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| 2. |
- Makarova, Tatiana L, et al.
(författare)
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Anisotropic metallic properties of highly-oriented rhombohedral C60 polymer.
- 2001
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Ingår i: Synthetic Metals vol. 121. - Amsterdam : Elsevier B.V.. ; , s. 1099-1100
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Konferensbidrag (refereegranskat)abstract
- The pure rhombohedral phase of C60 polymer displays highly anisotropic electrical properties. Conductivity in the polymerized (001) planes exhibits a metal-insulator transition and shows the features of 2D weak localization. Anisotropy ratio is temperature-dependent and reaches 10_6. Dysonian ESR lineshape is consistent with the metallic nature of the samples.
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| 3. |
- Makarova, Tatiana L, et al.
(författare)
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Electrical properties of the rhombohedral C60 polymers
- 1999
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Ingår i: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, vol. 7. - Pennington, NJ : The Electrochemical Society. - 1566772346 ; , s. 628-639
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Konferensbidrag (refereegranskat)abstract
- Electrical properties of polymerized fullerenes C60 are governed by the type of polymerization which is in turn determined by the initial (P or H) orientation of molecules, the pressure and the temperature of polymerization. The mixed tetragonal - rhombohedral polymerized structure shows a semiconductor-like behavior. An increase in the polymerization temperature results in a decrease in the activation energy and an increase in conductivity. The conductivity prefactor and the activation energy are interconnected by the Meyer-Neldel rule. The pure rhombohedral phase shows highly anisotropic electrical properties. The conductivity in the polymerized (111) planes exhibits a metal-insulator transition and shows the features of 2D weak localization.
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| 4. |
- Makarova, Tatiana L, et al.
(författare)
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Electrical properties of two-dimensional fullerene matrices
- 2001
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Ingår i: Carbon. - : Elsevier B.V.. - 0008-6223 .- 1873-3891. ; 39:14, s. 2203-2209
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Tidskriftsartikel (refereegranskat)abstract
- The electrical properties of two-dimensionally polymerized C60 fullerenes were studied. Fullerene matrices consisting of randomly oriented domains are compared to the highly-oriented rhombohedral phase. The conductivity of the randomly oriented polymers obeys the Arrhenius law and can be described in a multiple trapping model. The oriented phase of polymeric C60 shows a distinct anisotropy in the electrical properties with a metallic-like in-plane conductivity at high temperatures.
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| 5. |
- Moret, Roger, et al.
(författare)
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Single-crystal structural study of the pressure-temperature induced dimerization of C60
- 2004
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Ingår i: European Physics Journal B. - Berlin : Springer. - 1434-6028 .- 1434-6036. ; 37:1, s. 25-37
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Tidskriftsartikel (refereegranskat)abstract
- We present a study by Raman spectroscopy and X-ray diffraction/diffuse scattering of C60 single-crystals treated at high-pressure and high-temperature. This allowed us to obtain structural information on the C60 dimer state which can be considered as an intermediate state in the polymerization process. In the 1-6 GPa pressure range the crystals are primarily formed of dimers with additional minor fractions of monomers, 1D and 2D polymers, as shown by the analysis of the Raman spectra. The dimers are disordered within an average cubic lattice derived from that of the monomer. Single-crystal diffraction patterns reveal a characteristic diffuse scattering intensity distribution which has been simulated by calculating the diffuse scattering produced by dimer and trimer model structures. Satisfactory agreement is obtained for random positional and orientational disorder of the C60-C60 dimers although a small concentration of similarly disordered trimers is likely. In a first approximation the dimer/trimer disorder can be considered as random but various inter-dimer correlations are probably present, as discussed.
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