| 1. |
- Johansson, Erik M.J., et al.
(författare)
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Electronic and molecular surface structure of a polyene-diphenylaniline dye adsorbed from solution onto nanoporous TiO2
- 2007
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Ingår i: The Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 111:24, s. 8580-8586
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Tidskriftsartikel (refereegranskat)abstract
- The surface electronic and molecular structure of a new organic chromophore useful for dye-sensitized nanostructured solar cells has been investigated by means of electron spectroscopy. Initially the use of a simple molecular system containing the polyene-diphenylaniline chromophore in a solar cell device was verified. The electronic and molecular surface structure of the functional dye-sensitized interface was then investigated in detail by a combination of core level spectroscopy, valence level spectroscopy, X-ray absorption spectroscopy, and resonant photoemission spectroscopy. The results indicate a dominating orientation of the molecule at the surface, having the diphenylaniline moiety pointing out from the surface. Valence level spectroscopy, X-ray absorption spectroscopy, and resonant photoemission spectroscopy were used to experimentally delineate the frontier electronic structure of the molecule, and the experimental spectra were analyzed against theoretical spectra, based on density functional theory. Together the investigation gives insight into energy matching of the molecular electronic states with respect to the TiO2 substrate as well as the localization of the frontier electronic states and the direction of the charge-transfer absorption process with regards to the TiO2 surface.
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| 2. |
- Marinado, Tannia, et al.
(författare)
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Surface Molecular Quantification and Photoelectrochemical Characterization of Mixed Organic Dye and Coadsorbent Layers on TiO2 for Dye-Sensitized Solar Cells
- 2010
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Ingår i: The Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 114:27, s. 11903-11910
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Tidskriftsartikel (refereegranskat)abstract
- Different molecular layers on TiO2 were prepared by using the p-dimethylaniline triphenylamine based organic dye, D29, together with the coadsorbents decylphosphonic acid (DPA), dineohexyl bis(3,3-dimethylbutyl)phosphinic acid (DINHOP), and chenodeoxycholic acid (CDCA). The surface molecular structure of dye and coadsorbent layers on TiO2 was investigated by photoelectron spectroscopy (PES). A focus was to determine the surface molecular concentrations using characteristic photoelectron core levels. Dye-sensitized solar cells (DSCs) were prepared from the same substrate and were further characterized by photoelectrochemical methods. Together the investigation gives information on the arrangement of the mixed molecular layer and a first insight to the extent to which the coadsorbents exchange with dye molecules on the TiO2 surface for the examined conditions.
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