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- Karlsson Potter, Hanna, et al.
(författare)
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Greenhouse gas performance of biochemical biodiesel production from straw : Soil organic carbon changes and time-dependent climate impact
- 2017
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Ingår i: Biotechnology for Biofuels. - : Springer Science and Business Media LLC. - 1754-6834. ; 10:1
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Tidskriftsartikel (refereegranskat)abstract
- Background: Use of bio-based diesel is increasing in Europe. It is currently produced from oilseed crops, but can also be generated from lignocellulosic biomass such as straw. However, removing straw affects soil organic carbon (SOC), with potential consequences for the climate impact of the biofuel. This study assessed the climate impacts and energy balance of biodiesel production from straw using oleaginous yeast, with subsequent biogas production from the residues, with particular emphasis on SOC changes over time. It also explored the impact of four different scenarios for returning the lignin fraction of the biomass to soil to mitigate SOC changes. Climate impact was assessed using two methods, global warming potential (GWP) and a time-dependent temperature model (ΔT s ) that describes changes in mean global surface temperature as a function of time or absolute temperature change potential (AGTP). Results: Straw-derived biodiesel reduced GWP by 33-80% compared with fossil fuels and primary fossil energy use for biodiesel production was 0.33-0.80 MJprim/MJ, depending on the scenario studied. Simulations using the time-dependent temperature model showed that a scenario where all straw fractions were converted to energy carriers and no lignin was returned to soil resulted in the highest avoided climate impact. The SOC changes due to straw removal had a large impact on the results, both when using GWP and the time-dependent temperature model. Conclusions: In a climate perspective, it is preferable to combust straw lignin to produce electricity rather than returning it to the soil if the excess electricity replaces natural gas electricity, according to results from both GWP and time-dependent temperature modelling. Using different methods to assess climate impact did not change the ranking between the scenarios, but the time-dependent temperature model provided information about system behaviour over time that can be important for evaluation of biofuel systems, particularly in relation to climate target deadlines.
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| 2. |
- Bergendorff, Ola, et al.
(författare)
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Spontaneous Formation of Thiuram Disulfides in Solutions of Iron(III) Dithiocarbamates.
- 2002
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Ingår i: Journal of Agricultural and Food Chemistry. - : American Chemical Society (ACS). - 0021-8561 .- 1520-5118. ; 50:5, s. 1092-1096
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Tidskriftsartikel (refereegranskat)abstract
- Dithiocarbamates are used as pesticides and rubber additives. Dithiocarbamates are the reduced forms of thiuram disulfides and both of these groups of substances induce allergic contact dermatitis. The allergic cross-reactivity pattern between dithiocarbamates and thiurams is unclear. The aim of this study was to investigate why these cross-reactions occur sometimes but not always. HPLC-analysis of buffer solutions of iron(III) dithiocarbamates demonstrated that thiuram disulfides were formed spontaneously and rapidly in high yield. No such oxidation was observed in solutions of copper(II), zinc(II), or sodium dithiocarbamates. However, sodium diethyldithiocarbamate and zinc diethyldithiocarbamate were oxidized in buffer solution when ferric salt was added. The influence of different metal ions on the oxidation reaction is probably an explanation for the cross-reactivity patterns seen between dithiocarbamates and thiurams. These findings also show that careful handling is necessary in analytical and biological studies with solutions of iron(III) dithiocarbamates. Oxidation of dithiocarbamates in aqueous buffer at physiological pH has not been shown before.
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| 5. |
- Smith, Henrik G., et al.
(författare)
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Beyond dispersal : the roles of animal movement in modern agricultural landscapes
- 2014
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Ingår i: Animal Movement Across Scales. - : Oxford University Press. - 9780199677184 ; , s. 51-70
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Bokkapitel (refereegranskat)abstract
- In this chapter three major concepts relating animal population dynamics to landscape change mediated by animal mobility are outlined: meta-population/community dynamics (affecting many habitat specialists), spillover (affecting e.g. ground-living predators), and landscape complementation (affecting e.g. central-place foragers). It is shown that all three concepts contribute to current understanding of animal population dynamics in production landscapes, and that animals differ fundamentally in the extent to which the concepts are applicable. Therefore, it is argued that general recipes such as ‘reduce fragmentation’, ‘increase connectivity’, or ‘increase ecological heterogeneity’ may not provide a universal solution for conserving animals in contemporary agricultural landscapes. In addition, although animal movement studies have contributed to the understanding of biodiversity conservation in farmland, current knowledge about animal mobility is still limited. Thus research based on emerging methods such as landscape genetics or novel methods of tracking small animals is essential for increasing basic understanding of animal mobility.
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