenous coverage of the Cu nanorods and elemental analyses were also used to determine the amount of lithium in the Li-coated electrodes. The results show that 3D Cu2O/Cu electrodes can be cycled versus 3D Li/Cu electrodes but that the capacity decreased during the cycling due to Li trapping in the Cu current collector of the 3D Li/Cu electrode. These findings highlight the problem of using copper current collectors together with metallic lithium as the formation of a solid solution yields considerable losses of electroactive lithium and hence capacity.
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  • Resultat 1-3 av 3

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