| 1. |
- Karlsson, Rose-Marie Pernilla, et al.
(author)
-
Thermodynamics of the Water-Retaining Properties of Cellulose-Based Networks
- 2019
-
In: Biomacromolecules. - : American Chemical Society. - 1525-7797 .- 1526-4602. ; 20:4, s. 1603-1612
-
Journal article (peer-reviewed)abstract
- Noncrystalline cellulose-based gel beads were used as a model material to investigate the effect of osmotic stress on a cellulosic network. The gel beads were exposed to osmotic stress by immersion in solutions with different concentrations of high molecular mass dextran and the equilibrium dimensional change of the gel beads was studied using optical microscopy. The volume fraction of cellulose was calculated from the volume of the gel beads in dextran solutions and their dry content and the relation between the cellulose volume fraction and the total osmotic pressure was thus obtained. The results show that the contribution to the osmotic pressure from counterions increases the water-retaining capacity of the beads at high osmotic pressures but also that the main factor controlling the gel bead collapse at high osmotic strains is the resistance to the deformation of the polymer chain network within the beads. Furthermore, the osmotic pressure associated with the deformation of the polymer network, which counteracts the deswelling of the beads, could be fitted to the Wall model indicating that the response of the cellulose polymer networks was independent of the charge of the cellulose. The best fit to the Wall model was obtained when the Flory-Huggins interaction parameter (Ç) of the cellulose-water system was set to 0.55-0.60, in agreement with the well-established insolubility of high molecular mass β-(1,4)-d-glucan polymers in water.
|
|
| 2. |
- An, Junxue, et al.
(author)
-
Influence of Glycosylation on Interfacial Properties of Recombinant Mucins : Adsorption, Surface Forces, and Friction
- 2017
-
In: Langmuir. - : American Chemical Society. - 0743-7463 .- 1520-5827. ; 33:18, s. 4386-4395
-
Journal article (peer-reviewed)abstract
- Interfacial properties of two brush-with-anchor mucins, C-P55 and C-PSLex, have been investigated at the aqueous solution/poly(methyl methacrylate) (PMMA) interface. Both are recombinant mucin-type fusion proteins, produced by fusing the glycosylated mucin part of P-selectin glycoprotein ligand-1 (PSLG-1) to the Fc part of a mouse immunoglobulin in two different cells. They are mainly expressed as dimers upon production. Analysis of the O-glycans shows that the C-PSLex mucin has the longer and more branched side chains, but C-P55 has slightly higher sialic acid content. The adsorption of the mucins to PMMA surfaces was studied by quartz crystal microbalance with dissipation. The sensed mass, including the adsorbed mucin and water trapped in the layer, was found to be similar for these two mucin layers. Atomic force microscopy with colloidal probe was employed to study surface and friction forces between mucin-coated PMMA surfaces. Purely repulsive forces of steric origin were observed between mucin layers on compression, whereas a small adhesion was detected between both mucin layers on decompression. This was attributed to chain entanglement. The friction force between C-PSLex-coated PMMA is lower than that between C-P55-coated PMMA at low loads, but vice versa at high loads. We discuss our results in terms of the differences in the glycosylation composition of these two mucins.
|
|
| 3. |
|
|
| 4. |
|
|
| 5. |
- Blomqvist, Per, et al.
(author)
-
Detailed study of distribution patterns of polycyclic aromatic hydrocarbons and isocyanates under different fire conditions
- 2014
-
In: Fire and Materials. - : Wiley. - 0308-0501 .- 1099-1018. ; 38:1, s. 125-144
-
Journal article (peer-reviewed)abstract
- This study has examined the distribution patterns between gas phase and particle phase of some chemical compounds produced in fires. It has also addressed the question of the distribution of individual particle-associated species between the different size-ranges of particles. The chemical compounds studied and discussed in this paper are polycyclic aromatic hydrocarbons (PAHs), and isocyanates. The steady-state tube furnace, ISO/TS 19700, was chosen as the physical fire model in order to study the production of particles from different types of fire exposure, that is, oxidative pyrolysis, well-ventilated flaming fires and under-ventilated flaming post-flashover fires. Two materials were chosen for investigation, a polyvinyl chloride (PVC) carpet and a wood board. The particle production from the two materials investigated varied concerning both the amounts produced and the particle size distributions. The analysis of PAHs showed that volatile PAHs were generally dominant. However, when the toxicity of the individual species was taken into account, the relative importance between volatile and particle-associated PAHs shifted the dominance to particle-bound PAH for both materials. The substantial degradation in the tests of the low polyurethane content of the PVC carpet, and the (4,4′-methylenediphenyl diisocyanate)-based binder in the wood board resulted in no or very small amount of quantifiable diisocyanates.
|
|
| 6. |
- Bodvik, Rasmus, et al.
(author)
-
Aggregation and network formation of aqueous methylcellulose and hydroxypropylmethylcellulose solutions.
- 2010
-
In: Colloids and Surfaces A. - : Elsevier. - 0927-7757 .- 1873-4359. ; 354:1-3, s. 162-171
-
Journal article (peer-reviewed)abstract
- Solution properties of methylcellulose (MC) and hydroxypropylmethylcellulose (HPMC) have been investigated as a function of temperature and concentration using a broad range of experimental techniques. Novelties include the extensive comparison between MC and HPMC solutions as well as the combination of techniques, and the use of Cryo transmission electron microscopy (Cryo-TEM). The correlation between rheology and light scattering results clearly demonstrates the relation between viscosity change and aggregation. Cryo-TEM images show the network structures formed. Viscosity measurements show that for both MC and HPMC solutions sudden changes in viscosity occur as the temperature is increased. The onset temperature for these changes depends on polymer concentration and heating rate. For both MC and HPMC solutions the viscosity on cooling is very different compared to on heating, demonstrating the slow equilibration time. The viscosity changes in MC and HPMC solutions are dramatically different; for MC solutions the viscosity increases by several orders of magnitude when a critical temperature is reached, whereas for HPMC solutions the viscosity decreases abruptly at a given temperature, followed by an increase upon further heating. Light and (SAXS) small-angle X-ray scattering shows that the increase in viscosity, for MC as well as for HPMC solutions, is due to extensive aggregation of the polymers. Light scattering also provides information on aggregation kinetics. The SAXS measurements allow us to correlate aggregation hysteresis to the viscosity hysteresis, as well as to extract some structural information. Cryo-TEM images give novel information that a fibrillar network is formed in MC solutions, and the strong viscosity increase occurs when this network spans the whole solution volume. For HPMC solutions the behaviour is more complex. The decrease in viscosity can be related to the formation of compact objects, and the subsequent increase to formation of fibrillar structures, which are more linear and less entangled than for MC.
|
|
| 7. |
|
|
| 8. |
- Ebenhag, Sven-Christian, et al.
(author)
-
Coherent optical two-way frequency transfer in a commercial DWDM network
- 2016
-
In: Proceedings of the Annual Precise Time and Time Interval Systems and Applications Meeting. - : Institute of Navigation. ; 2015-January, s. 116-120
-
Conference paper (peer-reviewed)abstract
- An experimental fiber connection for ultra-stable optical frequency transfer is established between SP Technical Research Institute of Sweden in Borås and Chalmers University of Technology in Gothenburg. The distance is approximately 60 km, and the connection is implemented in the Swedish University Computer Network. The sites are connected through an active flexible communication network where each optical channel can be configured with terminal equipment based on the user needs. The network is implemented with unidirectional optical amplifiers and duplex fibers. The signal quality and the stability when sending an optical coherent frequency utilizing a wavelength in a DWDM system fiber pair, is evaluated within this work. The aim of the system is to be ultra-stable which corresponds to a stability of 10-13 for t = 1 s (Overlapping Allan Variance), as well as providing the ability to distribute monitored ultra-stable frequency with a future traceability to UTC (SP) to multiple users within the future network. This paper describes the current status and results from the frequency transfer between SP and Chalmers.
|
|
| 9. |
- Ebenhag, Sven-Christian, et al.
(author)
-
Implementation of an optical fiber frequency distribution via commercial DWDM
- 2016
-
In: 2016 IEEE International Frequency Control Symposium (IFCS). - 1075-6787. - 9781509020911
-
Conference paper (peer-reviewed)abstract
- The rapid development in communication infrastructure over the past decades entails an increasing dependence on time and frequency, as well as its redundant distribution. This places demands not only on already existing distribution methods, but also on the development of new ones to meet future needs. To meet these demands several research groups are working on high performance fiber-based frequency transfer techniques. The best achieved performance so far is the techniques using a single bi-directional fiber connection, with customized bi-directional optical amplifiers [1]. The objective of this project is to develop a method that is compatible with data communication in DWDM-systems, i.e. using the existing infrastructure, as well as to be complementary technique for time and frequency distribution. Even though it is likely to have worse performance than the bi-directional system in terms of frequency stability, it will allow for the impassable obligation to follow the deployed structure of telecom networks. The establishment and early results of the non-stabilized link has been previously presented [2, 3]. The ongoing evaluation and improvement will be aimed at finding relevant performance specifications for a connection using this technique. The work presented here is the most recent results of the frequency transfer and discusses the future plans for the fiber connection, including the added time transfer method. If proven successful, the long-term objective is to establish a distribution network for optical frequency references in Sweden.
|
|
| 10. |
- Ebenhag, Sven-Christian, 1976, et al.
(author)
-
Two-way coherent frequency transfer in a commercial DWDM communication network in Sweden
- 2015
-
In: 2015 Joint Conference of the IEEE International Frequency Control Symposium and the European Frequency and Time Forum, FCS 2015 - Proceedings. - 1075-6787. - 9781479988662 ; , s. 276-279
-
Conference paper (peer-reviewed)abstract
- An experimental fiber link is being established between SP Technical Research Institute of Sweden in Boras and Chalmers University of Gothenburg in Sweden. The one way fiber length is about 60 km and implemented in SUNET (Swedish University Network). The aim of the project is to evaluate the signal quality when sending a stable optical frequency utilizing a wavelength in a DWDM (Dense Wavelength Division Multiplexing) system fiber pair. The experiment uses a channel in the DWDM with the wavelength of 1542.14 nm. This wavelength is within the C band and is therefore compatible with common Erbium doped amplifiers in this network. Another aim of the system is to be ultra-stable which corresponds to a stability of 1×10-13 for τ = 1 s as well as providing the ability to distribute monitored ultra-stable frequency with a future traceability to UTC (SP) (National realization of Universal Time Coordinated within Sweden) to multiple users within the network. Measurements of an optical frequency transfer using a fiber-link based on unidirectional light signals in parallel fibers have shown promising results in a free-running setup and in a lab environment. The fractional frequency stability, analyzed as the Overlapping Allan deviation, is approximately 3×10-13 at τ = 10 s and almost 1×10-14 at 105 s.
|
|
