| 1. |
- Khodorkovskii, M. A., et al.
(författare)
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Electronic spectra of ArXe molecules in the region of Xe* (5d, 7s, 7p, 6p '), 80 300-89 500 cm(-1), using resonantly enhanced multiphoton ionization
- 2010
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Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 43:23, s. 235101-
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Tidskriftsartikel (refereegranskat)abstract
- The electronic spectra of ArXe molecules in the 80 300-89 500 cm(-1) region were recorded by (2 + n) and (3 + n) REMPI methods. The vibrational progressions attributed to transitions of molecules from the ground state to the bounded excited state and wide unstructured bands related to transitions to the continuous upper state were obtained. The molecular constants of ArXe* were calculated for all the observed progressions in the 80 300-87 000 cm(-1) region as an approximation of an anharmonic oscillator and the Morse potential. For different excited states the energy of harmonic oscillator and the dissociation energy are changed from 10 to 100 cm(-1) and from 70 to 750 cm(-1), respectively.
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| 2. |
- Khodorkovskii, M. A., et al.
(författare)
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Electronic spectra of ArXe molecules in the region of Xe* (6s ', 6p, 5d), 77 000-80 200 cm(-1), using resonantly enhanced multiphoton ionization
- 2010
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Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 43:15, s. 155101-
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Tidskriftsartikel (refereegranskat)abstract
- The excited electronic states of ArXe molecules in the region 77 000-80 200 cm(-1) were studied using the (2+1) and (3+1) resonance-enhanced multiphoton ionization methods. The use of different methods of multi-photon excitation and Ar+ ion registration allowed us to obtain some new data. Molecular constants were obtained for previously unknown excited states of molecules with the following dissociation limits: ArXe* -> (ArS0)-S-1+Xe*6p[5/2](3) with Omega = 2, 3 symmetry; (ArS0)-S-1+Xe*6p[3/2](2) with Omega = 1, 2 symmetry; (XeS1)-S-0 -> Xe*6s'[1/2](1)(0) with Omega = 0(+) symmetry.
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| 3. |
- Khodorkovskii, M. A., et al.
(författare)
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Electronic spectra of XeNe molecules in the range 77100-90100 cm(-1) near Xe* (6p, 5d, 6p', 7s, 7p, 6d) obtained by the (3+1) REMPI and (2+1) REMPI methods
- 2010
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Ingår i: Optics and Spectroscopy. - 0030-400X .- 1562-6911. ; 108:6, s. 899-914
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Tidskriftsartikel (refereegranskat)abstract
- The electronic spectra of XeNe molecules in the range of 77100-90100 cm(-1) are measured by the method of laser resonance multiphoton ionization in a supersonic jet. The photoionization spectra are obtained upon two- and three-photon excitations of molecules and their ionization by the next photon. In the range of 80300-90100 cm(-1) near Xe*(5d, 6p', 6d, 7s, and 7p), the spectra are obtained for the first time. A whole number of vibrational systems are measured in this range. The majority of vibrational systems near Xe* (5d, 6d, 7p, and 7s) are located in the red range with respect to their dissociation limits. In the blue range with respect to the dissociation limits, continua corresponding to transitions of molecules from the ground state to repulsive potential curves of excited states are detected. For a number of excited states of XeNe molecules, the vibrational analysis is performed and molecular constants are estimated.
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| 4. |
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| 5. |
- Galakhov, V. R., et al.
(författare)
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Electronic structure and x-ray spectra of defective oxides LixCoO2
- 2006
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 74:4, s. 045120-
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Tidskriftsartikel (refereegranskat)abstract
- X-ray absorption, resonant x-ray emission, and x-ray photoelectron spectra of the valence band and core levels have been measured for LixCoO2 (0.6 <= x <= 1.0). Resonant O K alpha x-ray emission spectra of LiCoO2 showed localized excitonic states due to a dd transition between unoccupied and occupied Co 3d states. On the basis of measurements of Co 3s x-ray photoelectron and Co 2p and O 1s x-ray absorption spectra it was established that in defective cobaltites the electronic holes are localized mainly in O 2p states. Evidence of phase separation in LixCoO2 has been found.
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| 6. |
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| 7. |
- Freelon, B., et al.
(författare)
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Low energy electronic spectroscopy of an infinite-layer cuprate : A resonant inelastic X-ray scattering study of CaCuO2
- 2010
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Ingår i: Physica. C, Superconductivity. - : Elsevier BV. - 0921-4534 .- 1873-2143. ; 470:3, s. 187-192
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Tidskriftsartikel (refereegranskat)abstract
- We report the results of Oxygen K-edge soft X-ray absorption and emission spectroscopy that was performed on an infinite-layer insulating cuprate thin film CaCuO2 Experimentally obtained spectra arc consistent with local density approximation calculations X-ray absorption spectra show a close resemblance to spectra obtained from homologous single crystal cuprates In addition to d-d excitations. X-ray emission spectra reveal the presence of Zhang-Rice singlet states in the infinite-layer CuO2 planes The question of whether the Zhang-Rice singlet features are masked by the O 2p main-band is addressed. it is possible to quantify the position of the Zhang-Rice singlet using emission intensity profiles X-ray emission is demonstrated as a tool for understanding CuO2 planar electronic correlation in the prototypical infinite-layer The energy difference, 2 0 eV, between the oxygen main-band and the Zhang-Rice singlet band is found to match values obtained theoretically using established planar electronic correlation parameters.
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| 8. |
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| 9. |
- Ivanov Öfverholm, I., et al.
(författare)
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Overexpression of chromatin remodeling and tyrosine kinase genes in iAMP21-positive acute lymphoblastic leukemia
- 2020
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Ingår i: Leukemia and Lymphoma. - : Informa UK Limited. - 1042-8194 .- 1029-2403. ; 61:3, s. 604-613
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Tidskriftsartikel (refereegranskat)abstract
- Intrachromosomal amplification of chromosome 21 (iAMP21) is a cytogenetic subtype associated with relapse and poor prognosis in pediatric B-cell precursor acute lymphoblastic leukemia (BCP ALL). The biology behind the high relapse risk is unknown and the aim of this study was to further characterize the genomic and transcriptional landscape of iAMP21. Using DNA arrays and sequencing, we could identify rearrangements and aberrations characteristic for iAMP21. RNA sequencing revealed that only half of the genes in the minimal region of amplification (20/45) were differentially expressed in iAMP21. Among them were the top overexpressed genes (p < 0.001) in iAMP21 vs. BCP ALL without iAMP21 and three candidate genes could be identified, the tyrosine kinase gene DYRK1A and chromatin remodeling genes CHAF1B and SON. While overexpression of DYRK1A and CHAF1B is associated with poor prognosis in malignant diseases including myeloid leukemia, this is the first study to show significant correlation with iAMP21-positive ALL.
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| 10. |
- Rohringer, N., et al.
(författare)
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Stimulated X-Ray Raman Scattering with Free-Electron Laser Sources
- 2016
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Ingår i: X-Ray Lasers 2014. - Cham : Springer. - 0930-8989. - 9783319195216 - 9783319195209 ; , s. 201-207
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Bokkapitel (refereegranskat)abstract
- Stimulated electronic x-ray Raman scattering is the building block for several proposed x-ray pump probe techniques, that would allow the study of electron dynamics at unprecedented timescales.We present high spectral resolution data on stimulated electronic x-ray Raman scattering in a gas sample of neon using a self-amplified spontaneous emission x-ray free-electron laser. Despite the limited spectral coherence and broad bandwidth of these sources, high-resolution spectra can be obtained by statistical methods, opening the path to coherent stimulated x-ray Raman spectroscopy. An extension of these ideas to molecules and the results of a recent experiment in CO are discussed.
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