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- Blomsma, Fenna, et al.
(författare)
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Developing a circular strategies framework for manufacturing companies to support circular economy-oriented innovation
- 2019
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Ingår i: Journal of Cleaner Production. - : Elsevier Ltd. - 0959-6526 .- 1879-1786. ; 241
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Tidskriftsartikel (refereegranskat)abstract
- This paper puts forward the Circular Strategies Scanner: a framework that introduces a taxonomy of circular strategies developed for use by manufacturing companies engaging in circular economy (CE) oriented innovation. Currently, a range of frameworks exists that propose a vision for how to operate in a CE, by identifying and organising relevant circular strategies. However, these frameworks have a limited applicability for specific business types, in particular manufacturing, and are unsuitable for use in CE oriented innovation, due to a lacking ability to support innovation processes through: 1) creating a comprehensive understanding of circular strategies, 2) mapping strategies currently applied and 3) finding opportunities for improved circularity across a range of business processes. This paper addresses these shortcomings by proposing a circular strategies framework for the manufacturing context, titled the Circular Strategies Scanner, which provides a comprehensive set of definitions of circular strategies and directly supports the early stages of CE oriented innovation. With this, the paper contributes to the body of work that develops CE transition methodology.
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| 2. |
- Ruiz-Caldas, Maria-Ximena, 1991-, et al.
(författare)
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Citrated cellulose nanocrystals from post-consumer cotton textiles
- 2023
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Ingår i: Journal of Materials Chemistry A. - : Royal Society of Chemistry. - 2050-7488 .- 2050-7496. ; 11:13, s. 6854-6868
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Tidskriftsartikel (refereegranskat)abstract
- We propose a new method for the extraction of cellulose nanocrystals (CNCs) from post-consumer cotton textiles through surface functionalization followed by mechanical treatment. Cotton-based textiles were esterified using an 85 wt% solution of citric acid at 100 °C, then further fibrillated in a microfluidizer. The final product, citrated cellulose nanocrystals (CitCNCs), was a dispersion of needle-like nanoparticles with high crystallinity. Up to 78 wt% of the cotton fabric was converted to CitCNCs that exhibited higher yields and a higher surface group content than CNCs extracted through H2SO4 hydrolysis, although CitCNCs showed a broader size distribution and decreased thermal stability. Experimental data supported by DFT calculations showed that the carboxyl groups on the CitCNC surface are bonded to cellulose by mono or diester linkages. An early-stage life cycle assessment (LCA) was performed to evaluate the environmental impact of using discarded textiles as a source of cellulose and analyze the environmental performance of the production of CitCNCs. Our work showed a significant reduction in the environmental burden of CNC extraction using post-consumer cotton instead of wood pulp, making clothing a good feedstock. The environmental impact of CitCNC production was mainly dominated by citric acid. As a proof of concept, around 58 wt% of the citric acid was recovered through evaporation and subsequent crystallization, which could reduce climate impact by 40%. With this work, we introduce a catalyst-free route to valorize textiles with the extraction of CitCNCs and how conducting LCA in laboratory-scale processes might guide future development and optimization.
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