| 1. |
- Chaika, Alexander N., et al.
(författare)
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Rotated domain network in graphene on cubic-SiC(001)
- 2014
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Ingår i: Nanotechnology. - : IOP Publishing. - 0957-4484 .- 1361-6528. ; 25:13
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Tidskriftsartikel (refereegranskat)abstract
- The atomic structure of the cubic-SiC(001) surface during ultra-high vacuum graphene synthesis has been studied using scanning tunneling microscopy (STM) and low-energy electron diffraction. Atomically resolved STM studies prove the synthesis of a uniform, millimeter-scale graphene overlayer consisting of nanodomains rotated by +/- 13.5 degrees relative to the < 110 >-directed boundaries. The preferential directions of the domain boundaries coincide with the directions of carbon atomic chains on the SiC(001)-c(2 x 2) reconstruction, fabricated prior to graphene synthesis. The presented data show the correlation between the atomic structures of the SiC(001)-c(2 x 2) surface and the graphene/SiC(001) rotated domain network and pave the way for optimizing large-area graphene synthesis on low-cost cubic-SiC(001)/Si(001) wafers.
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| 2. |
- Wu, Han-Chun, et al.
(författare)
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Transport Gap Opening and High On-Off Current Ratio in Trilayer Graphene with Self-Aligned Nanodomain Boundaries.
- 2015
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Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-086X .- 1936-0851. ; 9:9, s. 8967-8975
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Tidskriftsartikel (refereegranskat)abstract
- Trilayer graphene exhibits exceptional electronic properties that are of interest both for fundamental science and for technological applications. The ability to achieve a high on-off current ratio is the central question in this field. Here, we propose a simple method to achieve a current on-off ratio of 10(4) by opening a transport gap in Bernal-stacked trilayer graphene. We synthesized Bernal-stacked trilayer graphene with self-aligned periodic nanodomain boundaries (NBs) on the technologically relevant vicinal cubic-SiC(001) substrate and performed electrical measurements. Our low-temperature transport measurements clearly demonstrate that the self-aligned periodic NBs can induce a charge transport gap greater than 1.3 eV. More remarkably, the transport gap of ∼0.4 eV persists even at 100 K. Our results show the feasibility of creating new electronic nanostructures with high on-off current ratios using graphene on cubic-SiC.
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| 3. |
- Hugelius, Gustaf, et al.
(författare)
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High-resolution mapping of ecosystem carbon storage and potential effects of permafrost thaw in periglacial terrain, European Russian Arctic
- 2011
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Ingår i: Journal of Geophysical Research. - 0148-0227 .- 2156-2202. ; 116, s. G03024-
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Tidskriftsartikel (refereegranskat)abstract
- This study describes detailed partitioning of phytomass carbon (C) and soil organic carbon (SOC) for four study areas in discontinuous permafrost terrain, Northeast European Russia. The mean aboveground phytomass C storage is 0.7 kg C m(-2). Estimated landscape SOC storage in the four areas varies between 34.5 and 47.0 kg C m(-2) with LCC (land cover classification) upscaling and 32.5-49.0 kg C m(-2) with soil map upscaling. A nested upscaling approach using a Landsat thematic mapper land cover classification for the surrounding region provides estimates within 5 +/- 5% of the local high-resolution estimates. Permafrost peat plateaus hold the majority of total and frozen SOC, especially in the more southern study areas. Burying of SOC through cryoturbation of O- or A-horizons contributes between 1% and 16% (mean 5%) of total landscape SOC. The effect of active layer deepening and thermokarst expansion on SOC remobilization is modeled for one of the four areas. The active layer thickness dynamics from 1980 to 2099 is modeled using a transient spatially distributed permafrost model and lateral expansion of peat plateau thermokarst lakes is simulated using geographic information system analyses. Active layer deepening is expected to increase the proportion of SOC affected by seasonal thawing from 29% to 58%. A lateral expansion of 30 m would increase the amount of SOC stored in thermokarst lakes/fens from 2% to 22% of all SOC. By the end of this century, active layer deepening will likely affect more SOC than thermokarst expansion, but the SOC stores vulnerable to thermokarst are less decomposed.
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| 4. |
- Marchenko, Sergey, et al.
(författare)
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A plot-scale study of firn stratigraphy at Lomonosovfonna, Svalbard, using ice cores, borehole video and GPR surveys in 2012–14
- 2017
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Ingår i: Journal of Glaciology. - : Cambridge University Press (CUP). - 0022-1430 .- 1727-5652. ; 63:237, s. 67-78
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Tidskriftsartikel (refereegranskat)abstract
- Spatial heterogeneity of snow and firn properties on glaciers introduces uncertainty in interpretation of point and profile observations and complicates modelling of meltwater percolation and runoff. Here we present a study of the temporal and spatial dynamics of firn density and stratigraphy at the plot-scale (approximate to 10 m x 10 m x 10 m) repeated annually during 2012-14 at the Lomonosovfonna ice-field, Svalbard. Results from cores, video inspections in boreholes and radar grid surveys are compared. Ice layers 0.1-50 cm thick comprised approximate to 8% of the borehole length. Most of them are 1-3 cm thick and could not be traced between boreholes separated by 3 m. Large lateral variability of firn structure affects representativeness of observations in single holes and calls for repeated studies in multiple points to derive a representative stratigraphy signal. Radar reflections are poorly correlated with ice layers in individual boreholes. However, the match between the high amplitude peaks in the grid-averaged radar signal and horizons of preferential ice layer formation revealed by averaging the video surveys over multiple boreholes is higher. These horizons are interpreted as buried firn layers previously exposed to melt-freeze or wind-driven densification and several of them are consistently recovered throughout three field campaigns.
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| 5. |
- Marchenko, Sergey A., et al.
(författare)
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Water content of firn at Lomonosovfonna, Svalbard, derived from subsurface temperature measurements
- 2021
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Ingår i: Journal of Glaciology. - : Cambridge University Press. - 0022-1430 .- 1727-5652. ; 67:265, s. 921-932
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Tidskriftsartikel (refereegranskat)abstract
- The potential of capillary forces to retain water in pores is an important property of snow and firn at glaciers. Meltwater suspended in pores does not contribute to runoff and may refreeze during winter, which can affect the climatic mass balance and the subsurface density and temperature. However, measurement of firn water content is challenging and few values have been reported in the literature. Here, we use subsurface temperature and density measured at the accumulation zone of Lomonosovfonna (1200 m a.s.l.), Svalbard, to derive water content of the firn profiles after the 2014 and 2015 melt seasons. We do this by comparing measured and simulated rates of freezing front propagation. The calculated volumetric water content of firn is ~1.0–2.5 vol.% above the depth of 5 m and <0.5 vol.% below. Results derived using different thermistor strings suggest a prominent lateral variability in firn water content. Reported values are considerably lower than those commonly used in snow/firn models. This is interpreted as a result of preferential water flow in firn leaving dry volumes within wetted firn. This suggests that the implementation of irreducible water content values below 0.5 vol.% within snow/firn models should be considered at the initial phase of water infiltration.
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| 6. |
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| 7. |
- Marchenko, Sergey, et al.
(författare)
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Parameterizing deep water percolation improves subsurface temperature simulations by a multilayer firn model
- 2017
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Ingår i: Frontiers in Earth Science. - : Frontiers Media SA. - 2296-6463. ; 5:16
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Tidskriftsartikel (refereegranskat)abstract
- Deep preferential percolation of melt water in snow and firn brings water lower along the vertical profile than a laterally homogeneous wetting front. This widely recognized process is an important source of uncertainty in simulations of subsurface temperature, density, and water content in seasonal snow and in firn packs on glaciers and ice sheets. However, observation and quantification of preferential flow is challenging and therefore it is not accounted for by most of the contemporary snow/firn models. Here we use temperature measurements in the accumulation zone of Lomonosovfonna, Svalbard, done in April 2012-2015 using multiple thermistor strings to describe the process of water percolation in snow and firn. Effects of water flow through the snow and firn profile are further explored using a coupled surface energy balance - firn model forced by the output of the regional climate model WRF. In situ air temperature, radiation, and surface height change measurements are used to constrain the surface energy and mass fluxes. To account for the effects of preferential water flow in snow and firn we test a set of depth-dependent functions allocating a certain fraction of the melt water available at the surface to each snow/firn layer. Experiments are performed for a range of characteristic percolation depths and results indicate a reduction in root mean square difference between the modeled and measured temperature by up to a factor of two compared to the results from the default water infiltration scheme. This illustrates the significance of accounting for preferential water percolation to simulate subsurface conditions. The suggested approach to parameterization of the preferential water flow requires low additional computational cost and can be implemented in layered snow/ firn models applied both at local and regional scales, for distributed domains with multiple mesh points.
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| 8. |
- Marchenko, Sergey, 1988-
(författare)
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Subsurface fluxes of mass and energy at the accumulation zone of Lomonosovfonna ice cap, Svalbard
- 2018
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Glaciers cover ca 10% of the Earth's land and are found in the high altitudes and latitudes. They are important components of environmental systems due to the multiple feedbacks linking them with the atmosphere, hydrosphere and periglacial landscapes. The cold sloping surfaces of glaciers change the patterns of atmospheric circulation at different scales and at the same time glaciers are largely controlled by climate. They are commonly used as climatic archives for reconstruction of the past environmental changes based on evidences from the areas affected by glaciation at the moment and in the past. Glaciers are the largest fresh-water reservoirs on our planet and runoff thereof significantly affects the global sea level and life in glaciated catchments. However, melt- and rain-induced runoff from glaciers greatly depends on the subsurface conditions which thus need to be taken into account, particularly in a changing climate.This thesis focuses on the processes of subsurface mass and energy exchange in the accumulation zones of glaciers, which are largely driven by the climate at the surface. Results are largely based on empirical data from Lomonosovfonna ice cap, Svalbard, collected during field campaigns in 2012-2017. Observations of subsurface density and stratigraphy using shallow cores, video records from boreholes and radar surveys returned detailed descriptions of the snow and firn layering. The subsurface temperature data collected using multiple thermistor strings provided insights into several subsurface processes. The temperature values measured during three summer seasons were used to constrain the suggested parameterization of deep preferential water flow through snow and firn. The part of data recorded during the cold seasons was employed for an inverse modelling exercise resulting in optimized values of effective thermal conductivity of the subsurface profile. These results are then used to compute the subsurface water content by comparing the simulated and measured rates of freezing front propagation after the melt season in 2014.The field observations and quantitative estimates provide further empirical evidences of preferential water flow in snow/firn packs at glaciers. Results presented in the thesis call for implementation of description of the process in layered models simulating the subsurface fluxes of energy and mass at glaciers. This will result in a better understanding of glacier response to the past and future climatic changes and more accurate estimates of glacier runoff.
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| 9. |
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| 10. |
- Marchenko, Sergey, et al.
(författare)
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Thermal conductivity of firn at Lomonosovfonna, Svalbard, derived from subsurface temperature measurements
- 2019
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Ingår i: The Cryosphere. - : Copernicus GmbH. - 1994-0416 .- 1994-0424. ; 13, s. 1843-1859
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Tidskriftsartikel (refereegranskat)abstract
- Abstract. Accurate description of snow and firn processes is necessary for estimating the fraction of glacier surface melt that contributes to runoff. Most processes in snow and firn are to a great extent controlled by the temperature therein and in the absence of liquid water, the temperature evolution is dominated by the conductive heat exchange. The latter is controlled by the effective thermal conductivity k. Here we reconstruct the effective thermal conductivity of firn at Lomonosovfonna, Svalbard, using an optimization routine minimizing the misfit between simulated and measured subsurface temperatures and densities. The optimized k* values in the range from 0.2 to 1.6 W (m K)−1 increase downwards and over time. The results are supported by uncertainty quantification experiments, according to which k* is most sensitive to systematic errors in empirical temperature values and their estimated depths, particularly in the lower part of the vertical profile. Compared to commonly used density-based parameterizations, our k values are consistently larger, suggesting a faster conductive heat exchange in firn.
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