| 1. |
- Ahmed, Ejaz, et al.
(författare)
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The role of big data analytics in Internet of Things
- 2017
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Ingår i: Computer Networks. - : Elsevier. - 1389-1286 .- 1872-7069. ; 129:2, s. 459-471
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Tidskriftsartikel (refereegranskat)abstract
- The explosive growth in the number of devices connected to the Internet of Things (IoT) and the exponential increase in data consumption only reflect how the growth of big data perfectly overlaps with that of IoT. The management of big data in a continuously expanding network gives rise to non-trivial concerns regarding data collection efficiency, data processing, analytics, and security. To address these concerns, researchers have examined the challenges associated with the successful deployment of IoT. Despite the large number of studies on big data, analytics, and IoT, the convergence of these areas creates several opportunities for flourishing big data and analytics for IoT systems. In this paper, we explore the recent advances in big data analytics for IoT systems as well as the key requirements for managing big data and for enabling analytics in an IoT environment. We taxonomized the literature based on important parameters. We identify the opportunities resulting from the convergence of big data, analytics, and IoT as well as discuss the role of big data analytics in IoT applications. Finally, several open challenges are presented as future research directions.
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| 2. |
- Al-Ani, Ibrahim Abdulrazak, et al.
(författare)
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Multi criteria decision making to optimize the best runoff control measures for the Haditha Dam Reservoir, Iraq
- 2020
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Ingår i: Journal of Environmental Hydrology. - : International Association for Environmental Hydrology. - 1058-3912 .- 1996-7918. ; 28
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Tidskriftsartikel (refereegranskat)abstract
- In Iraq, the two dominating surface water sources are Tigris and Euphrates Rivers in which some dams constructed on both of them forming reservoirs. The Haditha Dam reservoir is one of the most essential sources of drinking, irrigation, flood control and hydropower generation in Anbar State, Western Iraq. Besides, the reservoir is a unique habitat with a wide spectrum of biodiversity. The objective of this study is to investigate and monitor the water quality in Haditha Dam reservoir and introduce Multi Criteria Analysis (MCA) as a means to highlight the best runoff control measures depending on selected criteria and criteria weights. Experts were interviewed for the selection of criteria and for the assignment of the weight factor and scores. Four criteria from three categories such as technical, economic and environmental aspects were selected. Results from this study indicated that a the difference in TSS and Turbidity between the dry and wet seasons necessitates the installation of runoff control measures. It was found that the soil binders, sediment basin and diversion channel are the best alternatives for controlling erosion, sediment and drainage respectively. The sensitivity analysis showed very strong decisions made by the experts for the technical, economic and environmental criteria.
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| 3. |
- Belay Ibrahim, Kassa, et al.
(författare)
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Emerging 2D materials beyond mxenes and TMDs: Transition metal carbo-chalcogenides
- 2024
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Ingår i: Progress in Materials Science. - : Elsevier Ltd. - 0079-6425 .- 1873-2208. ; 144
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Forskningsöversikt (refereegranskat)abstract
- Interestingly, it opens the door for the development of the 2D materials family, which includes different classes of 2D materials. Among them, transition metal dichalcogenides (TMDs) and transition metal carbide MXenes (TMCs) have emerged. TMDs have unique layered structures, low cost, and are composed of earth abundant elements, but their poor electronic conductivity, poor cyclic stability, their structural and morphological changes during electrochemical measurements hinder their practical use. Recently, TMC MXenes have garnered attention in the 2D material world, but the issue of restacking and aggregation limits their direct use in large-scale energy conversion and storage. To address these challenges, hetero structures based on conductive TMCs MXenes and electrochemically active TMDs have emerged as a promising solution. However, understanding the solid/solid interface in heterostructured materials remains a challenge. To tackle this, 2D single component crystals with high capacity, low diffusion barrier, and good electronic conductivity are highly sought. The emergence of transition metal carbo-chalcogenides (TMCCs) has provided a potential solution, as these 2D nanosheets consist of TM2X2C, where TM represents transition metal, X is either S or Se, and C atom. This new class of 2D materials serves as a remedy by avoiding the challenges related to solid/solid interfaces often encountered in heterostructures. This review focuses on the latest developments in TMCCs, including their synthetic strategies, surface/interface engineering, and potential application in batteries, water splitting, and other electro-catalytic processes. The challenges and future perspectives of the design of TMCCs for electrochemical energy conversion and storage are also discussed.
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| 4. |
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| 5. |
- Ibrahim, Kassa Belay, et al.
(författare)
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Confinement Accelerates Water Oxidation Catalysis : Evidence from In Situ Studies
- 2023
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Ingår i: Small Methods. - : John Wiley & Sons. - 2366-9608. ; 7:10
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Tidskriftsartikel (refereegranskat)abstract
- Basic insight into the structural evolution of electrocatalysts under operating conditions is of substantial importance for designing water oxidation catalysts. The first-row transition metal-based catalysts present state-of-the-art oxygen evolution reaction (OER) performance under alkaline conditions. Apparently, confinement has become an exciting strategy to boost the performance of these catalysts. The van der Waals (vdW) gaps of transition metal dichalcogenides are acknowledged to serve as a suitable platform to confine the first-row transition metal catalysts. This study focuses on confining Ni(OH)2 nanoparticle in the vdW gaps of 2D exfoliated SnS2 (Ex-SnS2) to accelerate water oxidation and to guarantee long term durability in alkaline solutions. The trends in oxidation states of Ni are probed during OER catalysis. The in situ studies confirm that the confined system produces a favorable environment for accelerated oxygen gas evolution, whereas the un-confined system proceeds with a relatively slower kinetics. The outstanding OER activity and excellent stability, with an overpotential of 300 mV at 100 mA cm−2 and Tafel slope as low as 93 mV dec−1 results from the confinement effect. This study sheds light on the OER mechanism of confined catalysis and opens up a way to develop efficient and low-cost electrocatalysts.
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| 6. |
- Ibrahim, Kassa Belay, et al.
(författare)
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Facile Electron Transfer in Atomically Coupled Heterointerface for Accelerated Oxygen Evolution
- 2023
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Ingår i: Small. - : John Wiley & Sons. - 1613-6810 .- 1613-6829. ; 19:1
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Tidskriftsartikel (refereegranskat)abstract
- An efficient and cost-effective approach for the development of advanced catalysts has been regarded as a sustainable way for green energy utilization. The general guideline to design active and efficient catalysts for oxygen evolution reaction (OER) is to achieve high intrinsic activity and the exposure of more density of the interfacial active sites. The heterointerface is one of the most attractive ways that plays a key role in electrochemical water oxidation. Herein, atomically cluster-based heterointerface catalysts with strong metal support interaction (SMSI) between WMn2O4 and TiO2 are designed. In this case, the WMn2O4 nanoflakes are uniformly decorated by TiO2 particles to create electronic effect on WMn2O4 nanoflakes as confirmed by X-ray absorption near edge fine structure. As a result, the engineered heterointerface requires an OER onset overpotential as low as 200 mV versus reversible hydrogen electrode, which is stable for up to 30 h of test. The outstanding performance and long-term durability are due to SMSI, the exposure of interfacial active sites, and accelerated reaction kinetics. To confirm the synergistic interaction between WMn2O4 and TiO2, and the modification of the electronic structure, high-resolution transmission electron microscopy (HR-TEM), X-ray photoemission spectroscopy (XPS), and X-ray absorption spectroscopy (XAS) are used.
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| 7. |
- Sendeku, Marshet Getaye, et al.
(författare)
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Frontiers in Photoelectrochemical Catalysis: A Focus on Valuable Product Synthesis
- 2024
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Ingår i: Advanced Materials. - : John Wiley & Sons. - 0935-9648 .- 1521-4095. ; 36:21
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Forskningsöversikt (refereegranskat)abstract
- Photoelectrochemical (PEC) catalysis provides the most promising avenue for producing value-added chemicals and consumables from renewable precursors. Over the last decades, PEC catalysis, including reduction of renewable feedstock, oxidation of organics, and activation and functionalization of C─C and C─H bonds, are extensively investigated, opening new opportunities for employing the technology in upgrading readily available resources. However, several challenges still remain unsolved, hindering the commercialization of the process. This review offers an overview of PEC catalysis targeted at the synthesis of high-value chemicals from sustainable precursors. First, the fundamentals of evaluating PEC reactions in the context of value-added product synthesis at both anode and cathode are recalled. Then, the common photoelectrode fabrication methods that have been employed to produce thin-film photoelectrodes are highlighted. Next, the advancements are systematically reviewed and discussed in the PEC conversion of various feedstocks to produce highly valued chemicals. Finally, the challenges and prospects in the field are presented. This review aims at facilitating further development of PEC technology for upgrading several renewable precursors to value-added products and other pharmaceuticals.
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| 8. |
- Shifa, Tofik Ahmed, et al.
(författare)
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Interfacing CrOx and CuS for synergistically enhanced water oxidation catalysis
- 2023
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Ingår i: Chemical Engineering Journal. - : Elsevier B.V.. - 1385-8947 .- 1873-3212. ; 453:Part 1
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Tidskriftsartikel (refereegranskat)abstract
- The sluggish kinetics associated with the oxygen evolution reaction (OER) limits the sustainability of fuel production and chemical synthesis. Developing catalysts based on Earth abundant elements with a reasonable strategy could solve the challenge. Here, we present a heterostructure built from CrOx and CuS whose interface gives rise to the advent of new functionalities in catalytic activity. Using X-ray photoelectron and absorption spectroscopies, we identified the multiple oxidation states and low coordination number of Cr metal in CrOx-CuS heterostructure. Benefitting from these features, CrOx-CuS generates oxygen gas through water splitting with a low over potential of 190 mV vs RHE at a current density of 10 mA cm−2. The catalyst shows no evident deactivation after a 36-hours operation in alkaline medium. The high catalytic activity, inspired by first principles calculations, and long-time durability make it one of the most effective OER electrocatalysts.
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| 9. |
- Sumaila, U. Rashid, et al.
(författare)
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WTO must ban harmful fisheries subsidies
- 2021
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Ingår i: Science. - : American Association for the Advancement of Science (AAAS). - 0036-8075 .- 1095-9203. ; 374:6567, s. 544-544
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)
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| 10. |
- Yaqoob, Ibrar, et al.
(författare)
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Big data : From beginning to future
- 2016
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Ingår i: International Journal of Information Management. - : Elsevier BV. - 0268-4012 .- 1873-4707. ; 36:6B, s. 1231-1247
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Tidskriftsartikel (refereegranskat)abstract
- Big data is a potential research area receiving considerable attention from academia and IT communities. In the digital world, the amounts of data generated and stored have expanded within a short period of time. Consequently, this fast growing rate of data has created many challenges. In this paper, we use structuralism and functionalism paradigms to analyze the origins of big data applications and its current trends. This paper presents a comprehensive discussion on state-of-the-art big data technologies based on batch and stream data processing. Moreover, strengths and weaknesses of these technologies are analyzed. This study also discusses big data analytics techniques, processing methods, some reported case studies from different vendors, several open research challenges, and the opportunities brought about by big data. The similarities and differences of these techniques and technologies based on important parameters are also investigated. Emerging technologies are recommended as a solution for big data problems.
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