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- Frankki, Sofia, et al.
(författare)
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Mobility of Chloroaromatic Compounds in Soil: Case Studies of Swedish Chlorophenol-contaminated Sawmill Sites
- 2007
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Ingår i: AMBIO: A Journal of the Human Environment. ; 36:6, s. 452–7-
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Tidskriftsartikel (refereegranskat)abstract
- This paper summarizes recent studies on the environmental fate of chloroaromatic compounds in chlorophenol (CP)-contaminated soil and groundwater at Swedish sawmill sites. Relative proportions of CPs, polychlorinated phenoxy phenols (PCPPs), polychlorinated diphenyl ethers (PCDEs), polychlorinated dibenzo-p-dioxins (PCDDs), and polychlorinated dibenzofurans (PCDFs) were determined in preservatives, particulate organic matter (POM), dissolved organic matter (DOM), groundwater, and particles filtered from groundwater. All compound classes were found in the different compartments. The fraction of PCPPs, PCDEs, PCDDs, and PCDFs had increased in the soil samples relative to the proportions in the preservatives. This increase showed correlation with the hydrophobicity, that is, PCDDs had the largest increase. Similar correlation was found between hydrophobicity and the importance of partitioning to POM over DOM. The more water soluble compound group, CP, was found equally distributed between POM and DOM. For PCPPs, PCDEs, PCDDs, and PCDFs, the relative partitioning to POM increased with increased hydrophobicity. Despite the relative partitioning towards POM, compared with DOM, cotransport with DOM and suspended colloidal fractions was found to substantially increase the transport of these compounds in the groundwater samples.
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| 2. |
- Persson, Ylva, 1976-
(författare)
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Chlorinated organic pollutants in soil and groundwater at chlorophenol-contaminated sawmill sites
- 2007
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Mixtures of chlorinated organic pollutants can be found in the soils at chlorophenol-contaminated sawmill, including (inter alia) polychlorinated phenols (CPs), phenoxyphenols (PCPPs), diphenyl ethers (PCDEs), dibenzofurans (PCDFs) and dioxins (PCDDs). These hydrophobic compounds have low water solubility and hence low mobility as truly dissolved compounds. However, they may migrate through the soil at significant rates via co-transport with dissolved organic matter (DOM) and colloids of fine, waterborne particulate matter. In the work underlying this thesis the distribution of chlorinated hydrophobic pollutants between these two mobile fractions in soil samples from five sawmill sites was studied Soils at five sites at which CPs were formerly used were characterized, and found to have complex profiles of chlorinated hydrophobic pollutants. CPs, PCPPs, PCDEs and PCDD/Fs were present at up to ppm-levels. Furthermore, the relative proportions of the pollutants differed from their relative proportions in the preservatives used at the sites, indicating that they have been transported from, and/or degraded in, the soil at different rates. These organic pollutants have low water solubility and strong affinity for soil organic matter (SOM). The importance of SOM for the fate of CPs, PCPPs, PCDEs, PCDFs and PCDDs in soil was investigated by examining the distribution of compounds between the mobile DOM and the immobile particulate organic matter (POM). The partitioning of CPs between DOM and POM was found to be approximately equal. However, the relative strength of association with POM of groups of chlorinated organic pollutants was positively correlated with their hydrophobicity, and thus increased in the order CP < PCPP < PCDE < PCDF < PCDD. Despite the weak association of PCDD/Fs with DOM our investigations found that considerable concentrations of these pollutants were bound to mobile fractions (DOM and colloids, >0.2 µm) in both a groundwater analysis and a leaching test. CPs and PCPP were present at up to ppm- and ppb-levels, respectively, and PCDEs and PCDD/Fs at up to ppt-levels. The importance of transport in association with the mobile fraction (DOM and colloids) increased with increasing hydrophobicity e.g. PCDDs were almost entirely associated with fine particulate matter, while CPs were largely found in the water phase and only minor proportions were associated with colloids.
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| 4. |
- Persson, Ylva, et al.
(författare)
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Dioxins, chlorophenols and other chlorinated organic pollutants in colloidal and water fractions of groundwater from a contaminated sawmill site
- 2008
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Ingår i: Environmental Science and Pollution Research. - : Springer. - 0944-1344 .- 1614-7499. ; 15:6, s. 463-471
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Tidskriftsartikel (refereegranskat)abstract
- Background, aim, and scope: The distribution of chlorinated organic contaminants in groundwater and the importance of colloids were studied in groundwater from a sawmill site contaminated by chlorophenol preservatives.Materials and methods: The groundwater was fractionated into three different size ranges: (1) >0.7 μm, (2) 0.4–0.7 μm and (3) 0.2–0.4 μm and the filtered water phase. The concentrations of chlorophenols (CP), chlorinated phenoxy phenols (PCPP), chlorinated diphenyl ethers (PCDE), chlorinated dibenzofurans (PCDF) and chlorinated dibenzo-p-dioxins (PCDD) were determined in each fraction. The colloids were characterised regarding the chemical composition using X-ray photoelectron spectroscopy (XPS).Results: Chlorophenols were mostly found in the water fraction and PCDD/Fs were found almost exclusively in the particulate fractions. For example, the filtered water phase contained 2,100 μg l−1 and 0.72 ng l−1 for CPs and PCDD/Fs, respectively, and the particulate fractions contained 27 μg l−1 and 32 ng l−1 for CPs and PCDD/Fs, respectively. XPS evaluation of the particulate phases showed no correlation between the surface chemistry of the particle properties and the distribution of chlorinated compounds.Discussion: The results suggest that groundwater transport of CPs, PCPPs, PCDEs and PCDD/Fs may occur from contaminated sawmill sites and that the colloid-facilitated transport, especially of PCDD/Fs, is substantial. The results correlated well with previous studies of compounds sorbed to dissolved organic carbon, which indicate that dissolved and colloidal organic carbon facilitated the transport of PCDEs, PCDFs and PCDDs particularly.Conclusions: Several classes of chlorinated compounds were readily detected in the groundwater samples. Due to the differences in their physicochemical properties, CPs, PCPPs, PCDEs and PCDD/Fs vary in their partitioning between colloidal fractions and the filtered groundwater. The proportion of the bound fraction increased with an increasing hydrophobicity of the chlorinated compounds. The groundwater transport of colloid-associated pollutants from the site may be significant.Recommendations and perspectives: The results imply that colloidal particles <0.7 μm are freely mobile in groundwater from this site. The groundwater transport of colloid-associated pollutants may be significant. However, the extent of the problem is not yet known and, thus, further research is needed to evaluate the impact of colloidal transport of hydrophobic organic contaminants. In Sweden alone, 400 to 500 sawmill sites are estimated to be contaminated with PCDD/Fs as a result of the former use of CP-based wood preservatives. The widespread use of CP mixtures for a variety of applications, including wood preservation, indicates that potential colloidal transport will be an issue of concern in many countries.
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| 7. |
- Persson, Ylva, et al.
(författare)
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Levels of chlorinated compounds (CPs, PCPPs, PCDEs, PCDFs and PCDDs) in soils at contaminated sawmill sites in Sweden.
- 2007
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Ingår i: Chemosphere. - : Elsevier BV. - 0045-6535 .- 1879-1298. ; 66:2, s. 234-42
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Tidskriftsartikel (refereegranskat)abstract
- Soil samples from five contaminated sawmill sites in Sweden were characterized with respect to chlorophenols (CP), chlorinated phenoxy phenols (PCPP, hydroxylated chlorinated diphenyl ethers), chlorinated diphenyl ethers (PCDE), chlorinated dibenzofurans (PCDF) and chlorinated dibenzo-p-dioxins (PCDD). The composition of chlorinated compounds in the soil samples was compared to the composition of two preservatives commonly used in the Scandinavian wood impregnation industry: the 2,3,4,6-tetrachlorophenol preservative called Ky-5 and the pentachlorophenol preservative Dowicide G. The levels of CPs in the soil samples ranged from 0.1 to 4500 mg kg−1 d.w., PCPPs from <0.15 to 940 mg kg−1 d.w., PCDEs from <38 to 6800 μg kg−1 d.w., PCDFs from 7.4 to 18 000 μg kg−1 d.w. and PCDDs from 9.9 to 35 000 μg kg−1 d.w. The resulting WHO-TEQ of PCDD/Fs in the soil samples ranged from 0.14 to 3000 μg kg−1 d.w. Despite a wide range of concentrations the congener compositions were similar within tetrachlorophenate and pentachlorophenate contaminated soils respectively. The contamination at each sawmill site may be linked to the use of either a tetrachlorphenol preservative, e.g. Ky-5, or a pentachlorophenol preservative, e.g. Dowicide G. Best-fit calculations were used to compare the chlorinated phenol contents of the preservatives to those of the soil samples. This revealed a positive correlation between the hydrophobicity (log Kow) of contaminants and the ratio of their levels in soil to preservatives. The relative abundance of the chlorinated compounds varied greatly between the five sites studied, suggesting that their transport parameters differ substantially.
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