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- Erkfeldt, Sara U, 1974, et al.
(författare)
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Alumina-supported In2O3, Ga2O3 and B2O3 catalysts for lean NOx reduction with dimethyl ether
- 2012
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Ingår i: Applied Catalysis B: Environmental. - : Elsevier BV. - 0926-3373 .- 1873-3883. ; 117, s. 369-383
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Tidskriftsartikel (refereegranskat)abstract
- Alumina-supported In2O3, Ga2O3 and B2O3 were investigated as catalysts for lean NOx reduction with DME as reducing agent and compared to pure Al2O3 and In2O3. The In2O3-promoted alumina catalysts showed the highest NOx conversion at low temperatures, although with a narrow temperature window. Pure In2O3, on the other hand, was inactive for NOx reduction with DME. The Ga2O3- and B2O3-promoted alumina catalysts gave the highest NOx conversion at higher temperatures, showed a temperature window similar to pure alumina, but were less sensitive to H2O inhibition. Possible reasons for these observations are discussed.
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2. |
- Erkfeldt, Sara U, 1974, et al.
(författare)
-
Influence of the reducing agent for lean NOx reduction over Cu-ZSM-5
- 2011
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Ingår i: Applied Catalysis B: Environmental. - : Elsevier BV. - 0926-3373 .- 1873-3883. ; 102:3-4, s. 547-554
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Tidskriftsartikel (refereegranskat)abstract
- A range of ethers, alcohols and alkanes were compared as reducing agents for NOx over a Cu-ZSM-5 lean NOx catalyst. The nature of the reducing agent was found to determine the degree of NOx reduction. Methanol and DME were virtually inactive as reductants over this catalyst, while higher ethers and alcohols showed high NOx conversion. A detailed study was performed to investigate the differences. Among the studied variables, the chemical structure of the reductant was found to be especially important. Despite having a lower reducing capacity than DME, ethylene glycol was active for NOx reduction. It is concluded that a C-C bond in the reducing agent is required for lean NOx reduction over Cu-ZSM-5. The absence of this bond in DME and methanol explains their low activity for NOx reduction over this catalyst.
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3. |
- Erkfeldt, Sara U, 1974, et al.
(författare)
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Lean NOx Reduction with Various Bio-Diesels as Reducing Agents
- 2011
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Ingår i: Topics in Catalysis. - : Springer Science and Business Media LLC. - 1572-9028 .- 1022-5528. ; 54:16-18, s. 1219-1223
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Tidskriftsartikel (refereegranskat)abstract
- Commercial Cu-ZSM-5- and Ag/Al2O3-based lean NOx catalysts were evaluated in a synthetic exhaust gas bench with the fuels RME, B30, B15, Agrodiesel 15, GTL, NExBTL, and MK1 as reducing agents. The influence of reductant was larger for Ag/Al2O3, albeit moderate, whereas the Cu-zeolite showed the highest NOx conversion at lower temperature for all alternative fuels tested.
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